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2,2,3,3-四氟丙醇

2,2,3,3-四氟丙醇用途

【用途一】
用作医药、农药中间体，光盘涂料溶剂，清洗剂等

2,2,3,3-四氟丙醇名称

[ CAS 号 ]:
76-37-9

[ 中文名 ]:
2,2,3,3-四氟丙醇

[ 英文名 ]:
2,2,3,3-Tetrafluoro-1-propanol

[中文别名 ]:

[英文别名 ]:

1-Propanol, 2,2,3,3-tetrafluoro-
EINECS 200-955-5
2,2,3,3-Tetrafluoro-1-propanol
2,2,3,3-Tetrafluoro-1-propanol/TFP
2,2,3,3-tetrafluoropropan-1-ol
MFCD00004676

2,2,3,3-四氟丙醇物理化学性质

[ 密度 ]:
1.4±0.1 g/cm3

[ 沸点 ]:
109.5±0.0 °C at 760 mmHg

[ 熔点 ]:
-15°C

[ 分子式 ]:
C₃H₄F₄O

[ 分子量 ]:
132.057

[ 闪点 ]:
31.0±25.9 °C

[ 精确质量 ]:
132.019821

[ PSA ]:
20.23000

[ LogP ]:
0.30

[ 外观性状 ]:
无色液体

[ 蒸汽压 ]:
13.1±0.4 mmHg at 25°C

[ 折射率 ]:
1.296

[ 储存条件 ]:
Flammables area

[ 稳定性 ]:
Stable. Flammable. Incompatible with strong oxidizing agents, strong bases, sodium, potassium, acid chlorides, acid anhydrides.

2,2,3,3-四氟丙醇MSDS

2,2,3,3-四氟丙醇毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: UB9400000

CHEMICAL NAME :: 1-Propanol, 2,2,3,3-tetrafluoro-

CAS REGISTRY NUMBER :: 76-37-9

BEILSTEIN REFERENCE NO. :: 1738264

LAST UPDATED :: 199701

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C3-H4-F4-O

MOLECULAR WEIGHT :: 132.07

WISWESSER LINE NOTATION :: Q1XFFYFF

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3400 mg/kg

TOXIC EFFECTS :: Behavioral - general anesthetic Lungs, Thorax, or Respiration - other changes Gastrointestinal - other changes

REFERENCE :: JOCMA7 Journal of Occupational Medicine. (Chicago, IL) V.1-9, 1957-67. For publisher information, see:JJOMDZ Volume(issue)/page/year: 4,262,1962

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2000 ppm/4H

TOXIC EFFECTS :: Behavioral - general anesthetic Behavioral - somnolence (general depressed activity) Behavioral - muscle weakness

REFERENCE :: JOCMA7 Journal of Occupational Medicine. (Chicago, IL) V.1-9, 1957-67. For publisher information, see:JJOMDZ Volume(issue)/page/year: 4,262,1962

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 8600 mg/m3/2H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,109,1982

2,2,3,3-四氟丙醇安全信息

[ 符号 ]:

GHS02, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H226-H319-H331

[ 警示性声明 ]:
P261-P305 + P351 + P338-P311

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xn:Harmful

[ 风险声明 (欧洲) ]:
R10;R20;R36/37/38

[ 安全声明 (欧洲) ]:
S26-S37/39-S16

[ 危险品运输编码 ]:
UN 1986 3/PG 3

[ WGK德国 ]:
1

[ RTECS号 ]:
UB9400000

[ 包装等级 ]:
III

[ 危险类别 ]:
3

[ 海关编码 ]:
2905590090

2,2,3,3-四氟丙醇合成路线

2,2,3,3-四氟丙醇上下游产品

2,2,3,3-四氟丙醇上游产品

2,2,3,3-四氟丙醇下游产品

2,2,3,3-四氟丙醇海关

[ 海关编码 ]: 2905590090

[ 中文概述 ]:
2905590090 其他无环醇的卤化、磺化等衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 包装

[ Summary ]:
2905590090 other halogenated, sulphonated, nitrated or nitrosated derivatives of acyclic alcohols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

2,2,3,3-四氟丙醇文献

Supercritical CO2 desorption of activated carbon loaded with 2,2,3,3-tetrafluoro-1-propanol in a rotating packed bed.

Environ. Sci. Technol. 42(6) , 2150-4, (2008)

Desorption of activated carbon loaded with 2,2,3,3-tetrafluoro-1-propanol (TFP) by supercritical carbon dioxide in a rotating packed bed was investigated in this study. The experimental data show that...

Mineralization and defluoridation of 2,2,3,3-tetrafluoro -1-propanol (TFP) by UV oxidation in a novel three-phase fluidized bed reactor (3P-FBR).

Water Res. 47(7) , 2325-30, (2013)

2,2,3,3-Tetrafluoro-1-propanol (TFP, C3H4F4O, M.W. = 132.06) is extensively used as the solvent in CD-R and DVD-R fabrication. Since it has a fluorinated alky-chain configuration and is non-biodegrada...

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