2528-36-1

• 常用中文名：磷酸二丁基苯基脂
• 常用英文名：Dibutyl phenyl phosphate
• CAS号：2528-36-1
• 分子式：C₁₄H₂₃O₄P
• 分子量：286.304
• 发布时间：2018-02-15 08:00:00
• 更新时间：2025-08-20 07:05:40

名称

• 中文名: 磷酸二丁基苯基脂
• 英文名: dibutyl phenyl phosphate
• 英文别名: Phosphoric acid, dibutyl phenyl ester; Phosphoric acid,dibutyl phenyl ester; Di(n-butyl) phenyl phosphate; Dibutyl-phenyl-phosphat; dibutylphenyl phosphate; Dibutyl phenyl phosphate; EINECS 219-772-7; phosphoric acid dibutyl ester-phenyl ester; Phosphorsaeure-dibutylester-phenylester; O,o-dibutyl-O-phenyl phosphate

物化性质

• 密度: 1.1±0.1 g/cm3
• 沸点: 333.3±15.0 °C at 760 mmHg
• 分子式: C₁₄H₂₃O₄P
• 分子量: 286.304
• 闪点: 169.1±40.7 °C
• 精确质量: 286.133392
• PSA: 54.57000
• LogP: 4.41
• 蒸汽压: 0.0±0.7 mmHg at 25°C
• 折射率: 1.482

毒性和生态

CHEMICAL IDENTIFICATION RTECS NUMBER : TB9626600 CHEMICAL NAME : Phosphoric acid, dibutyl phenyl ester CAS REGISTRY NUMBER : 2528-36-1 BEILSTEIN REFERENCE NO. : 2140519 LAST UPDATED : 199712 DATA ITEMS CITED : 18 MOLECULAR FORMULA : C14-H23-O4-P MOLECULAR WEIGHT : 286.34 WISWESSER LINE NOTATION : 4OPO&O4&OR HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 2140 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(4),46,1981 TYPE OF TEST : LC - Lethal concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : >7 mg/m3 TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(4),46,1981 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 1790 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(4),46,1981 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : >5 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 41,291,1977 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Bird - chicken DOSE/DURATION : 2030 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : TSCAT* Office of Toxic Substances Report. (U.S. Environmental Protection Agency, Office of Toxic Substances, 401 M St., SW, Washington, DC 20460) Volume(issue)/page/year: OTS 206227 ** OTHER MULTIPLE DOSE TOXICITY DATA ** TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 22750 mg/kg/91D-C TOXIC EFFECTS : Liver - changes in liver weight Blood - changes in erythrocyte (RBC) count Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase REFERENCE : FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 16,117,1991 TYPE OF TEST : TCLo - Lowest published toxic concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 6 mg/m3/17W-I TOXIC EFFECTS : Brain and Coverings - recordings from specific areas of CNS Cardiac - changes in heart weight Nutritional and Gross Metabolic - weight loss or decreased weight gain REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(4),46,1981 ** REPRODUCTIVE DATA ** TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral DOSE : 48 gm/kg SEX/DURATION : male 10 week(s) pre-mating female 10 day(s) pre-mating - 3 week(s) post-birth TOXIC EFFECTS : Reproductive - Effects on Newborn - viability index (e.g., # alive at day 4 per # born alive) Reproductive - Effects on Newborn - weaning or lactation index (e.g., # alive at weaning per # alive at day 4) Reproductive - Effects on Newborn - physical REFERENCE : FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 16,117,1991 *** REVIEWS *** ACGIH TLV-TWA 3.5 mg/m3 (0.3 ppm) (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 0.1 mg/m3;Skin JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M3288 No. of Facilities: 35 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 210 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M3288 No. of Facilities: 314 (estimated) No. of Industries: 7 No. of Occupations: 23 No. of Employees: 26747 (estimated) No. of Female Employees: 266 (estimated)

安全

• 海关编码: 2919900090

合成路线

1809-19-4 108-95-2 ~93% 2528-36-1

文献：Batra; Purnanand Indian Journal of Chemistry - Section B Organic Chemistry Including Medicinal Chemistry, 1991 , vol. 30, # 1 p. 57 - 58

3266-57-7 ~% 2528-36-1

文献：GB398659 , ;

770-12-7 71-36-3 ~% 2528-36-1

文献：US1869768 , ; DE566514 , ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 19, p. 668

819-43-2 ~% 2528-36-1

文献：Journal of the American Chemical Society, , vol. 80, p. 727,729

10359-36-1 ~% 2528-36-1 48168-03-2 113303-26-7 详细

文献：Journal of Organic Chemistry, , vol. 53, # 9 p. 2009 - 2011

108-95-2 819-43-2 ~% 2528-36-1

文献：GB328963 , ; US1844408 , ;

4124-92-9 ~% 2528-36-1

文献：GB398659 , ;

139-02-6 ~% 2528-36-1

文献：GB398659 , ;

3266-57-7 7446-11-9 ~% 2528-36-1

文献：GB398659 , ;

上下游产品

上游产品  9
1809-19-4 108-95-2 3266-57-7 770-12-7
71-36-3 819-43-2 10359-36-1 139-02-6
7446-11-9
下游产品  1
107-66-4

海关

海关编码	2919900090
中文概述	HS:2919900090 其他磷酸酯及其盐（包括乳磷酸盐）（包括它们的卤化，磺化，硝化和亚硝化衍生物） 增值税率:17.0% 退税率:9.0% 监管条件:AB(入境货物通关单,出境货物通关单) 最惠国关税:6.5% 普通关税:30.0%
申报要素	品名, 成分含量, 用途
监管条件	A.入境货物通关单 B.出境货物通关单
检验检疫	R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验
Summary	2919900090 other phosphoric esters and their salts, including lactophosphates; their halogenated, sulphonated, nitrated or nitrosated derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%