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1-甲酰哌啶

1-甲酰哌啶用途

用于格氏试剂的甲酰基转移。

1-甲酰哌啶名称

[ CAS 号 ]:
2591-86-8

[ 中文名 ]:
哌啶-1-甲醛

[ 英文名 ]:
Formylpiperidine

[中文别名 ]:

[英文别名 ]:

1-formylpiperidine
1-formyl-piperidin
1-Piperidinecarboxaldehyde
Piperidine-1-carboxaldehyde
N-Formylpiperidine
EINECS 219-986-0
Formylpiperidine
Piperidin-1-carbaldehyd
N-formyl piperidine
1-Piperidinecarbaldehyde

1-甲酰哌啶物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
222.5±9.0 °C at 760 mmHg

[ 熔点 ]:
-31 °C

[ 分子式 ]:
C₆H₁₁NO

[ 分子量 ]:
113.158

[ 闪点 ]:
91.7±0.0 °C

[ 精确质量 ]:
113.084061

[ PSA ]:
20.31000

[ LogP ]:
0.24

[ 外观性状 ]:
液体;Colorless to Light yellow to Light orange clear liquid

[ 蒸汽压 ]:
0.1±0.4 mmHg at 25°C

[ 折射率 ]:
1.551

[ 储存条件 ]:
存放于惰性气体之中;避免空气

[ 水溶解性 ]:
freely soluble

1-甲酰哌啶MSDS

1-甲酰哌啶毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TN0380000

CHEMICAL NAME :: Piperidine, 1-formyl-

CAS REGISTRY NUMBER :: 2591-86-8

LAST UPDATED :: 199710

DATA ITEMS CITED :: 8

MOLECULAR FORMULA :: C6-H11-N-O

MOLECULAR WEIGHT :: 113.18

WISWESSER LINE NOTATION :: T6NTJ AVH

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0534369 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 870 uL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0534315

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 840 uL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0534315

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 300 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: BDCGAS Berichte der Deutschen Chemischen Gesellschaft. (Leipzig, Ger. Dem. Rep.) V.1-61, 1868-1928. For publisher information, see CHBEAM. Volume(issue)/page/year: 34,2408,1901 ** REPRODUCTIVE DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

DOSE :: 6600 mg/kg

SEX/DURATION :: female 6-20 day(s) after conception

TOXIC EFFECTS :: Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants) Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus)

REFERENCE :: FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 18,96,1992

1-甲酰哌啶安全信息

[ 符号 ]:

GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H302-H311-H315-H319-H335

[ 警示性声明 ]:
P261-P280-P305 + P351 + P338-P312

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R21/22

[ 安全声明 (欧洲) ]:
S26-S36/37

[ 危险品运输编码 ]:
UN 2810 6.1/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
TN0380000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1(b)

[ 海关编码 ]:
29333999

1-甲酰哌啶合成路线

1-甲酰哌啶上下游产品

1-甲酰哌啶上游产品

1-甲酰哌啶下游产品

1-甲酰哌啶海关

[ 海关编码 ]: 2933399090

[ 中文概述 ]:
2933399090. 其他结构含非稠合吡啶环的化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

1-甲酰哌啶文献

The small GTPase ROP10 of Medicago truncatula is required for both tip growth of root hairs and nod factor-induced root hair deformation.

Plant Cell 27 , 806-22, (2015)

Rhizobia preferentially enter legume root hairs via infection threads, after which root hairs undergo tip swelling, branching, and curling. However, the mechanisms underlying such root hair deformatio...

Binding of formamides to liver alcohol dehydrogenase.

Biochemistry 36(12) , 3522-7, (1997)

Amides are analogs of aldehydes and potent inhibitors of liver alcohol dehydrogenases. They can be used for structural studies and for inhibiting the metabolism of alcohols that form toxic products. W...

Uncompetitive inhibitors of alcohol dehydrogenases.

Adv. Exp. Med. Biol. 463 , 295-303, (1999)

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