64091-14-1

• 常用中文名：TBS-科里内酯醛
• 常用英文名：TBS-Corey Lactone Aldehyde
• CAS号：64091-14-1
• 分子式：C₁₄H₂₄O₄Si
• 分子量：284.423
• 发布时间：2017-09-16 06:12:37
• 更新时间：2024-01-03 18:50:21

名称

• 中文名: TBS-科里内酯醛
• 英文名: 5-[tert-butyl(dimethyl)silyl]oxy-2-oxo-3,3a,4,5,6,6a-hexahydrocyclopenta[b]furan-4-carbaldehyde
• 英文别名: Corey-TBS aldehyde; (3aR,4S,5S,6aS)-5-{[Dimethyl(2-methyl-2-propanyl)silyl]oxy}-2-oxohexahydro-2H-cyclopenta[b]furan-4-carbaldehyde; 2H-Cyclopenta[b]furan-4-carboxaldehyde, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]hexahydro-2-oxo-, (3aR,4S,5S,6aS)-; TBS-COREY LACTONE ALDEHYDE; 2H-Cyclopenta[b]furan-4-carboxaldehyde, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]hexahydro-2-oxo-; 5-{[Dimethyl(2-methyl-2-propanyl)silyl]oxy}-2-oxohexahydro-2H-cyclopenta[b]furan-4-carbaldehyde

物化性质

• 密度: 1.1±0.1 g/cm3
• 沸点: 365.6±42.0 °C at 760 mmHg
• 分子式: C₁₄H₂₄O₄Si
• 分子量: 284.423
• 闪点: 145.3±23.4 °C
• 精确质量: 284.144379
• PSA: 52.60000
• LogP: 1.79
• 蒸汽压: 0.0±0.8 mmHg at 25°C
• 折射率: 1.476

合成路线

39968-95-1 ~% 64091-14-1

文献：Sheddan, Neil A.; Arion, Vladimir B.; Mulzer, Johann Tetrahedron Letters, 2006 , vol. 47, # 37 p. 6689 - 6693

101208-17-7 ~% 64091-14-1

文献：Sheddan, Neil A.; Arion, Vladimir B.; Mulzer, Johann Tetrahedron Letters, 2006 , vol. 47, # 37 p. 6689 - 6693

912445-64-8 ~% 64091-14-1

文献：Sheddan, Neil A.; Arion, Vladimir B.; Mulzer, Johann Tetrahedron Letters, 2006 , vol. 47, # 37 p. 6689 - 6693

39746-00-4 ~% 64091-14-1

文献：Sheddan, Neil A.; Arion, Vladimir B.; Mulzer, Johann Tetrahedron Letters, 2006 , vol. 47, # 37 p. 6689 - 6693

62939-85-9 ~% 64091-14-1

文献：Sheddan, Neil A.; Arion, Vladimir B.; Mulzer, Johann Tetrahedron Letters, 2006 , vol. 47, # 37 p. 6689 - 6693

上下游产品

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