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三聚氟氰

三聚氟氰用途

【用途一】
主要用于制备活性染料
【用途二】
用于有机合成。

三聚氟氰名称

[ CAS 号 ]:
675-14-9

[ 中文名 ]:
三聚氟氰

[ 英文名 ]:
Cyanuric fluoride

[中文别名 ]:

[英文别名 ]:

2,4,6-trifluorotriazine
1,3,5-Triazine, 2,4,6-trifluoro-
2,4,6-trifluoro-s-triazine
1,3,5-trifluoro-2,4,6-triazine
2,4,6-tri-fluoro-1,3,5-triazine
Trifluoro-s-triazine
MFCD00014597
2,4,6-trifluro-s-triazin
cyanuric trifluoride
Cyanuric Flouride

三聚氟氰物理化学性质

[ 密度 ]:
1.7±0.1 g/cm3

[ 沸点 ]:
316.1±25.0 °C at 760 mmHg

[ 熔点 ]:
-38°C

[ 分子式 ]:
C₃F₃N₃

[ 分子量 ]:
135.047

[ 闪点 ]:
145.0±23.2 °C

[ 精确质量 ]:
135.004425

[ PSA ]:
38.67000

[ LogP ]:
1.21

[ 外观性状 ]:
琥珀色液体

[ 蒸汽压 ]:
0.0±0.6 mmHg at 25°C

[ 折射率 ]:
1.416

[ 储存条件 ]:
室温

三聚氟氰MSDS

三聚氟氰毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: XZ1750000

CHEMICAL NAME :: s-Triazine, 2,4,6-trifluoro-

CAS REGISTRY NUMBER :: 675-14-9

BEILSTEIN REFERENCE NO. :: 0124237

LAST UPDATED :: 199709

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C3-F3-N3

MOLECULAR WEIGHT :: 135.06

WISWESSER LINE NOTATION :: T6N CN ENJ BF DF FF

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3100 ppb/4H

TOXIC EFFECTS :: Behavioral - excitement Lungs, Thorax, or Respiration - chronic pulmonary edema Lungs, Thorax, or Respiration - dyspnea

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 33,382,1972

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 160 mg/kg

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - lacrimation Lungs, Thorax, or Respiration - bronchiolar constriction Tumorigenic - Carcinogenic by RTECS criteria

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 33,382,1972

三聚氟氰安全信息

[ 符号 ]:

GHS05, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H310 + H330-H314

[ 警示性声明 ]:
P260-P280-P284-P302 + P350-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T+:Verytoxic;C:Corrosive;

[ 风险声明 (欧洲) ]:
R24;R26;R35

[ 安全声明 (欧洲) ]:
S26-S28-S36/37/39-S45

[ 危险品运输编码 ]:
UN 3389 6.1/PG 1

[ WGK德国 ]:
3

[ RTECS号 ]:
XZ1750000

[ 包装等级 ]:
I

[ 危险类别 ]:
6.1

[ 海关编码 ]:
2933699090

三聚氟氰合成路线

三聚氟氰上下游产品

三聚氟氰上游产品

三聚氟氰下游产品

三聚氟氰制备

在聚乙烯容器中，加入氰尿酰氯，冷至-78℃，通入干燥的氟化氢气体，氟化氢被冷凝，氰尿酰氯慢慢溶解，当氰尿酰氯全部溶解，反应产生的氯化氢先在低温下逸出，继续在室温下逸出，当不再有氯化氢逸出时，反应即告完成。稍加热并通氮气除去过量的氟化氢，在聚乙烯装置中蒸馏，得氰尿酰氟。产率76%。

三聚氟氰海关

[ 海关编码 ]: 2933699090

[ 中文概述 ]:
2933699090 其他结构上含非稠合三嗪环化合物. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

[ Summary ]:
2933699090 other compounds containing an unfused triazine ring (whether or not hydrogenated) in the structure。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:20.0%

三聚氟氰文献

[43] cyanuration.

Meth. Enzymol. 25 , 506, (1972)

Cyanuric fluoride (CyF) is introduced as a tyrosine modifying reagent. The reason that CyF may be considered as a very reactive acid halide, cyanuration of tyrosine should give the O-derivative, in co...

Chemical reactivity of the tyrosyl residues in yeast hexokinase. Properties of the nitroenzyme.

Biochim. Biophys. Acta 484 , 322, (1977)

Reactivity of acid fluoride-terminated self-assembled monolayers on gold.

Langmuir 23(3) , 1209-14, (2007)

This report describes the reactivity of acid fluoride (AF)-terminated self-assembled monolayers (SAMs) on gold toward amine and alcohol compounds and the potentiality of AF as a reactive intermediate ...

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