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反式-BETA-苯乙烯硼酸

反式-BETA-苯乙烯硼酸名称

[ CAS 号 ]:
6783-05-7

[ 中文名 ]:
反式-BETA-苯乙烯硼酸

[ 英文名 ]:
styrylboronic acid

[中文别名 ]:

[英文别名 ]:

TRANS-B-STYRENEBORONIC ACID
[(E)-2-Phenylvinyl]boronic acid
trans-2-styrylboronic acid
TRANS-PHENYLVINYLBORONIC ACID
MFCD00963621
trans-styreneboronic acid
styrylboronic acid
trans-phenylethenyl boronic acid
dihydroxy-(E)-styrylborane
TRANS-2-PHENYLVINYLBORONIC ACID

反式-BETA-苯乙烯硼酸物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
315.9±35.0 °C at 760 mmHg

[ 熔点 ]:
146-156 °C(lit.)

[ 分子式 ]:
C₈H₉BO₂

[ 分子量 ]:
147.967

[ 闪点 ]:
144.9±25.9 °C

[ 精确质量 ]:
148.069565

[ PSA ]:
40.46000

[ LogP ]:
2.57

[ 外观性状 ]:
棕色粒状的粉末

[ 蒸汽压 ]:
0.0±0.7 mmHg at 25°C

[ 折射率 ]:
1.587

[ 储存条件 ]:
0-6°C

反式-BETA-苯乙烯硼酸MSDS

反式-BETA-苯乙烯硼酸安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xi

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S37/39-S26

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ 海关编码 ]:
2931900090

反式-BETA-苯乙烯硼酸合成路线

反式-BETA-苯乙烯硼酸上下游产品

反式-BETA-苯乙烯硼酸上游产品

反式-BETA-苯乙烯硼酸下游产品

反式-BETA-苯乙烯硼酸海关

[ 海关编码 ]: 2931900090

[ 中文概述 ]:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

反式-BETA-苯乙烯硼酸文献

Rh2(II)-catalyzed intramolecular aliphatic C-H bond amination reactions using aryl azides as the N-atom source.

J. Am. Chem. Soc. 17th ed., 134 , 7262-7265, (2012)

Rhodium(II) dicarboxylate complexes were discovered to catalyze the intramolecular amination of unactivated primary, secondary, or tertiary aliphatic C-H bonds using aryl azides as the N-atom precurso...

Copper-mediated sequential cyanation of aryl C-B and arene C-H bonds using ammonium iodide and DMF.

J. Am. Chem. Soc. 5th ed., 134 , 2528-2531, (2012)

The cyanation of aromatic boronic acids, boronate esters, and borate salts was developed under copper-mediated oxidative conditions using ammonium iodide and DMF as the source of nitrogen and carbon a...

Ambient temperature synthesis of high enantiopurity N-protected peptidyl ketones by peptidyl thiol ester-boronic acid cross-coupling.

J. Am. Chem. Soc. 129 , 1132, (2007)

alpha-Amino acid thiol esters derived from N-protected mono-, di-, and tripeptides couple with aryl, pi-electron-rich heteroaryl, or alkenyl boronic acids in the presence of stoichiometric Cu(I) thiop...

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