2-(叔丁基二甲基甲硅烷基)-1,3-二噻烷

2-(叔丁基二甲基甲硅烷基)-1,3-二噻烷名称

[ CAS 号 ]:
95452-06-5

[ 中文名 ]:
2-(叔丁基二甲基甲硅烷基)-1,3-二噻烷

[ 英文名 ]:
2-(TERT-BUTYLDIMETHYLSILYL)-1,3-DITHIANE

[中文别名 ]:

2-(叔丁基二甲基甲硅烷基)-1,3-二硫烷

[英文别名 ]:

2-TBS-1,3-dithiane
TBS-1,3-dithiane
2-(tert-butyldimethylsilyl)-1,3-dithiane
1-tert-butyldimethylsilyl(1,3)dithiane
2-TBS-1,3-dithinane
MFCD02093667
tert-butyl(1,3-dithian-2-yl)dimethylsilane
t-Butyl[1,3]dithian-2-yldimethylsilane

2-(叔丁基二甲基甲硅烷基)-1,3-二噻烷物理化学性质

[ 密度 ]:
1.01 g/mL at 25ºC(lit.)

[ 沸点 ]:
124ºC5 mm Hg(lit.)

[ 分子式 ]:
C₁₀H₂₂S₂Si

[ 分子量 ]:
234.49700

[ 闪点 ]:
221 °F

[ 精确质量 ]:
234.09300

[ PSA ]:
50.60000

[ LogP ]:
4.65020

[ 折射率 ]:
n20/D 1.531(lit.)

2-(叔丁基二甲基甲硅烷基)-1,3-二噻烷安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ 海关编码 ]:
2934999090

2-(叔丁基二甲基甲硅烷基)-1,3-二噻烷海关

[ 海关编码 ]: 2934999090

[ 中文概述 ]:
2934999090. 其他杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

2-(叔丁基二甲基甲硅烷基)-1,3-二噻烷文献

Multicomponent linchpin couplings of silyl dithianes: synthesis of the Schreiber C(16-28) trisacetonide subtarget for mycoticins A and B.

Org. Lett. 1(12) , 2001-4, (1999)

[formula: see text] An efficient synthesis of trisacetonide (+)-11, the Schreiber C(16-28) subtarget for mycoticins A and B, is described. The key synthetic transformation entails a one-flask, five-co...

A general, convergent strategy for the construction of indolizidine alkaloids: total syntheses of (-)-indolizidine 223AB and alkaloid (-)-205B.

J. Org. Chem. 71 , 2547, (2006)

N-Toluenesulfonyl aziridines comprise effective second electrophiles in the solvent controlled three-component linchpin union of silyl dithianes for the stereocontrolled convergent elaboration of prot...

Total synthesis of the neotropical poison-frog alkaloid (-)-205B.

Org. Lett. 7 , 3247, (2005)

[reaction: see text]. A stereocontrolled total synthesis of the neotropical poison-frog alkaloid (-)-205B (1) has been achieved, employing a dithiane three-component linchpin coupling, a one-pot seque...

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