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( )-反式-菊酸

( )-反式-菊酸名称

[ CAS 号 ]:
4638-92-0

[ 中文名 ]:
(+)-反式-菊酸

[ 英文名 ]:
TRANS-(+)-CHRYSANTHEMIC ACID

[中文别名 ]:

( )-反式-菊酸

[英文别名 ]:

trans-(+)-Chrysanthemic acid
MFCD01941572
EINECS 225-067-5

( )-反式-菊酸物理化学性质

[ 密度 ]:
1.077 g/cm3

[ 沸点 ]:
246.4ºC at 760 mmHg

[ 熔点 ]:
17-21ºC

[ 分子式 ]:
C₁₀H₁₆O₂

[ 分子量 ]:
168.23300

[ 闪点 ]:
119ºC

[ 精确质量 ]:
168.11500

[ PSA ]:
37.30000

[ LogP ]:
2.30940

[ 外观性状 ]:
无色至黄色透明液体

[ 折射率 ]:
1.477

[ 储存条件 ]:
2-8°C，干燥，密闭

( )-反式-菊酸MSDS

( )-反式-菊酸毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: GZ1280000

CHEMICAL NAME :: Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methylpropenyl)-, (1R,3R)-(+)-

CAS REGISTRY NUMBER :: 4638-92-0

BEILSTEIN REFERENCE NO. :: 2043419

LAST UPDATED :: 199701

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C10-H16-O2

MOLECULAR WEIGHT :: 168.26

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 60600 ug/kg

TOXIC EFFECTS :: Behavioral - ataxia Lungs, Thorax, or Respiration - dyspnea

REFERENCE :: PCBPBS Pesticide Biochemistry and Physiology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1971- Volume(issue)/page/year: 6,491,1976

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 98 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JAFCAU Journal of Agricultural and Food Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC 20037) V.1- 1953- Volume(issue)/page/year: 22,212,1974

( )-反式-菊酸安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319

[ 警示性声明 ]:
P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 风险声明 (欧洲) ]:
R36/38

[ 安全声明 (欧洲) ]:
S26

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
GZ1280000

[ 海关编码 ]:
2916209090

( )-反式-菊酸合成路线

( )-反式-菊酸上下游产品

( )-反式-菊酸上游产品

( )-反式-菊酸下游产品

( )-反式-菊酸海关

[ 海关编码 ]: 2916209090

[ 中文概述 ]:
2916209090 其他（环烷、环烯、环萜烯）一元羧酸（包括酸酐、酰卤化物，过氧化物和过氧酸及该税号的衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:AB(入境货物通关单,出境货物通关单) 最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验

[ Summary ]:
2916209090 other cyclanic, cyclenic or cyclotherpenic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0%

( )-反式-菊酸文献

[Determination of chrysanthemic acid and its ethyl ester in the air of a work area].

Gig. Sanit. (3) , 42-3, (1988)

Characteristics and function of Alcaligenes sp. NBRC 14130 esterase catalysing the stereo-selective hydrolysis of ethyl chrysanthemate.

J. Appl. Microbiol. 108(4) , 1263-70, (2010)

Alcaligenes sp. NBRC 14130 was found as a strain hydrolysing a mixture of (+/-)-trans- and (+/-)-cis ethyl chrysanthemates to (1R,3R)-(+)-trans-chrysanthemic acid. The Alcaligenes cells also have hydr...

Gas chromatographic determination of racemic cis- and trans-chrysanthemols and their potential aldehyde and carboxylic acid microbial metabolites.

J. Chromatogr. A. 437(2) , 436-41, (1988)

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