氟化钡
氟化钡用途
用于电子、仪表、冶金工业、防腐剂
【用途二】
用于制造电机电刷、光学玻璃、光导纤维、激光发生器、助熔剂、涂料和珐琅以及木材防腐剂和杀虫剂等
【用途三】
用于制造电机电刷、光学玻璃、光导纤维、激光发生器、助熔剂、涂料及珐琅。用作木材防腐剂及杀虫剂。
【用途四】
防腐剂。金属热处理。陶瓷。搪瓷。制造玻璃。冶金。仪表等工业。
氟化钡名称
[ CAS 号 ]:
7787-32-8
[ 中文名 ]:
氟化钡
[ 英文名 ]:
Barium fluoride
[英文别名 ]:
- MFCD00003450
- EINECS 232-108-0
- barium(2+),difluoride
氟化钡物理化学性质
[ 密度 ]:
4.89
[ 沸点 ]:
2260ºC
[ 熔点 ]:
1354ºC
[ 分子式 ]:
BaF2
[ 分子量 ]:
175.32400
[ 闪点 ]:
2260ºC
[ 精确质量 ]:
175.90200
[ LogP ]:
0.84040
[ 外观性状 ]:
无色无臭晶体
[ 折射率 ]:
1.4741
[ 储存条件 ]:
库房通风低温干燥,与食品分开储运
[ 稳定性 ]:
Stable. Incompatible with acids.
[ 水溶解性 ]:
1.6 g/L (20 ºC)
氟化钡MSDS
氟化钡毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- CQ9100000
- CHEMICAL NAME :
- Barium fluoride
- CAS REGISTRY NUMBER :
- 7787-32-8
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 55
- MOLECULAR FORMULA :
- Ba-F2
- MOLECULAR WEIGHT :
- 175.34
- WISWESSER LINE NOTATION :
- BA F2
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 250 mg/kg
- TOXIC EFFECTS :
- Behavioral - somnolence (general depressed activity) Behavioral - ataxia Lungs, Thorax, or Respiration - respiratory depression
- REFERENCE :
- VAMNAQ Vestnik Akademii Meditsinskikh Nauk SSSR. Journal of the Academy of Medical Sciences of the USSR. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1946- Volume(issue)/page/year: (2),28,1977
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 29910 ug/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- DZZEA7 Deutsche Zahnaerztliche Zeitschrift. (Carl Hanser Verlag, Postfach 860420, D-8000 Munich 86, Fed. Rep. Ger.) V.1- 1946- Volume(issue)/page/year: 34,484,1979
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Amphibian - frog
- DOSE/DURATION :
- 1540 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- CRSBAW Comptes Rendus des Seances de la Societe de Biologie et de Ses Filiales. (SPPIF, B.P.22, F-41353 Vineuil, France) V.1- 1849- Volume(issue)/page/year: 124,133,1937 ** OTHER MULTIPLE DOSE TOXICITY DATA **
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 5660 ug/m3/4H/17W-I
- TOXIC EFFECTS :
- Kidney, Ureter, Bladder - other changes in urine composition Blood - normocytic anemia Nutritional and Gross Metabolic - weight loss or decreased weight gain
- REFERENCE :
- GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 22(5),34,1978 ** REPRODUCTIVE DATA **
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- DOSE :
- 5660 ug/m3/24H
- SEX/DURATION :
- female 1-21 day(s) after conception
- TOXIC EFFECTS :
- Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) Reproductive - Effects on Embryo or Fetus - fetal death
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 41(2),109,1976
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Intraperitoneal
- DOSE :
- 525 mg/kg
- SEX/DURATION :
- female 1-21 day(s) after conception
- TOXIC EFFECTS :
- Reproductive - Specific Developmental Abnormalities - other developmental abnormalities
- REFERENCE :
- DZZEA7 Deutsche Zahnaerztliche Zeitschrift. (Carl Hanser Verlag, Postfach 860420, D-8000 Munich 86, Fed. Rep. Ger.) V.1- 1946- Volume(issue)/page/year: 34,484,1979
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Intraperitoneal
- DOSE :
- 656 mg/kg
- SEX/DURATION :
- female 1-21 day(s) after conception
- REFERENCE :
- DZZEA7 Deutsche Zahnaerztliche Zeitschrift. (Carl Hanser Verlag, Postfach 860420, D-8000 Munich 86, Fed. Rep. Ger.) V.1- 1946- Volume(issue)/page/year: 34,484,1979 *** REVIEWS *** ACGIH TLV-TWA 0.5 mg(Ba)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 2.5 mg(F)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 TOXICOLOGY REVIEW AMSSAQ Acta Medica Scandinavica, Supplement. (Almqvist & Wiksell, POB 45150, S-10430 Stockholm, Sweden) No.1-730, 1921-88. Volume(issue)/page/year: 400,5,1963 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.5 mg(Ba)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,21,1971 OSHA PEL (Gen Indu):8H TWA 0.5 mg(Ba)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Gen Indu):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.5 mg(Ba)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Construc):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.5 mg(Ba)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Shipyard):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.5 mg(Ba)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 OSHA PEL (Fed Cont):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 0.5 mg(Ba)/m3 JAN 1993 OEL-AUSTRALIA:TWA 2.5 mg(F)/m3 JAN 1993 OEL-AUSTRIA:TWA 0.5 mg(Ba)/m3 JAN 1993 OEL-BELGIUM:TWA 0.5 mg(Ba)/m3 JAN 1993 OEL-BELGIUM:TWA 2.5 mg(F)/m3 JAN 1993 OEL-DENMARK:TWA 0.5 mg(Ba)/m3 JAN 1993 OEL-DENMARK:TWA 2.5 mg(F)/m3 JAN 1993 OEL-FINLAND:TWA 0.5 mg(Ba)/m3 JAN 1993 OEL-FINLAND:TWA 2.5 mg(F)/m3 JAN 1993 OEL-FRANCE:TWA 2.5 mg(F)/m3 JAN 1993 OEL-GERMANY:TWA 0.5 mg(Ba)/m3 (total dust) JAN 1993 OEL-GERMANY:TWA 2.5 mg(F)/m3 JAN 1993 OEL-HUNGARY:STEL 0.5 mg(Ba)/m3 JAN 1993 OEL-HUNGARY:TWA 1 mg(F)/m3;STEL 2 mg(F)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.5 mg(Ba)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 2.5 mg(F)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.5 mg(Ba)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 2.5 mg(F)/m3 JAN 1993 OEL-POLAND:TWA 0.5 mg(Ba)/m3;STEL 1.5 mg(Ba)/m3 JAN 1993 OEL-POLAND:TWA 1 mg(F)/m3 JAN 1993 OEL-RUSSIA:STEL 0.1 mg/m3 JAN 1993 OEL-SWEDEN:TWA 2 mg(F)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.5 mg(Ba)/m3;STEL 1 mg(Ba)/m3 JAN 1993 OEL-SWITZERLAND:TWA 1.8 ppm (1.5 mg(F)/m3);STEL 9.0 ppm JAN 1993 OEL-THAILAND:TWA 2.5 mg(F)/m3 JAN 1993 OEL-TURKEY:TWA 0.5 mg(Ba)/m3 JAN 1993 OEL-TURKEY:TWA 2.5 mg(F)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.5 mg(Ba)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 2.5 mg(F)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO FLUORIDES, INORGANIC-air:10H TWA 2.5 mg(F)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M3299 No. of Facilities: 223 (estimated) No. of Industries: 6 No. of Occupations: 6 No. of Employees: 1061 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M3299 No. of Facilities: 1341 (estimated) No. of Industries: 31 No. of Occupations: 14 No. of Employees: 14859 (estimated) No. of Female Employees: 837 (estimated)
氟化钡安全信息
[ 符号 ]:
GHS06
[ 信号词 ]:
Danger
[ 危害声明 ]:
H301-H332
[ 警示性声明 ]:
Missing Phrase - N15.00950417-P261
[ 危害码 (欧洲) ]:
Xn:Harmful
[ 风险声明 (欧洲) ]:
R20/22
[ 安全声明 (欧洲) ]:
S28
[ 危险品运输编码 ]:
UN 2811
[ WGK德国 ]:
1
[ RTECS号 ]:
CQ9100000
[ 包装等级 ]:
III
[ 危险类别 ]:
6.1
氟化钡制备
1.将碳酸钡与水搁成浆菠,加人氢氟酸进行反应,控制反应终点Ph值,并保持不变为止。产物经过滤、干燥、粉碎,即为氟化钡成品。其反应方程式如下:
2.将过量的氢氟酸装入铂皿中,一点点地加入计算量的碳酸钡,用文火加热至不再发生CO2为止。用倾析法反复水洗,将沉淀过滤,蒸发至干。往其中再加少量HF,直到不再有CO2放出。再蒸发至干。为除去HF,将沉淀置于铂皿中于惰性气体中加热至熔融,即可制得纯净的氟化钡。
也可用与制备氟化钙的方法:用碳酸钡与氟化铵或氟氢化铵加热而制取。
3.碳酸钡溶于过量氢氟酸中进行反应,经脱水、干燥、粉碎,制得成品。其反应式如下。
氟化钡文献
Biol. Trace Elem. Res. 167 , 84-90, (2015)
Various fluoride compounds are widely used in industry. The present risk assessment study was conducted using a series of inorganic binary fluorides of the type XFn, where X(n) = Na(+), K(+), Li(+), M...
Hybrid BaYbF(5) nanoparticles: novel binary contrast agent for high-resolution in vivo X-ray computed tomography angiography.Adv. Healthc. Mater. 1(4) , 461-6, (2012)
A novel CT contrast agent denoted as BaYbF(5) @SiO(2) @PEG is presented. The as-prepared nanoparticles exhibit significantly enhanced contrast efficacy relative to clinical iodinated agents and mainta...
Studies of EPR spectra and defect structure for Er³⁺ ions in BaF₂ and SrF₂ crystals.Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 102 , 169-74, (2013)
The local lattice structure and electron paramagnetic resonance (EPR) spectra have been studied systematically by diagonalizing 364 × 364 complete energy matrices for a f(11) ion in a trigonal ligand-...
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相关化合物
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标题:氟化钡_MSDS_用途_密度_氟化钡CAS号【7787-32-8】_化源网 地址:https://www.chemsrc.com/amp/cas/7787-32-8_1042152.html