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溴代硝基甲烷

溴代硝基甲烷用途

Bromonitromethane 是一种卤代硝基甲烷,可用于生产各种受保护的 α-溴硝基烷烃供体,以用于 Umpolung 酰胺合成。

溴代硝基甲烷名称

[ CAS 号 ]:
563-70-2

[ 中文名 ]:
溴代硝基甲烷

[ 英文名 ]:
Bromonitromethane

[英文别名 ]:

MFCD00007401
EINECS 209-258-0
bromo(nitro)methane

溴代硝基甲烷生物活性

[ 描述 ]:

Bromonitromethane 是一种卤代硝基甲烷,可用于生产各种受保护的 α-溴硝基烷烃供体,以用于 Umpolung 酰胺合成。

[ 相关类别 ]:

研究领域 >> 癌症

信号通路 >> 其他 >> 其他

[参考文献]

[1]. Dawn M Makley, et al. Silyl Imine Electrophiles in Enantioselective Catalysis: A Rosetta Stone for Peptide Homologation, Enabling Diverse N-protected Aryl Glycines From Aldehydes in Three Steps. Org Lett. 2014 Jun 6;16(11):3146-9.

[2]. Alicia Marsà, et al. In Vitro Studies on the Tumorigenic Potential of the Halonitromethanes Trichloronitromethane and Bromonitromethane. Toxicol In Vitro. 2017 Dec;45(Pt 1):72-80.

溴代硝基甲烷物理化学性质

[ 密度 ]:
2.07

[ 沸点 ]:
146-148 °C (750 mmHg)

[ 分子式 ]:
CH₂BrNO₂

[ 分子量 ]:
139.93600

[ 闪点 ]:
4°C

[ 精确质量 ]:
138.92700

[ PSA ]:
45.82000

[ LogP ]:
1.13870

[ 外观性状 ]:
透明黄色液体

[ 折射率 ]:
1.485-1.495

[ 储存条件 ]:
室温

溴代硝基甲烷MSDS

溴代硝基甲烷安全信息

[ 符号 ]:

GHS03, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H272-H315-H319-H335

[ 警示性声明 ]:
P220-P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
O: Oxidizing agent;Xn: Harmful;

[ 风险声明 (欧洲) ]:
R8;R36/37/38

[ 安全声明 (欧洲) ]:
S36/37/39-S26-S17-S36

[ 危险品运输编码 ]:
3098

[ RTECS号 ]:
PA5360000

[ 包装等级 ]:
III

[ 危险类别 ]:
5.1

[ 海关编码 ]:
2904909090

溴代硝基甲烷合成路线

溴代硝基甲烷海关

[ 海关编码 ]: 2904909090

[ 中文概述 ]:
2904909090 其他烃的磺化、硝化、亚硝化衍生物（不论是否卤化）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

溴代硝基甲烷文献

Silyl imine electrophiles in enantioselective catalysis: a Rosetta Stone for peptide homologation, enabling diverse N-protected aryl glycines from aldehydes in three steps.

Org. Lett. , (2014)

We report that N-(trimethylsilyl)imines serve in the Bis(AMidine)-catalyzed addition of bromonitromethane with a high degree of enantioselection. This allows for the production of a range of protected...

Stereoselective synthesis of highly functionalized nitrocyclopropanes through the organocatalyic Michael-addition-initiated cyclization of bromonitromethane and β,γ-unsaturated α-ketoesters.

Chem. Asian J. 8(11) , 2859-63, (2013)

A highly diastereo- and enantioselective cyclopropanation of β,γ-unsaturated α-ketoesters with bromonitromethane has been successfully developed through a domino Michael-addition/intramolecular-alkyla...

Synthesis of enantiopure 2-C-glycosyl-3-nitrochromenes.

J. Org. Chem. 78(24) , 12831-6, (2013)

A novel methodology has been developed to obtain enantiopure 2-C-glycosyl-3-nitrochromenes. First, (Z)-1-bromo-1-nitroalkenes were prepared from the corresponding sugar aldehydes through a sodium iodi...

更多文献

溴代硝基甲烷

溴代硝基甲烷用途

溴代硝基甲烷名称

溴代硝基甲烷生物活性

溴代硝基甲烷物理化学性质

溴代硝基甲烷MSDS

详细MSDS(安全技术说明书)

溴代硝基甲烷安全信息

溴代硝基甲烷合成路线

详细合成路线

溴代硝基甲烷海关

溴代硝基甲烷文献

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