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二甲基三甲硅基膦酸酯

二甲基三甲硅基膦酸酯名称

[ CAS 号 ]:
36198-87-5

[ 中文名 ]:
二甲基三甲硅基膦酸酯

[ 英文名 ]:
dimethyl trimethylsilyl phosphite

[英文别名 ]:

phosphonic acid dimethyl trimethylsilyl ether
Me3SiOP(OMe)2
EINECS 252-908-3
mono(trimethylsilyl)dimethyl phosphite
Phosphorous acid,dimethyl trimethylsilyl ester
dimethyl (trimethylsilyl)phosphite
(MeO)2POSiMe3
MFCD00075439

二甲基三甲硅基膦酸酯物理化学性质

[ 密度 ]:
0.954 g/mL at 25 °C(lit.)

[ 沸点 ]:
146.6ºC at 760mmHg

[ 分子式 ]:
C₅H₁₅O₃PSi

[ 分子量 ]:
182.23000

[ 闪点 ]:
38.9ºC

[ 精确质量 ]:
182.05300

[ PSA ]:
41.28000

[ LogP ]:
2.35760

[ 折射率 ]:
n20/D 1.410(lit.)

[ 储存条件 ]:
2-8°C

二甲基三甲硅基膦酸酯MSDS

详细MSDS(安全技术说明书)

二甲基三甲硅基膦酸酯安全信息

[ 符号 ]:

GHS02, GHS05

[ 信号词 ]:
Danger

[ 危害声明 ]:
H226-H314

[ 警示性声明 ]:
P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
C: Corrosive;

[ 风险声明 (欧洲) ]:
10-34

[ 安全声明 (欧洲) ]:
26-36/37/39-45

[ 危险品运输编码 ]:
UN 2920 8/PG 2

[ WGK德国 ]:
3

[ 包装等级 ]:
III

[ 危险类别 ]:
3.2

[ 海关编码 ]:
2931900090

二甲基三甲硅基膦酸酯海关

[ 海关编码 ]: 2931900090

[ 中文概述 ]:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

二甲基三甲硅基膦酸酯文献

Efficient Fmoc/solid-phase synthesis of Abu(P)-containing peptides using Fmoc-Abu(PO3Me2)-OH.

Int. J. Pept. Protein Res. 44(3) , 288-94, (1994)

The synthesis of the two 4-phosphono-2-aminobutanoyl-containing peptides, Leu-Arg-Arg-Val-Abu(P)-Leu-Gly-OH.CF3CO2H and Ile-Val-Pro-Asn-Abu(P)-Val-Glu-Glu-OH.CF3CO2H was accomplished by the use of Fmo...

Silyl phosphites. Part 20. A facile synthesis of phosphoenolpyruvate and its analogue utilizing in situ generated trimethylsilyl bromide. Sekine M, et al.

J. Chem. Soc. Perkin Trans. I , 2509-13, (1982)

Synthesis of novel CMP-NeuNAc analogues having a glycosyl phosphonate structure. Imamura M and Hashimoto H.

Tetrahedron Lett. 37(9) , 1451-54, (1996)

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