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异佛尔酮二胺

异佛尔酮二胺用途

主要用作环氧树脂的固化剂，参考用量24质量份，固化条件80℃/4h或150℃/1h。固化物热变形温度149℃。在室温也可固化，但是只能到B阶段，所以有必要进行加热固化。加热固化的热变形温度高，固化色度稳定，耐药性能优良。

异佛尔酮二胺名称

[ CAS 号 ]:
2855-13-2

[ 中文名 ]:
异佛尔酮二胺

[ 英文名 ]:
Isophorone diamine

[中文别名 ]:

[英文别名 ]:

Cyclohexanemethanamine, 5-amino-1,3,3-trimethyl-
5-amino-1-aminomethyl-1,3,3-trimethylcyclohexane
1-aminomethyl-5-amino-1,3,3-trimethylcyclohexane
1-amino-3,3,5-trimethyl-5-aminomethyl-cyclohexane
Cyclohexanemethanamine,5-amino-1,3,3-trimethyl
MFCD00019397
1-Amino-3-aminomethyl-3,5,5-trimethylcyclohexane
EINECS 220-666-8
3-(Aminomethyl)-3,5,5-trimethylcyclohexanamine
Isophorone diamine

异佛尔酮二胺物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
217.2±8.0 °C at 760 mmHg

[ 熔点 ]:
10 °C(lit.)

[ 分子式 ]:
C₁₀H₂₂N₂

[ 分子量 ]:
170.295

[ 闪点 ]:
98.7±17.9 °C

[ 精确质量 ]:
170.178299

[ PSA ]:
52.04000

[ LogP ]:
1.68

[ 外观性状 ]:
淡黄色液体

[ 蒸汽压 ]:
0.1±0.4 mmHg at 25°C

[ 折射率 ]:
1.458

[ 储存条件 ]:
库房通风低温干燥,与酸、氧化剂分开存放

[ 稳定性 ]:
Stable. Incompatible with strong oxidizing agents.

[ 水溶解性 ]:
miscible

异佛尔酮二胺MSDS

异佛尔酮二胺安全信息

[ 符号 ]:

GHS05, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H302 + H312-H314-H317-H412

[ 警示性声明 ]:
P273-P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
C:Corrosive;

[ 风险声明 (欧洲) ]:
R21/22;R34;R43;R52/53

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45-S61

[ 危险品运输编码 ]:
UN 2289 8/PG 3

[ WGK德国 ]:
1

[ RTECS号 ]:
GV5020833

[ 包装等级 ]:
III

[ 危险类别 ]:
8

[ 海关编码 ]:
2921300090

异佛尔酮二胺合成路线

异佛尔酮二胺上下游产品

异佛尔酮二胺上游产品

异佛尔酮二胺下游产品

异佛尔酮二胺制备

3-氰基-3,5,5-三甲基环己酮在钴、氢气的催化下，与氨气反应合成，反应压强15.2MPa（150ATM），温度120。或使用3个分子的丙酮缩合成异佛尔酮，进一步用HCN加成异佛尔酮的双键得到异佛尔酮腈（3-氰基-3,5,5-三甲基环己酮），继续在H2存在下还原和胺化得到产品。反应式如下：

异佛尔酮二胺海关

[ 海关编码 ]: 2921300090

[ 中文概述 ]:
2921300090 其他环（烷，烯，萜烯）单胺或多胺（包括其衍生物及它们的盐）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2921300090 other cyclanic, cyclenic or cyclotherpenic mono- or polyamines, and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

异佛尔酮二胺文献

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Little is known about the use of prick tests with chemicals in diagnosing occupational diseases.To evaluate the use of prick tests in the diagnosis of occupational contact urticaria, asthma and rhinit...

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An attempt to improve diagnostics of contact allergy due to epoxy resin systems. First results of the multicentre study EPOX 2002.

Contact Dermatitis 51(5-6) , 263-72, (2004)

Epoxy resin systems (ERSs) are a frequent cause of occupational allergic contact dermatitis. Sensitization occurs not only to the resins, but also to hardeners and reactive diluents. However, only a f...

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