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1-环状己烯三氟甲烷磺酸

1-环状己烯三氟甲烷磺酸名称

[ CAS 号 ]:
28075-50-5

[ 中文名 ]:
1-环状己烯三氟甲烷磺酸

[ 英文名 ]:
1-Cyclohexen-1-yl trifluoromethanesulfonate

[英文别名 ]:

Cyclohexenyl triflate
1-Cyclohexenyl trifluoromethanesulfonate
Cyclohex-1-en-1-yl triflate
1-Cyclohexen-1-yl trifluoromethanesulfonate
1-cyclohexenyl triflate
trifluoromethanesulfonic acid 1-cyclohexenyl ester
cyclohex-1-en-1-yl trifluoromethanesulfonate
O-trifluoromethylsulfonyl-1-cyclohexenol
MFCD06411281
cyclohex-1-en-1-yl trifluoromethane sulfonate

1-环状己烯三氟甲烷磺酸物理化学性质

[ 密度 ]:
1.4±0.1 g/cm3

[ 沸点 ]:
244.6±40.0 °C at 760 mmHg

[ 分子式 ]:
C₇H₉F₃O₃S

[ 分子量 ]:
230.205

[ 闪点 ]:
101.7±27.3 °C

[ 精确质量 ]:
230.022446

[ PSA ]:
51.75000

[ LogP ]:
3.45

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.446

[ 储存条件 ]:
2-8℃

1-环状己烯三氟甲烷磺酸安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ 危险品运输编码 ]:
NA 1993 / PGIII

[ WGK德国 ]:
3

[ 海关编码 ]:
2906199090

1-环状己烯三氟甲烷磺酸合成路线

详细合成路线

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1-环状己烯三氟甲烷磺酸海关

[ 海关编码 ]: 2906199090

[ 中文概述 ]:
2906199090. 其他环烷醇，环烯醇及环萜烯醇. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2906199090. cyclanic, cyclenic or cyclotherpenic alcohols. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

1-环状己烯三氟甲烷磺酸文献

The palladium-catalyzed trifluoromethylation of vinyl sulfonates.

Org. Lett. 13(24) , 6552-5, (2011)

A method for the palladium-catalyzed trifluoromethylation of cyclohexenyl sulfonates has been developed. Various cyclohexenyl triflates and nonaflates underwent trifluoromethylation under mild reactio...

Proline derived phosphine-oxazoline ligands in the asymmetric Heck reaction. Gilbertson SR, et al.

Tetrahedron Lett. 42(3) , 365-368, (2001)

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