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己腈

己腈用途

【用途一】
用于有机合成。

己腈名称

[ CAS 号 ]:
628-73-9

[ 中文名 ]:
已腈

[ 英文名 ]:
capronitrile

[中文别名 ]:

[英文别名 ]:

MFCD00001979
PENTYLCYANIDE
n-Hexanenitrile
Hexanenitrile
Tricapronile
1-Cyanopentane
n-capronitrile
EINECS 211-052-0
n-Pentyl cyanide
Pentyl cyanide

己腈物理化学性质

[ 密度 ]:
0.8±0.1 g/cm3

[ 沸点 ]:
164.5±3.0 °C at 760 mmHg

[ 熔点 ]:
−80 °C(lit.)

[ 分子式 ]:
C₆H₁₁N

[ 分子量 ]:
97.158

[ 闪点 ]:
43.3±0.0 °C

[ 精确质量 ]:
97.089149

[ PSA ]:
23.79000

[ LogP ]:
1.68

[ 外观性状 ]:
无色-微浅黄色透明液体

[ 蒸汽压 ]:
2.0±0.3 mmHg at 25°C

[ 折射率 ]:
1.407

[ 储存条件 ]:
库房通风低温干燥,与酸类、氧化剂、食品添加剂分开存放

己腈MSDS

详细MSDS(安全技术说明书)

己腈毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MO3900000

CHEMICAL NAME :: Hexanenitrile

CAS REGISTRY NUMBER :: 628-73-9

BEILSTEIN REFERENCE NO. :: 1633601

LAST UPDATED :: 199710

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C6-H11-N

MOLECULAR WEIGHT :: 97.18

WISWESSER LINE NOTATION :: NC5

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 463 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NEZAAQ Nippon Eiseigaku Zasshi. Japanese Journal of Hygiene. (Nippon Eisei Gakkai, c/o Kyoto Daigaku Igakubu, Konoe-cho, Yoshida, Sakyo-ku, Kyoto 606, Japan) V.1- 1946- Volume(issue)/page/year: 39,423,1984

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 42 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: COREAF Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. (Paris, France) V.1-261, 1835-1965. For publisher information, see CRASEV. Volume(issue)/page/year: 153,895,1911

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 310 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: COREAF Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. (Paris, France) V.1-261, 1835-1965. For publisher information, see CRASEV. Volume(issue)/page/year: 153,895,1911

己腈安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H226-H302-H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R10;R22;R36/37/38

[ 安全声明 (欧洲) ]:
S36/37

[ 危险品运输编码 ]:
UN 1993 3/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
MO3900000

[ 包装等级 ]:
III

[ 危险类别 ]:
3.2

己腈上下游产品

己腈上游产品

己腈下游产品

己腈制备

由正已酰胺与氯化亚砜反应而得。将正乙酰胺与新蒸过的氯化亚砜回流反应1h，待氯化氢不再急剧逸出时，将反应液常压蒸除过量的氯化亚砜，放冷后，加无水乙醚萃取。取乙醚萃取液蒸除乙醚，所得产物进行蒸馏，收集161-163℃馏分，得己腈，收率86%。

己腈文献

A three-component Fischer indole synthesis.

Nat. Protoc. 3(8) , 1249-52, (2008)

This protocol describes a three-component approach to multiply-substituted indoles from nitriles, organometallic reagents and arylhydrazine hydrochloride salts. The condensation of organolithium or Gr...

Methods of cell lysis and effect of detergents for the recovery of nitrile metabolizing enzyme from< i> Amycolatopsis</i> sp. IITR215. Babu V and Choudhury B.

J. Genet. Eng. Biotechnol. 11(2) , 117-22, (2013)

更多文献

己腈