菲醌

菲醌用途

【用途一】
菲醌本身是农药，可以用作杀菌剂、拌种剂、电子照相，可用作光导材料、光敏阻焊剂和纸张防腐剂。
【用途二】
菲醌用于有机合成，可用来生产苯绕蒽酮。菲醌具有抑菌能力，用于拌种可防止谷物黑穗病、棉花苗期病，还可作为纸浆防腐剂。经氢氧化钠处理后可制得多效能的植物生长调节剂整形素。

菲醌名称

[ CAS 号 ]:
84-11-7

[ 中文名 ]:
菲醌

[ 英文名 ]:
Phenanthrene-9,10-dione

[中文别名 ]:

[英文别名 ]:

Phenanthrenequinone
MFCD00001163
9,10-phenanthraquinone
9,10-Phenanthrenedione
phenanthrene-9,10-dione
EINECS 201-515-5
9,10-Phenanthrenequinone

菲醌物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
360.0±0.0 °C at 760 mmHg

[ 熔点 ]:
209-212 °C(lit.)

[ 分子式 ]:
C₁₄H₈O₂

[ 分子量 ]:
208.212

[ 闪点 ]:
163.1±4.4 °C

[ 精确质量 ]:
208.052429

[ PSA ]:
34.14000

[ LogP ]:
3.13

[ 外观性状 ]:
黄色晶体粉末

[ 蒸汽压 ]:
0.0±0.8 mmHg at 25°C

[ 折射率 ]:
1.659

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

[ 稳定性 ]:
Stable. Incompatible with strong oxidizing agents.

菲醌MSDS

菲醌毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: SF7875000

CHEMICAL NAME :: Phenanthrenequinone

CAS REGISTRY NUMBER :: 84-11-7

BEILSTEIN REFERENCE NO. :: 0608838

LAST UPDATED :: 199710

DATA ITEMS CITED :: 8

MOLECULAR FORMULA :: C14-H8-O2

MOLECULAR WEIGHT :: 208.22

WISWESSER LINE NOTATION :: L B666 HVVJ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 165 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 800 mg/kg/29W-C

TOXIC EFFECTS :: Tumorigenic - equivocal tumorigenic agent by RTECS criteria Skin and Appendages - tumors Tumorigenic - tumors at site of application

MUTATION DATA

TYPE OF TEST :: DNA repair

TEST SYSTEM :: Bacteria - Bacillus subtilis

DOSE/DURATION :: 400 ug/plate

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 66,337,1979 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5889 No. of Facilities: 306 (estimated) No. of Industries: 4 No. of Occupations: 4 No. of Employees: 3675 (estimated) No. of Female Employees: 632 (estimated)

菲醌安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36-S24/25-S22

[ 危险品运输编码 ]:
UN3077

[ WGK德国 ]:
3

[ RTECS号 ]:
SF7875000

[ 包装等级 ]:
III

[ 危险类别 ]:
9

[ 海关编码 ]:
29146990

菲醌合成路线

菲醌上下游产品

菲醌上游产品

菲醌下游产品

菲醌制备

由菲氧化制成，有化学法及电解法。1.化学法用重铬酸钠（或钾）与菲在硫酸水溶液中氧化。2.电解氧化法电解液含三氧化铬120g/L、硫酸450g/L，含菲35g/L。阴极电流密度3.75A/cm2，电解液温度60-65℃，经电解8h后，过滤，得产品。

菲醌海关

[ 海关编码 ]: 2914399090

[ 中文概述 ]:
2914399090. 其他不含其他含氧基的芳香酮. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装

[ Summary ]:
2914399090. other aromatic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

菲醌文献

Fluorescence Titrations of Bio-relevant Complexes with DNA: Synthesis, Structural Investigation, DNA Binding/Cleavage, Antimicrobial and Molecular Docking Studies.

J. Fluoresc. 25 , 1127-40, (2015)

In the present work, we attempted to develop new metal complexes (Cu(II), Co(II), Ni(II) and Zn(II)) of the imine ligand which was synthesized from 9,10-phenanthrenequinone and para-anisidine. With an...

Sulfa drugs inhibit sepiapterin reduction and chemical redox cycling by sepiapterin reductase.

J. Pharmacol. Exp. Ther. 352(3) , 529-40, (2015)

Sepiapterin reductase (SPR) catalyzes the reduction of sepiapterin to dihydrobiopterin (BH2), the precursor for tetrahydrobiopterin (BH4), a cofactor critical for nitric oxide biosynthesis and alkylgl...

3-Deoxyglucosone: a potential glycating agent accountable for structural alteration in H3 histone protein through generation of different AGEs.

PLoS ONE 10(2) , e0116804, (2015)

Advanced glycation end-products (AGEs) are heterogeneous group of compounds, known to be implicated in diabetic complications. One of the consequences of the Maillard reaction is attributed to the pro...

更多文献

菲醌