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3-溴苯甲酸甲酯

3-溴苯甲酸甲酯名称

[ CAS 号 ]:
618-89-3

[ 中文名 ]:
3-溴苯甲酸甲酯

[ 英文名 ]:
Methyl 3-bromobenzoate

[中文别名 ]:

[英文别名 ]:

3-methoxycarbonyl-1-bromobenzene
(3-bromophenyl)acetic acid methyl ester
m-bromobenzoic acid methyl ester
Methyl 3-bromobenzoate
Benzoic acid, m-bromo-, methyl ester
MFCD00017777
Benzoic acid,3-bromo-,methyl ester
Methyl-3-brombenzolcarboxylat
Benzoic acid, 3-bromo-, methyl ester
methyl-3-bromobenzoate

3-溴苯甲酸甲酯物理化学性质

[ 密度 ]:
1.5±0.1 g/cm3

[ 沸点 ]:
244.4±13.0 °C at 760 mmHg

[ 熔点 ]:
31-33 °C(lit.)

[ 分子式 ]:
C₈H₇BrO₂

[ 分子量 ]:
215.044

[ 闪点 ]:
101.6±19.8 °C

[ 精确质量 ]:
213.962936

[ PSA ]:
26.30000

[ LogP ]:
2.88

[ 外观性状 ]:
淡黄色晶体

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.550

[ 储存条件 ]:
Room temperature.

3-溴苯甲酸甲酯MSDS

3-溴苯甲酸甲酯安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S37/39-S26

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ 海关编码 ]:
2916399090

3-溴苯甲酸甲酯合成路线

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3-溴苯甲酸甲酯海关

[ 海关编码 ]: 2916399090

[ 中文概述 ]:
2916399090 其他芳香一元羧酸. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

3-溴苯甲酸甲酯文献

Cyanation of aryl bromides with K4[Fe(CN)6] catalyzed by dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium, a molecular source of nanoparticles, and the reactions involved in the catalyst-deactivation processes.

Chemistry 18(10) , 2978-86, (2012)

Dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium [(P{(NC(5)H(10))(C(6)H(11))(2)})(2)PdCl(2)] (1) is a highly active and generally applicable C-C cross-coupling catalyst. Apart from its hig...

Dual catalysis. Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis.

Science 345(6195) , 433-6, (2014)

The routine application of C(sp3)-hybridized nucleophiles in cross-coupling reactions remains an unsolved challenge in organic chemistry. The sluggish transmetalation rates observed for the preferred ...

Negishi cross-coupling reaction catalyzed by an aliphatic, phosphine based pincer complex of palladium. biaryl formation via cationic pincer-type Pd^IV intermediates. Gerber R, et al.

Dalton Trans. 40(35) , 8996-9003, (2011)

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