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4-苯基苯甲酸

4-苯基苯甲酸用途

【用途一】
用于有机合成
【用途二】
该品为极谱分析试剂，也是有机合成的中间体。

4-苯基苯甲酸名称

[ CAS 号 ]:
92-92-2

[ 中文名 ]:
4-苯基苯甲酸

[ 英文名 ]:
4-Biphenylcarboxylic acid

[中文别名 ]:

[英文别名 ]:

[1,1'-Biphenyl]-4-carboxylic acid
Biphenyl-4-carboxylic acid
p-Phenylbenzoic Acid
4-Phenylbenzic acid
4-Carboxybiphenyl
PHENYLBENZOICACID
EINECS 202-203-1
RARECHEM AL BO 0062
4-phenyl benzoic acid
4-Biphenylcarboxylic

4-苯基苯甲酸物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
372.6±21.0 °C at 760 mmHg

[ 熔点 ]:
220-225 °C(lit.)

[ 分子式 ]:
C₁₃H₁₀O₂

[ 分子量 ]:
198.217

[ 闪点 ]:
170.0±16.7 °C

[ 精确质量 ]:
198.068085

[ PSA ]:
37.30000

[ LogP ]:
3.75

[ 外观性状 ]:
略米色粉末

[ 蒸汽压 ]:
0.0±0.9 mmHg at 25°C

[ 折射率 ]:
1.607

[ 储存条件 ]:
Room temperature.

[ 水溶解性 ]:
水溶性：实际上不溶；可溶于：乙醚,苯,乙醇

4-苯基苯甲酸MSDS

4-苯基苯甲酸毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DV1925100

CHEMICAL NAME :: 4-Biphenylcarboxylic acid

CAS REGISTRY NUMBER :: 92-92-2

BEILSTEIN REFERENCE NO. :: 0973519

LAST UPDATED :: 199701

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C13-H10-O2

MOLECULAR WEIGHT :: 198.23

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

DOSE :: 1 gm/kg

SEX/DURATION :: female 7-16 day(s) after conception

TOXIC EFFECTS :: Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) Reproductive - Effects on Embryo or Fetus - fetal death Reproductive - Specific Developmental Abnormalities - body wall

REFERENCE :: TJADAB Teratology, The International Journal of Abnormal Development. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.1- 1968- Volume(issue)/page/year: 39,537,1989

4-苯基苯甲酸安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302-H319

[ 警示性声明 ]:
P301 + P312 + P330-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S37/39-S26

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
1

[ RTECS号 ]:
DV1925100

[ 海关编码 ]:
29163900

4-苯基苯甲酸合成路线

4-苯基苯甲酸上下游产品

4-苯基苯甲酸上游产品

4-苯基苯甲酸下游产品

4-苯基苯甲酸制备

由联苯与氯乙酰反应后用高锰酸钾氧化而得。将联苯溶解在苯中，搅拌下缓缓加入无水三氯化铝，在微沸情况下滴加氯乙酰。加毕，继续保温搅拌2h。回收苯至尽，趁热将反应物倒入冰水中结晶。取结晶与高锰酸钾于90℃以下反应，过滤，用盐酸中和至pH为2，得粗品。再经乙醇重结晶、酸碱沉淀精制得到4-苯基苯甲酸。

4-苯基苯甲酸海关

[ 海关编码 ]: 2916399090

[ 中文概述 ]:
2916399090 其他芳香一元羧酸. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

4-苯基苯甲酸文献

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Eur. J. Med. Chem. 43 , 478-85, (2008)

Values of in vitro gas to lung partition coefficients, K(lung), of VOCs have been collected from the literature. For 44 VOCs, application of the Abraham solvation equation to log K(lung) yielded a cor...

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J. Colloid. Interface Sci. 456 , 182-9, (2015)

The incorporation of gold nanoparticles in heterojunction solar cells is expected to increase the efficiency due to plasmon effects, but the literature studies are sometimes controversial. In this wor...

Predicting human serum albumin affinity of interleukin-8 (CXCL8) inhibitors by 3D-QSPR approach.

J. Med. Chem. 48 , 2469-79, (2005)

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