| 中文名 | 乙酸-3-甲基-3-丁烯-1-醇酯 |
|---|---|
| 英文名 | 3-Methyl-3-buten-1-yl acetate |
| 密度 | 0.899g/cm3 |
|---|---|
| 沸点 | 147.3ºC at 760mmHg |
| 分子式 | C7H12O2 |
| 分子量 | 128.16900 |
| 闪点 | 56.8ºC |
| 精确质量 | 128.08400 |
| PSA | 26.30000 |
| LogP | 1.51570 |
| 折射率 | 1.416 |
|
Version 1.1
Regulation (EC) No 1907/2006 1 - Product and Company Information Product Name3-METHYL-3-BUTEN-1-YL ACETATE - 50 MG 2 - Hazards Identification SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT Flammable.
3 - Composition/Information on Ingredients Product NameCAS #EC noAnnex I Index Number 3-METHYL-3-BUTEN-1-YL ACETATE5205-07-2 225-996-6 None FormulaC7H12O2 Molecular Weight 128,1710 AMU Synonyms3-Buten-1-ol, 3-methyl-, acetate 4 - First Aid Measures AFTER INHALATION If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. AFTER SKIN CONTACT In case of skin contact, flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing and shoes. Call a physician. AFTER EYE CONTACT In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. Call a physician. AFTER INGESTION If swallowed, wash out mouth with water provided person is conscious. Call a physician immediately. 5 - Fire Fighting Measures ALDRICHwww.molbase.com EXTINGUISHING MEDIA Suitable: For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray; solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water. SPECIAL RISKS Specific Hazard(s): Flammable liquid. Emits toxic fumes under fire conditions. Explosion Hazards: Vapor may travel considerable distance to source of ignition and flash back. Container explosion may occur under fire conditions. SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. 6 - Accidental Release Measures PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL Evacuate area. Shut off all sources of ignition. Use nonsparking tools. PROCEDURE(S) OF PERSONAL PRECAUTION(S) Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves. METHODS FOR CLEANING UP Cover with dry-lime, sand, or soda ash. Place in covered containers using non-sparking tools and transport outdoors. Ventilate area and wash spill site after material pickup is complete. 7 - Handling and Storage HANDLING Directions for Safe Handling: Avoid contact with eyes, skin, and clothing. Do not breathe vapor. Avoid prolonged or repeated exposure. STORAGE Conditions of Storage: Keep container closed. Keep away from heat, sparks, and open flame. 8 - Exposure Controls / Personal Protection ENGINEERING CONTROLS Safety shower and eye bath. Use nonsparking tools. Mechanical exhaust required. GENERAL HYGIENE MEASURES Wash thoroughly after handling. PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Where risk assessment shows air-purifying respirators ALDRICHwww.molbase.com are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Hand Protection: Compatible chemical-resistant gloves. Eye Protection: Chemical safety goggles. 9 - Physical and Chemical Properties AppearancePhysical State: Liquid PropertyValueAt Temperature or Pressure pH N/A BP/BP RangeN/A MP/MP RangeN/A Flash Point< 25,000 °C FlammabilityN/A Autoignition TempN/A Oxidizing Properties N/A Explosive Properties N/A Explosion LimitsN/A Vapor PressureN/A Partition Coefficient Log Kow: 2,120 ViscosityN/A Vapor DensityN/A Saturated Vapor Conc. N/A Evaporation RateN/A Bulk DensityN/A Decomposition Temp.N/A Solvent ContentN/A Water ContentN/A Surface TensionN/A ConductivityN/A Miscellaneous DataN/A SolubilityN/A 10 - Stability and Reactivity STABILITY Stable: Stable. Materials to Avoid: Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide. HAZARDOUS POLYMERIZATION Hazardous Polymerization: Will not occur 11 - Toxicological Information ACUTE TOXICITY LD50 Oral Rat > 10.000, mg/kg ROUTE OF EXPOSURE Skin Contact: May cause skin irritation. Skin Absorption: May be harmful if absorbed through the skin. ALDRICHwww.molbase.com Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. 12 - Ecological Information No data available. 13 - Disposal Considerations SUBSTANCE DISPOSAL Contact a licensed professional waste disposal service to dispose of this material. Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Observe all federal, state, and local environmental regulations. 14 - Transport Information RID/ADR UN#: 1993 Class: 3 PG: III Kemmler Number: 30 Proper Shipping Name: Flammable liquid, n.o.s. IMDG UN#: 1993 Class: 3 PG: III Proper Shipping Name: Flammable liquid, n.o.s. Marine Pollutant: No Severe Marine Pollutant: No Technical Name: Required IATA UN#: 1993 Class: 3 PG: III Proper Shipping Name: Flammable liquid, n.o.s. Inhalation Packing Group I: No Technical Name: Required 15 - Regulatory Information CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES R-PHRASES: 10 Flammable. S-PHRASES: 16 Keep away from sources of ignition - no smoking. 16 - Other Information WARRANTY The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any ALDRICHwww.molbase.com guarantee of the properties of the product. Inc., shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. Copyright 2010 Co. License granted to make unlimitedpaper copies for internal use only. DISCLAIMER For R&D use only. Not for drug, household or other uses. ALDRICHwww.molbase.com SECTION 16 - ADDITIONAL INFORMATION N/A |
