21239-57-6

• 常用中文名：TETRACARBONYL(TRIFLUOROMETHYLTHIO)MANGANESE dimer
• 常用英文名：TETRACARBONYL(TRIFLUOROMETHYLTHIO)MANGANESE dimer
• CAS号：21239-57-6
• 分子式：C₁₀H₂F₆Mn₂O₈S₂
• 分子量：538.11500
• 发布时间：2017-11-08 21:56:12
• 更新时间：2024-01-29 11:07:22

名称

• 英文名: Manganese, tetracarbonyl(trifluoromethylthio)-, dimer

物化性质

• 分子式: C₁₀H₂F₆Mn₂O₈S₂
• 分子量: 538.11500
• 精确质量: 537.78600
• PSA: 77.60000
• LogP: 1.93520
• 蒸汽压: 6010mmHg at 25°C

毒性和生态

CHEMICAL IDENTIFICATION RTECS NUMBER : OP1325000 CHEMICAL NAME : Manganese, tetracarbonyl(trifluoromethylthio)-, dimer CAS REGISTRY NUMBER : 21239-57-6 LAST UPDATED : 199701 DATA ITEMS CITED : 19 MOLECULAR FORMULA : C10-F6-Mn2-O8-S2 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 180 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#07141 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:CL 5 mg(Mn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,149,1971 OSHA PEL (Gen Indu):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 5 mg(Mn)/m3 JAN 1993 OEL-BELGIUM:TWA 5 mg(Mn)/m3 JAN 1993 OEL-DENMARK:TWA 2.5 mg(Mn)/m3 JAN 1993 OEL-FINLAND:TWA 2.5 mg(Mn)/m3 JAN 1993 OEL-HUNGARY:TWA 0.3 mg(Mn)/m3;STEL 0.6 mg(Mn)/m3 JAN 1993 OEL-JAPAN:TWA 0.3 mg(Mn)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg(Mn)/m3 JAN 1993 OEL-POLAND:TWA 0.3 mg(Mn)/m3 JAN 1993 OEL-SWEDEN:TWA 1 mg(Mn)/m3;STEL 2.5 mg(Mn)/m3 (resp. dust) JAN 1993 OEL-SWEDEN:TWA 2.5 mg(Mn)/m3;STEL 5 mg(Mn)/m3 (total dust) JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg(Mn)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

合成路线

10170-69-1 372-64-5 ~87% 21239-57-6 50979-57-2

文献：Gmelin Handbook: F: PerFHalOrg.SVol.2, 6.2.1.6.5, page 172 - 209

35646-82-3 372-64-5 ~44% 21239-57-6 50979-57-2

文献：Gmelin Handbook: F: PerFHalOrg.SVol.2, 6.2.1.6.5, page 172 - 209

10170-69-1 4317-00-4 ~77% 21239-57-6

文献：Gmelin Handbook: F: PerFHalOrg.SVol.2, 6.2.1.6.3.1, page 85 - 99

421-17-0 10170-69-1 ~% 21239-57-6

文献：Gmelin Handbook: F: PerFHalOrg.1, 1.1.6.5.2, page 157 - 193

421-17-0 10170-69-1 ~% 21239-57-6 372-64-5

文献：Gmelin Handbook: F: PerFHalOrg.1, 1.1.6.5.2, page 157 - 193

上下游产品

上游产品  5
10170-69-1 372-64-5 35646-82-3 4317-00-4
421-17-0
下游产品  0