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三氯甲基磺酰氯

三氯甲基磺酰氯名称

[ CAS 号 ]:
2547-61-7

[ 中文名 ]:
三氯甲基磺酰氯

[ 英文名 ]:
Trichloromethanesulfonyl chloride

[中文别名 ]:

三氯甲烷磺酰氯

[英文别名 ]:

Trichlor-methansulfonylchlorid
Trichloromethane sulfonyl chloride
trichlormethanesulfonyl chloride
Trichloromethylsulfonyl chloride
Methanesulfonyl chloride,trichloro
EINECS 219-830-1
MFCD00007452
TrichloroMethanesulfonyl Chloride

三氯甲基磺酰氯物理化学性质

[ 密度 ]:
1.951g/cm3

[ 沸点 ]:
181.7ºC at 760mmHg

[ 熔点 ]:
137-140 °C(lit.)

[ 分子式 ]:
CCl₄O₂S

[ 分子量 ]:
217.88700

[ 闪点 ]:
63.7ºC

[ 精确质量 ]:
215.83700

[ PSA ]:
42.52000

[ LogP ]:
2.96350

[ 外观性状 ]:
固体;White to Almost white powder to crystal

[ 蒸汽压 ]:
1.14mmHg at 25°C

[ 折射率 ]:
1.536

[ 储存条件 ]:
存放于惰性气体之中;避免湿气 (分解)

[ 水溶解性 ]:
可溶于：甲苯

三氯甲基磺酰氯MSDS

详细MSDS(安全技术说明书)

三氯甲基磺酰氯安全信息

[ 符号 ]:

GHS05, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H314-H335

[ 警示性声明 ]:
P261-P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
C: Corrosive;

[ 风险声明 (欧洲) ]:
R34;R36/37

[ 安全声明 (欧洲) ]:
S26-S27-S28-S36/37/39-S45

[ 危险品运输编码 ]:
UN 3261 8/PG 2

[ WGK德国 ]:
3

[ 包装等级 ]:
III

[ 危险类别 ]:
8

[ 海关编码 ]:
2904909090

三氯甲基磺酰氯海关

[ 海关编码 ]: 2904909090

[ 中文概述 ]:
2904909090 其他烃的磺化、硝化、亚硝化衍生物（不论是否卤化）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

三氯甲基磺酰氯文献

TRICHLOROMETHANESULFONYL CHLORIDE AS A SELECTIVE CHLORINATING AGENT1. Huyser ES.

J. Am. Chem. Soc. 82(19) , 5246-47, (1960)

Homolytic displacement at saturated carbon. Part 9. The reactions of trichloromethanesulfonyl chloride with pent-4-enylcobaloximes and with olefins. A novel route to (trichloroethyl) sulfolanes via an SHi mechanism. Ashcroft MR, et al.

J. Org. Chem. 49(10) , 1751-61, (1984)

Reactions of trichloromethanesulfonyl chloride and carbon tetrachloride with silyl enol ethers catalyzed by a ruthenium (II) phosphine complex. Kamigata N, et al.

J. Organomet. Chem. 552(1) , 9-43, (1998)

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