反-1-溴-1-丙烯

反-1-溴-1-丙烯名称

[ CAS 号 ]:
590-15-8

[ 中文名 ]:
反式-1-溴-1-丙烯

[ 英文名 ]:
1-bromo-1-propene

[中文别名 ]:

反-1-溴-1-丙烯

[英文别名 ]:

trans-1-bromoprop-1-ene
trans-1-bromo-1-propene
n-propenyl bromide
trans-1-Bromopropene
1-PROPENYL BROMIDE
EINECS 209-671-6
MFCD00000186
PROPENYL BROMIDE

反-1-溴-1-丙烯物理化学性质

[ 密度 ]:
1.420 g/mL at 20 °C(lit.)

[ 沸点 ]:
64-65 °C(lit.)

[ 熔点 ]:
−116 °C(lit.)

[ 分子式 ]:
C₃H₅Br

[ 分子量 ]:
120.97600

[ 闪点 ]:
5 °F

[ 精确质量 ]:
119.95700

[ LogP ]:
1.91490

[ 折射率 ]:
n20/D 1.454

[ 储存条件 ]:
2-8°C

反-1-溴-1-丙烯安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H315-H319-H335

[ 警示性声明 ]:
P210-P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)

[ 危害码 (欧洲) ]:
F,Xi

[ 风险声明 (欧洲) ]:
11-36/37/38-53

[ 安全声明 (欧洲) ]:
S26-S36-S36/37/39-S16

[ 危险品运输编码 ]:
UN 1993 3/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
UC7080000

[ 包装等级 ]:
II

[ 危险类别 ]:
3.1

反-1-溴-1-丙烯合成路线

详细合成路线

反-1-溴-1-丙烯上下游产品

反-1-溴-1-丙烯上游产品

反-1-溴-1-丙烯下游产品

反-1-溴-1-丙烯文献

Palladium-catalyzed enantioselective alpha-arylation and alpha-vinylation of oxindoles facilitated by an axially chiral P-stereogenic ligand.

J. Am. Chem. Soc. 131(29) , 9900-1, (2009)

The enantioselective alpha-arylation and alpha-vinylation of oxindoles catalyzed by Pd and a biarylmonophosphine ligand with both axial and phosphorus-based chirogenicity is reported. The resultant qu...

Preparation of (+)-trans-isoalliin and its isomers by chemical synthesis and RP-HPLC resolution.

J. Biomol. Tech. 25(3) , 67-76, (2014)

Naturally occurring (+)-trans-isoalliin, (R(C)R(S))-(+)-trans-S-1-propenyl-L-cysteine sulfoxide, is a major cysteine sulfoxide in onion. The importance of producing it synthetically to support further...

Structure Analysis of Poly (propylene-β-d oxide) by Proton Nuclear Magnetic Resonance Spectroscopy. Oguni N, et al.

Macromolecules 6(3) , 459-465, (1973)

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