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苄基叠氮

苄基叠氮名称

[ CAS 号 ]:
622-79-7

[ 中文名 ]:
苄基叠氮

[ 英文名 ]:
benzyl azide

[中文别名 ]:

Α-疊氮甲苯

[英文别名 ]:

MFCD00013836
Benzylazide

苄基叠氮物理化学性质

[ 密度 ]:
1.0655

[ 沸点 ]:
81-83°C 16mm

[ 熔点 ]:
157ºC

[ 分子式 ]:
C₇H₇N₃

[ 分子量 ]:
133.15100

[ 闪点 ]:
82-85°C/16mm

[ 精确质量 ]:
133.06400

[ PSA ]:
49.75000

[ LogP ]:
1.94966

[ 外观性状 ]:
无色至浅棕色液体

[ 折射率 ]:
1.5341

[ 储存条件 ]:
通风低温干燥,与库房食品原料分开存放

苄基叠氮MSDS

苄基叠氮毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: XS6650000

CHEMICAL NAME :: Toluene, alpha-azido-

CAS REGISTRY NUMBER :: 622-79-7

BEILSTEIN REFERENCE NO. :: 1907583

LAST UPDATED :: 199612

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C7-H7-N3

MOLECULAR WEIGHT :: 133.17

WISWESSER LINE NOTATION :: NNNR B1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 120 ug/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium) V.4- 1898- Volume(issue)/page/year: 108,473,1956

苄基叠氮安全信息

[ 符号 ]:

GHS08

[ 信号词 ]:
Warning

[ 危害声明 ]:
H351-H373

[ 警示性声明 ]:
P281

[ 危害码 (欧洲) ]:
Xi

[ 风险声明 (欧洲) ]:
2-11-48/20/21/22-40

[ 安全声明 (欧洲) ]:
S15-S17-S33

[ 危险品运输编码 ]:
1993

[ 包装等级 ]:
III

[ 危险类别 ]:
3

[ 海关编码 ]:
2929909090

苄基叠氮合成路线

苄基叠氮海关

[ 海关编码 ]: 2929909090

[ 中文概述 ]:
2929909090 其他含氮基化合物. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2929909090 other compounds with other nitrogen function VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

苄基叠氮文献

High-throughput chemical modification of oligonucleotides for systematic structure-activity relationship evaluation.

Bioconjug. Chem. 25(12) , 2222-32, (2014)

Chemical modification of siRNA is achieved in a high-throughput manner (96-well plate format) by copper catalyzed azide-alkyne cycloadditions. This transformation can be performed in one synthetic ope...

Bioorthogonal Labeling, Bioimaging, and Photocytotoxicity Studies of Phosphorescent Ruthenium(II) Polypyridine Dibenzocyclooctyne Complexes.

Chemistry 21 , 10729-40, (2015)

The synthesis, characterization, photophysics, lipophilicity, and cellular properties of new phosphorescent ruthenium(II) polypyridine complexes functionalized with a dibenzocyclooctyne (DIBO) or amin...

Phosphoramidite accelerated copper(i)-catalyzed [3 + 2] cycloadditions of azides and alkynes.

Chem. Commun. (Camb.) 16 , 2139-2141, (2009)

Monodentate phosphoramidite ligands are used to accelerate the copper(i)-catalyzed 1,3-dipolar cycloaddition of azides and alkynes (CuAAC) rapidly yielding a wide variety of functionalized 1,4-disubst...

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