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苯基膦

苯基膦名称

[ CAS 号 ]:
638-21-1

[ 中文名 ]:
苯基膦

[ 英文名 ]:
Phenylphosphine

[中文别名 ]:

苯膦

[英文别名 ]:

phenyl phosphane
Monophenylphosphine
Phenylphosphine
MFCD00002094
phenylphosphane
EINECS 211-325-4
Phosphine, phenyl-

苯基膦物理化学性质

[ 密度 ]:
1.001

[ 沸点 ]:
160.5±9.0 °C at 760 mmHg

[ 分子式 ]:
C₆H₇P

[ 分子量 ]:
110.093

[ 闪点 ]:
73.9±0.0 °C

[ 精确质量 ]:
110.028534

[ PSA ]:
13.59000

[ LogP ]:
1.18700

[ 外观性状 ]:
透明无色液体,有着强烈的渗透的气味

[ 蒸汽压 ]:
3.1±0.3 mmHg at 25°C

[ 折射率 ]:
1.578

[ 储存条件 ]:
库房低温,通风,干燥,容器密闭,防火,与氧化剂,食品原料分开存放

苯基膦MSDS

苯基膦毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: SZ2100000

CHEMICAL NAME :: Phosphine, phenyl-

CAS REGISTRY NUMBER :: 638-21-1

BEILSTEIN REFERENCE NO. :: 0741946

LAST UPDATED :: 199712

DATA ITEMS CITED :: 14

MOLECULAR FORMULA :: C6-H7-P

MOLECULAR WEIGHT :: 110.10

WISWESSER LINE NOTATION :: PHHR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 38 ppm/4H

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,154,1969 *** REVIEWS *** ACGIH TLV-CL 0.23 mg/m3 (0.05 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.05 ppm (0.25 mg/m3) DTLWS* "Documentation of the Threshold Limit Values for Substances in Workroom Air," Supplements. For publisher information, see 85INA8. Volume(issue)/page/year: 3,26,1973 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 0.05 ppm (0.25 mg/m3) JAN 1993 OEL-BELGIUM:STEL 0.05 ppm (0.23 mg/m3) JAN 1993 OEL-DENMARK:TWA 0.05 ppm (0.25 mg/m3) JAN 1993 OEL-FINLAND:STEL 0.05 ppm (0.25 mg/m3) JAN 1993 OEL-FRANCE:STEL 0.05 ppm (0.25 mg/m3) JAN 1993 OEL-THE NETHERLANDS:TWA 0.05 ppm (0.25 mg/m3) JAN 1993 OEL-SWITZERLAND:TWA 0.05 ppm (0.25 mg/m3) JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO PHENYLPHOSPHINE-air:CL 0.05 ppm REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

苯基膦安全信息

[ 符号 ]:

GHS02, GHS07, GHS08, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H250-H302-H304-H315-H319-H336-H361f-H373-H411

[ 警示性声明 ]:
P210-P222-P231-P261-P273-P422

[ 危害码 (欧洲) ]:
F:Flammable;T:Toxic;N:Dangerousfortheenvironment;

[ 风险声明 (欧洲) ]:
R11;R17;R23/24/25;R36/37/38;R48/20;R51/53;R62;R65;R67

[ 安全声明 (欧洲) ]:
S16-S26-S36/37/39-S45-S62

[ 危险品运输编码 ]:
2924

[ RTECS号 ]:
SZ2100000

[ 包装等级 ]:
I

[ 危险类别 ]:
4.2

[ 海关编码 ]:
2902909090

苯基膦合成路线

苯基膦上下游产品

苯基膦上游产品

苯基膦下游产品

苯基膦海关

[ 海关编码 ]: 2902909090

[ 中文概述 ]:
2902909090. 其他芳香烃. 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:2.0%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量

[ Summary ]:
2902909090 other aromatic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%

苯基膦文献

A proximity-based programmable DNA nanoscale assembly line.

Nature 465 , 202-5, (2010)

Our ability to synthesize nanometre-scale chemical species, such as nanoparticles with desired shapes and compositions, offers the exciting prospect of generating new functional materials and devices ...

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苯基膦