二丙酮腙

二丙酮腙名称

[ CAS 号 ]:
627-70-3

[ 中文名 ]:
二丙酮腙

[ 英文名 ]:
acetone azine

[中文别名 ]:

4-甲基-3-戊烯-2-酮腙

[英文别名 ]:

1,1,4,4,-tetramethyl-2,3-diazabutadiene
1,1,4,4-tetramethyl-2,3-diazabuta-1,3-diene
Acetone,azine
Ketazine
diisopropylidenehydrazine
Acetone ketazine
EINECS 211-009-6
Dimethyl ketazine
MFCD00015645
2,5-dimethyl-3,4-diazahexa-2,4-diene

二丙酮腙物理化学性质

[ 密度 ]:
0.842 g/mL at 25ºC(lit.)

[ 沸点 ]:
133ºC763 mm Hg(lit.)

[ 熔点 ]:
-125ºC(lit.)

[ 分子式 ]:
C₆H₁₂N₂

[ 分子量 ]:
112.17300

[ 闪点 ]:
88 °F

[ 精确质量 ]:
112.10000

[ PSA ]:
24.72000

[ LogP ]:
1.86300

[ 外观性状 ]:
淡黄色液体

[ 折射率 ]:
n20/D 1.454(lit.)

[ 储存条件 ]:
室温，干燥，密封

二丙酮腙MSDS

详细MSDS(安全技术说明书)

二丙酮腙毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: UC3080550

CHEMICAL NAME :: 2-Propanone, (1-methylethylidene)hydrazone

CAS REGISTRY NUMBER :: 627-70-3

BEILSTEIN REFERENCE NO. :: 0956583

LAST UPDATED :: 199701

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C6-H12-N2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LC - Lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >2300 mg/m3/10M

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NDRC** National Defense Research Committee, Office of Scientific Research and Development, Progress Report. Volume(issue)/page/year: NDCrc-132,FEB1942

二丙酮腙安全信息

[ 符号 ]:

GHS02, GHS06, GHS08

[ 信号词 ]:
Danger

[ 危害声明 ]:
H226-H302-H311-H315-H319-H335-H350

[ 警示性声明 ]:
P201-P261-P280-P305 + P351 + P338-P308 + P313

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T

[ 风险声明 (欧洲) ]:
45-10-21/22-36/37/38

[ 安全声明 (欧洲) ]:
53-26-36/37-45

[ 危险品运输编码 ]:
UN 1992 3/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
UC3080550

[ 包装等级 ]:
III

[ 危险类别 ]:
3.2

[ 海关编码 ]:
2928000090

二丙酮腙合成路线

详细合成路线

二丙酮腙上下游产品

二丙酮腙上游产品

二丙酮腙下游产品

二丙酮腙海关

[ 海关编码 ]: 2928000090

[ 中文概述 ]:
2928000090 其他肼（联氨）及胲（羟胺）的有机衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

二丙酮腙文献

Reactions of methyl-substituted titanocene–bis(trimethylsilyl)acetylene complexes with acetone azine: crystal structures of (η5:η1-C₅HMe₃CH₂CMe₂NH)₂Ti and (C₅Me₅)₂Ti(NCMe₂) Rep M, et al.

J. Organomet. Chem. 597(1) , 146-156, (2000)

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