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特屈儿

特屈儿用途

1.有良好引爆能力，用于引爆药及猛烈炸药。由于毒性较大，已逐渐被太安、黑索今等炸药取代，但仍作为传爆药柱的装药。

2.用作引爆药、导爆索及雷管的副装药、指示剂。

特屈儿名称

[ CAS 号 ]:
479-45-8

[ 中文名 ]:
特屈儿

[ 英文名 ]:
tetryl

[中文别名 ]:

[英文别名 ]:

N-METHYL-N,2,4,6-TETRANITROANILINE
Nitramine
2,4,6-trinitrophenylmethylnitramine
EINECS 207-531-9
2,4,6-trinitrophenyl-N-methylnitramine
N-methyl-N-(2,4,6-trinitrophenyl)nitramide
2,4,6-Tetryl
N-Methyl-N-picrylnitramine
Picrylmethylnitramine
Tetril

特屈儿物理化学性质

[ 密度 ]:
1.803g/cm3

[ 沸点 ]:
503.7ºC at 760mmHg

[ 熔点 ]:
130ºC

[ 分子式 ]:
C₇H₅N₅O₈

[ 分子量 ]:
287.14300

[ 闪点 ]:
258.4ºC

[ 精确质量 ]:
287.01400

[ PSA ]:
186.52000

[ LogP ]:
3.13190

[ 折射率 ]:
1.686

[ 储存条件 ]:
轻装轻放,库房通风、远离明火、高温、阳光,与氧化剂、碱分开存放

特屈儿MSDS

特屈儿毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: BY6300000

CHEMICAL NAME :: Aniline, N-methyl-N,2,4,6-tetranitro-

CAS REGISTRY NUMBER :: 479-45-8

BEILSTEIN REFERENCE NO. :: 0964788

LAST UPDATED :: 199712

DATA ITEMS CITED :: 31

MOLECULAR FORMULA :: C7-H5-N5-O8

MOLECULAR WEIGHT :: 287.17

WISWESSER LINE NOTATION :: WNN1&R BNW DNW ENW

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 5 gm/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Skin and Appendages - hair Nutritional and Gross Metabolic - weight loss or decreased weight gain

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 5 gm/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Skin and Appendages - hair Nutritional and Gross Metabolic - weight loss or decreased weight gain

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Mammal - dog

DOSE/DURATION :: 5 gm/kg

TOXIC EFFECTS :: Liver - fatty liver degeneration Kidney, Ureter, Bladder - changes in both tubules and glomeruli Kidney, Ureter, Bladder - interstitial nephritis

TYPE OF TEST :: LD - Lethal dose

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >2 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 5580 mg/kg/90D-C

TOXIC EFFECTS :: Blood - other changes Blood - changes in erythrocyte (RBC) count Nutritional and Gross Metabolic - weight loss or decreased weight gain

MUTATION DATA

TYPE OF TEST :: Gene conversion and mitotic recombination

TEST SYSTEM :: Yeast - Saccharomyces cerevisiae

REFERENCE :: TOLED5 Toxicology Letters. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1977- Volume(issue)/page/year: 5,11,1980 *** REVIEWS *** ACGIH TLV-TWA 1.5 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 1.5 mg/m3 (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,255,1971 OSHA PEL (Gen Indu):8H TWA 1.5 mg/m3 (skin) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 1.5 mg/m3 (skin) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 1.5 mg/m3 (skin) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 1.5 mg/m3 (skin) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 1.5 mg/m3 JAN 1993 OEL-BELGIUM:TWA 1.5 mg/m3 JAN 1993 OEL-DENMARK:TWA 1.5 mg/m3;Skin JAN 1993 OEL-FINLAND:TWA 1.5 mg/m3;STEL 3 mg/m3;Skin JAN 1993 OEL-FRANCE:TWA 1.5 mg/m3;Skin JAN 1993 OEL-GERMANY:TWA 1.5 mg/m3;Skin JAN 1993 OEL-THE NETHERLANDS:TWA 15 mg/m3;Skin JAN 1993 OEL-THE PHILIPPINES:TWA 1.5 mg/m3;Skin JAN 1993 OEL-SWITZERLAND:TWA 1.5 mg/m3;Skin JAN 1993 OEL-TURKEY:TWA 1.5 mg/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 1.5 mg/m3;STEL 3 mg/m3;Skin JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO TETRYL-air:10H TWA 1.5 mg/m3 (Sk) REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

特屈儿安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H302 + H312 + H332-H319

[ 警示性声明 ]:
P210-P261-P302 + P352 + P312-P304 + P340 + P312-P337 + P313-P403 + P235

[ 危害码 (欧洲) ]:
E,T,F

[ 风险声明 (欧洲) ]:
2-23/24/25-33-36/37/38-11

[ 安全声明 (欧洲) ]:
35-45-27-16

[ 危险品运输编码 ]:
0208

[ WGK德国 ]:
3

[ 危险类别 ]:
1.1

特屈儿合成路线

特屈儿上下游产品

特屈儿上游产品

特屈儿下游产品

特屈儿制备

由二甲基苯胺经中和、硝化、稀释、精制制得，也可由二硝基氯苯与甲胺在苯中缩合，然后再进行硝化制得。

特屈儿文献

Measurement of nitrosamine and nitramine formation from NOx reactions with amines during amine-based carbon dioxide capture for postcombustion carbon sequestration.

Environ. Sci. Technol. 46(17) , 9793-801, (2012)

With years of full-scale experience for precombustion CO(2) capture, amine-based technologies are emerging as the prime contender for postcombustion CO(2) capture. However, concerns for postcombustion...

Evaluation of a TiO2 photocatalysis treatment on nitrophenols and nitramines contaminated plant wastewaters by solid-phase extraction coupled with ESI HPLC-MS.

J. Hazard. Mater. 166(1) , 284-90, (2009)

Nitration reactions of aromatic compounds are commonly involved in different industrial processes for pharmaceutical, pesticide or military uses. For many years, most of the manufacturing sites used l...

A reliable simple method to estimate density of nitroaliphatics, nitrate esters and nitramines.

J. Hazard. Mater. 169(1-3) , 158-69, (2009)

In this work, a new simple method is presented to estimate crystal density of three important classes of explosives including nitroalphatics, nitrate esters and nitramines. This method allows reliable...

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特屈儿