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苯亚甲基丙二腈

苯亚甲基丙二腈名称

[ CAS 号 ]:
2700-22-3

[ 中文名 ]:
苄烯丙二腈

[ 英文名 ]:
benzylidenemalononitrile

[中文别名 ]:

[英文别名 ]:

2-benzylidene-malononitrile
2-Phenyl-1,1-dicyanoethylene
MFCD00001855
EINECS 220-283-6
phenylmethylidenemalononitrile
Benzalmalononitrile
2,2-Dicyano-1-phenylethylene
MALONONITRILE,BENZYLIDENE
Benzylidenemalononitrile
2-(phenylmethylene)malononitrile

苯亚甲基丙二腈物理化学性质

[ 密度 ]:
1.154 g/cm3

[ 沸点 ]:
120-125°C 0,6mm

[ 熔点 ]:
83-85 °C(lit.)

[ 分子式 ]:
C₁₀H₆N₂

[ 分子量 ]:
154.16800

[ 闪点 ]:
120-125°C/0.6mm

[ 精确质量 ]:
154.05300

[ PSA ]:
47.58000

[ LogP ]:
2.11716

[ 外观性状 ]:
白色至灰白色粉末

[ 蒸汽压 ]:
0.00159mmHg at 25°C

[ 折射率 ]:
1.612

[ 储存条件 ]:
室温，干燥

苯亚甲基丙二腈MSDS

苯亚甲基丙二腈毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: OO3500000

CHEMICAL NAME :: Malononitrile, benzylidene-

CAS REGISTRY NUMBER :: 2700-22-3

LAST UPDATED :: 199209

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C10-H6-N2

MOLECULAR WEIGHT :: 154.18

WISWESSER LINE NOTATION :: NCYCN&1R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 40 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: BCPCA6 Biochemical Pharmacology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.1- 1958- Volume(issue)/page/year: 14,1325,1965

TYPE OF TEST :: LC - Lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >1450 mg/m3/10M

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NDRC** National Defense Research Committee, Office of Scientific Research and Development, Progress Report. Volume(issue)/page/year: NDCrc-132,Dec,1942

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 30 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NATUAS Nature. (Nature Subscription Dept., POB 1018, Manasguan, NJ 08736) V.1- 1869- Volume(issue)/page/year: 228,1315,1970

苯亚甲基丙二腈安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302 + H312 + H332-H315-H319-H335

[ 警示性声明 ]:
P261-P280-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
T:Toxic;

[ 风险声明 (欧洲) ]:
R23/24/25

[ 安全声明 (欧洲) ]:
S26-S36/37/39

[ 危险品运输编码 ]:
3276

[ WGK德国 ]:
3

[ RTECS号 ]:
OO3500000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1

[ 海关编码 ]:
2926909090

苯亚甲基丙二腈合成路线

苯亚甲基丙二腈上下游产品

苯亚甲基丙二腈上游产品

苯亚甲基丙二腈下游产品

苯亚甲基丙二腈海关

[ 海关编码 ]: 2926909090

[ 中文概述 ]:
2926909090 其他腈基化合物. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

苯亚甲基丙二腈文献

A mild and catalyst-free conversion of solid phase benzylidenemalononitrile/benzylidenemalonate to N-benzylidene-amine and its application for fluorescence detection of primary alkyl amine vapor.

Chem. Commun. (Camb.) 50(7) , 872-4, (2014)

A new rapid and catalyst-free solid/vapor reaction between benzylidenemalonate/benzylidenemalononitrile and primary alkyl amines was found. With these as sensory units of fluorescent polymers, probes ...

Direct addition of Zr-C bonds of alkylzirconocenes to activated alkenes.

J. Org. Chem. 67(20) , 7019-28, (2002)

Direct addition of alkylzirconocenes to activated alkenes was found, for the first time. Octyl- and decylzirconocene chloride reacted with benzylidenemalononitrile to give the corresponding addition p...

A rapid fluorescence-based assay for detecting soluble methane monooxygenase.

Appl. Microbiol. Biotechnol. 58(2) , 183-8, (2002)

A fluorescence-based assay was developed to estimate soluble methane monooxygenase (sMMO) activity in solution. Whole cells of Methylosinus trichosporium OB3b expressing sMMO were used to oxidize vari...

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