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顺式-3-己烯醇 2-甲基-2-丁烯酸酯

顺式-3-己烯醇 2-甲基-2-丁烯酸酯用途

用于配制蔬果香精，提调增加其新鲜感，也可用于配制烟用香精。产品质量：含量97％以上。

顺式-3-己烯醇 2-甲基-2-丁烯酸酯名称

[ CAS 号 ]:
67883-79-8

[ 中文名 ]:
惕各酸叶醇酯

[ 英文名 ]:
(Z)-3-Hexenyl tiglate

[中文别名 ]:

[英文别名 ]:

cis-3-Hexenyl-tiglat
CIS-3-HEXEN-1-YL TIGLATE
Tiglic acid 3-hexen-1-yl ester
HEXENYL-CIS-3-TIGLATE
cis-Hex-3-ene-1-yl trans-2-methyl-2-butenoate
MFCD00036528
(Z,Z)-3-hexenyl 2-methyl-2-butenoate
(Z)-3-Hexenyl tiglate
EINECS 267-554-5
(3Z)-Hex-3-en-1-yl (2E)-2-methylbut-2-enoate

顺式-3-己烯醇 2-甲基-2-丁烯酸酯物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
244.3±19.0 °C at 760 mmHg

[ 分子式 ]:
C₁₁H₁₈O₂

[ 分子量 ]:
182.259

[ 闪点 ]:
106.2±12.6 °C

[ 精确质量 ]:
182.130676

[ PSA ]:
26.30000

[ LogP ]:
4.20

[ 外观性状 ]:
淡黄色液体,植物芳香

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.458

[ 储存条件 ]:
室温

顺式-3-己烯醇 2-甲基-2-丁烯酸酯MSDS

详细MSDS(安全技术说明书)

顺式-3-己烯醇 2-甲基-2-丁烯酸酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: EM9253500

CHEMICAL NAME :: 2-Butenoic acid, 2-methyl-, 3-hexenyl ester, (E,Z)-

CAS REGISTRY NUMBER :: 67883-79-8

LAST UPDATED :: 199701

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C11-H18-O2

MOLECULAR WEIGHT :: 182.29

WISWESSER LINE NOTATION :: 3U3OVY1&U2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 17,809,1979 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 17,809,1979

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 17,809,1979 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X7451 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 5 No. of Employees: 1557 (estimated) No. of Female Employees: 276 (estimated)

顺式-3-己烯醇 2-甲基-2-丁烯酸酯安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315

[ 个人防护装备 ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 风险声明 (欧洲) ]:
R38

[ 安全声明 (欧洲) ]:
S37

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
2

[ RTECS号 ]:
EM9253500

[ 海关编码 ]:
2916190090

顺式-3-己烯醇 2-甲基-2-丁烯酸酯制备

叶醇与惕恪酸再加入催化剂及苯共沸剂，回流脱水，酯化生成所需产物。

顺式-3-己烯醇 2-甲基-2-丁烯酸酯海关

[ 海关编码 ]: 2916190090

[ 中文概述 ]:
2916190090 其他不饱和无环一元羧酸（包括其酸酐、酰卤化物，过氧化物和过氧酸以及它们的衍生物）。监管条件:AB(入境货物通关单,出境货物通关单)。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验

[ Summary ]:
2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

顺式-3-己烯醇 2-甲基-2-丁烯酸酯文献

Mosciano, G.

Perfum. Flavor. 5th ed., 25 , 78, (2000)

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