腐霉利标准溶液

腐霉利标准溶液用途

【用途一】
属保护地用蔬菜杀菌剂
【用途二】
用于防治保护地番茄灰霉病等病害
【用途三】
内吸性杀菌剂，兼有保护和治疗的作用，低温高湿条件下使用效果明显。用于油菜、萝卜、茄子、黄瓜、白菜、番茄、向日葵、西瓜、草莓、元葱、桃、樱桃、花卉、葡萄等作物，防治灰霉病和菌核病及灰星病、花腐病、褐腐病、蔓枯病等，也可用于对甲基硫菌灵、多菌灵有抗性原菌。如防治灰霉病，在开花初期、盛花期、结果期分别用50%可湿性粉剂1000～2000倍液喷雾；防治菌核病在发病初期，用50%可湿性粉剂1500～2000倍液喷雾，在初花期、盛花期喷1～2次。

腐霉利标准溶液名称

[ CAS 号 ]:
32809-16-8

[ 中文名 ]:
腐霉利

[ 英文名 ]:
Procymidone

[中文别名 ]:

[英文别名 ]:

Sumisclex
Procymidone
Procymidon
MFCD00078740
EINECS 251-233-1
Sumilex
Dicyclidine

腐霉利标准溶液物理化学性质

[ 密度 ]:
1.5±0.1 g/cm3

[ 沸点 ]:
477.9±35.0 °C at 760 mmHg

[ 熔点 ]:
166-167°C

[ 分子式 ]:
C₁₃H₁₁Cl₂NO₂

[ 分子量 ]:
284.138

[ 闪点 ]:
242.8±25.9 °C

[ 精确质量 ]:
283.016693

[ PSA ]:
37.38000

[ LogP ]:
2.67

[ 外观性状 ]:
无色固体

[ 蒸汽压 ]:
0.0±1.2 mmHg at 25°C

[ 折射率 ]:
1.643

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

腐霉利标准溶液MSDS

详细MSDS(安全技术说明书)

腐霉利标准溶液毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: GZ2150000

CHEMICAL NAME :: 1,2-Cyclopropanedicarboximide, N-(3,5-dichlorophenyl)-1,2-dimethyl-

CAS REGISTRY NUMBER :: 32809-16-8

BEILSTEIN REFERENCE NO. :: 1539058

LAST UPDATED :: 199710

DATA ITEMS CITED :: 18

MOLECULAR FORMULA :: C13-H11-Cl2-N-O2

MOLECULAR WEIGHT :: 284.15

WISWESSER LINE NOTATION :: T35 DVNVTJ A1 C1 ER CG EG

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 7 gm/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - changes in motor activity (specific assay) Behavioral - ataxia

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >2500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 730 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >10 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 7800 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 7800 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1560 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >10 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 10 gm/kg

TOXIC EFFECTS :: Autonomic Nervous System - other (direct) parasympathomimetic Behavioral - somnolence (general depressed activity) Behavioral - ataxia

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Bird - quail

DOSE/DURATION :: >6637 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Bird - duck

DOSE/DURATION :: >4 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: >10 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 25480 mg/kg/26W-I

TOXIC EFFECTS :: Endocrine - other changes Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - phosphatases

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 36400 mg/kg/26W-I

TOXIC EFFECTS :: Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol) Biochemical - Metabolism (Intermediary) - lipids including transport

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - quail

DOSE/DURATION :: 1190 mg/kg/7D-C

TOXIC EFFECTS :: Gastrointestinal - other changes Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - cytochrome oxidases (including oxidative phosphorylation) Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other oxidoreductases

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

DOSE :: 360 mg/kg

SEX/DURATION :: male 14 day(s) pre-mating

TOXIC EFFECTS :: Reproductive - Paternal Effects - other effects on male Endocrine - changes in luteinizing hormone Endocrine - androgenic

MUTATION DATA

TYPE OF TEST :: Morphological transformation

TEST SYSTEM :: Rodent - mouse Fibroblast

DOSE/DURATION :: 50 mg/L

REFERENCE :: EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 21,81,1993

腐霉利标准溶液安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危险品运输编码 ]:
NONH for all modes of transport

[ RTECS号 ]:
GZ2150000

[ 海关编码 ]:
2921519012

腐霉利标准溶液制备

【方法一】
制备方法一
由α-氯代丙酸甲酯、α-甲基丙烯酸甲酯和3，5-二氯苯胺为原料制备。先将α-氯代丙酸甲酯与α-甲基丙烯酸甲酯作用，制备1，2-二甲基环丙烷-1，2-二甲酸甲酯，然后水解得1，2-二甲基环丙烷-1，2-二甲酸。将上述产物与3，5-二氯苯胺反应，合成腐霉利。
制备方法二
α-甲基丙烯酸乙酯与α-氯代丙酸乙酯、步丁醇钾和氢氧化钠、乙酐反应，制得1，2-二甲基环丙烷-1，2-二羧酐。再滴加3，5-二氯苯胺的苯溶液，析出中间体，滴毕搅拌30min，减压脱苯，往残留物中加入乙酐和无水乙酸钠，于100℃加热30～60min，脱去乙酸和过量的乙酐，用稀氢氧化钠和水洗涤，干燥得腐霉剂。m.p.165～167℃。

腐霉利标准溶液海关

[ 海关编码 ]: 2921519012

[ 中文概述 ]:
2921519012 氨氟乐灵退税率:9.0% 监管条件:S(进出口农药登记证明)

[ Summary ]:
2921519012 3-(3,5-dichlorophenyl)-1,5-dimethyl-3-azabicyclo[3.1.0]hexane-2,4-dione

腐霉利标准溶液文献

Determination of pesticides in sunflower seeds by high-performance liquid chromatography coupled with a diode array detector.

J. AOAC Int. 97(4) , 1012-20, (2014)

The application of RP-HPLC with a diode array detector for identification and quantitative analysis of pesticides in sunflower seed samples is demonstrated. An HPLC procedure on C18 RP column has been...

Assessment of estrogenic and anti-androgenic activities of the mycotoxin zearalenone and its metabolites using in vitro receptor-specific bioassays.

Food Chem. Toxicol. 74 , 233-9, (2015)

Zearalenone (ZEN) is a well-known mycotoxin present in numerous agricultural products. Humans and animals are therefore at a risk of exposure to zearalenone through consumption of contaminated food. A...

A multi-lysimeter investigation on the mobility and persistence of pesticides in the loam soil of the Fucino Plain (Italy).

J. Environ. Monit. 10(6) , 747-52, (2008)

In order to evaluate the impact of intensive horticulture on the water resources of the Fucino Plain, one of the most important agricultural settlements of Central Italy, the mobility and persistence ...

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