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5-氨基邻甲酚

5-氨基邻甲酚用途

:用于有机合成，染料和染发中间体

5-氨基邻甲酚名称

[ CAS 号 ]:
2835-95-2

[ 中文名 ]:
5-氨基-2-甲基苯酚

[ 英文名 ]:
5-Amino-2-methylphenol

[中文别名 ]:

[英文别名 ]:

EINECS 220-618-6
5-Amino-2-methylphenol
2-hydroxy-p-toluidine
5-AMINO-ORTHO-CRESOL
5-AMINO-2-CRESOL
2-methyl-5-amino-phenol
1-methyl-2-hydroxy-4-amino-benzene
Rodol PAOC
4-Amino-2-hydroxytoluene
JAROCOL 2M5AP

5-氨基邻甲酚物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
268.6±20.0 °C at 760 mmHg

[ 熔点 ]:
160-162 °C(lit.)

[ 分子式 ]:
C₇H₉NO

[ 分子量 ]:
123.152

[ 闪点 ]:
116.3±21.8 °C

[ 精确质量 ]:
123.068413

[ PSA ]:
46.25000

[ LogP ]:
0.80

[ 外观性状 ]:
米色晶体

[ 蒸汽压 ]:
0.0±0.6 mmHg at 25°C

[ 折射率 ]:
1.616

[ 储存条件 ]:
库房通风低温干燥

5-氨基邻甲酚MSDS

5-氨基邻甲酚毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: SJ6090000

CHEMICAL NAME :: Phenol, 5-amino-2-methyl-

CAS REGISTRY NUMBER :: 2835-95-2

BEILSTEIN REFERENCE NO. :: 2802317

LAST UPDATED :: 199701

DATA ITEMS CITED :: 10

MOLECULAR FORMULA :: C7-H9-N-O

MOLECULAR WEIGHT :: 123.17

WISWESSER LINE NOTATION :: ZR CQ D1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3600 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - ataxia Skin and Appendages - hair

TYPE OF TEST :: LD - Lethal dose

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - quail

DOSE/DURATION :: 750 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - domestic

DOSE/DURATION :: 562 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 54 gm/kg/13W-C

TOXIC EFFECTS :: Endocrine - evidence of thyroid hypofunction Blood - changes in erythrocyte (RBC) count Nutritional and Gross Metabolic - weight loss or decreased weight gain

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 328 gm/kg/26W-C

TOXIC EFFECTS :: Liver - changes in liver weight Endocrine - changes in thyroid weight Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol)

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 333 ug/plate

REFERENCE :: EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 11(Suppl 12),1,1988 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5756 No. of Facilities: 4579 (estimated) No. of Industries: 2 No. of Occupations: 2 No. of Employees: 44842 (estimated) No. of Female Employees: 35032 (estimated)

5-氨基邻甲酚安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36-S37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
1

[ RTECS号 ]:
SJ6090000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1

[ 海关编码 ]:
2922299090

5-氨基邻甲酚合成路线

5-氨基邻甲酚上下游产品

5-氨基邻甲酚上游产品

5-氨基邻甲酚下游产品

5-氨基邻甲酚海关

[ 海关编码 ]: 2922299090

[ 中文概述 ]:
2922299090. 其他氨基(萘酚、酚)及醚、酯〔包括它们的盐, 但含有一种以上含氧基的除外〕. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乙醇胺及其盐应报明色度, 乙醇胺及其盐应报明包装

[ Summary ]:
2922299090. other amino-naphthols and other amino-phenols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

5-氨基邻甲酚文献

Benzoquinone imines. Part IX. Mechanism and kinetics of the reaction of p-benzoquinone di-imines with m-aminophenols.

J. Chem. Soc., Perkin Trans. II 5 , 539-548, (1972)

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