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2,4,5-三溴咪唑

2,4,5-三溴咪唑名称

[ CAS 号 ]:
2034-22-2

[ 中文名 ]:
2,4,5-三溴咪唑

[ 英文名 ]:
2,4,5-Tribromoimidazole

[中文别名 ]:

2,4,5-三溴1-H-咪唑

[英文别名 ]:

2,4,5-TribroMoiMidazole
2,4,5-Tribrom-1H-imidazol
Imidazole,2,4,5-tribromo
tribromoimidazole
MFCD00005184
1H-Imidazole, 2,4,5-tribromo-
1H-Imidazole,2,4,5-tribromo
EINECS 217-997-5
2,4,5-Tribromo-1H-imidazole
2,4,5-Tribromo imidazole

2,4,5-三溴咪唑物理化学性质

[ 密度 ]:
2.8±0.1 g/cm3

[ 沸点 ]:
401.3±48.0 °C at 760 mmHg

[ 熔点 ]:
217-220 °C (dec.)(lit.)

[ 分子式 ]:
C₃HBr₃N₂

[ 分子量 ]:
304.765

[ 闪点 ]:
196.5±29.6 °C

[ 精确质量 ]:
301.768951

[ PSA ]:
28.68000

[ LogP ]:
2.20

[ 外观性状 ]:
米色-黄色粉末

[ 蒸汽压 ]:
0.0±0.9 mmHg at 25°C

[ 折射率 ]:
1.690

[ 储存条件 ]:
Refrigerator (+4°C)

2,4,5-三溴咪唑MSDS

2,4,5-三溴咪唑毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: NI8660000

CHEMICAL NAME :: Imidazole, 2,4,5-tribromo-

CAS REGISTRY NUMBER :: 2034-22-2

BEILSTEIN REFERENCE NO. :: 0115314

LAST UPDATED :: 199612

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C3-H-Br3-N2

MOLECULAR WEIGHT :: 304.79

WISWESSER LINE NOTATION :: T5M CNJ BE DE EE

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 34 mg/kg

TOXIC EFFECTS :: Behavioral - tremor Lungs, Thorax, or Respiration - respiratory stimulation Nutritional and Gross Metabolic - body temperature increase

REFERENCE :: ARTODN Archives of Toxicology. (Springer-Verlag, Heidelberger Pl. 3, D-1000 Berlin 33, Fed. Rep. Ger.) V.32- 1974- Volume(issue)/page/year: 56,109,1984

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 15 mg/kg

TOXIC EFFECTS :: Behavioral - tremor Lungs, Thorax, or Respiration - respiratory stimulation Nutritional and Gross Metabolic - body temperature increase

REFERENCE :: ARTODN Archives of Toxicology. (Springer-Verlag, Heidelberger Pl. 3, D-1000 Berlin 33, Fed. Rep. Ger.) V.32- 1974- Volume(issue)/page/year: 56,109,1984

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 40 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - tremor Nutritional and Gross Metabolic - body temperature increase

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 89,175,1987

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 18 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#05092

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - gerbil

DOSE/DURATION :: >40 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - tremor Nutritional and Gross Metabolic - body temperature increase

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 89,175,1987

2,4,5-三溴咪唑安全信息

[ 符号 ]:

GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H300-H311 + H331-H315-H319-H335

[ 警示性声明 ]:
P261-P264-P280-P301 + P310-P305 + P351 + P338-P311

[ 个人防护装备 ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
T:Toxic;

[ 风险声明 (欧洲) ]:
R23/24/25;R36/37/38

[ 安全声明 (欧洲) ]:
S22-S26-S36/37/39-S45

[ 危险品运输编码 ]:
UN 2811 6.1/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
NI8660000

[ 包装等级 ]:
II

[ 危险类别 ]:
6.1

2,4,5-三溴咪唑合成路线

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2,4,5-三溴咪唑文献

Semiconductor-mediated photocatalysed degradation of two selected pesticide derivatives, terbacil and 2,4,5-tribromoimidazole, in aqueous suspension.

Water Sci. Technol. 44(5) , 331-7, (2001)

The photocatalysed degradation of two selected pesticide derivatives, namely 3-tert-butyl-5-chloro-6-methyluracil (terbacil) and 2,4,5-tribromoimidazole (TBI) has been investigated in aqueous suspensi...

Synthesis and antiviral evaluation of polyhalogenated imidazole nucleosides: dimensional analogues of 2,5,6-trichloro-1-(beta-D-ribofuranosyl)benzimidazole.

J. Med. Chem. 47(23) , 5743-52, (2004)

A series of polyhalogenated imidazole nucleosides were designed and synthesized as ring-contracted analogues of 2,5,6-trichloro-1-(beta-D-ribofuranosyl)benzimidazole (TCRB) and its 2-bromo analogue (B...

The toxicity and neuropathology of 2,4,5-tribromoimidazole and its derivatives in rats.

Arch. Toxicol. 56(2) , 109-12, (1984)

2,4,5-tribromoimidazole and its 1-n-butylcarboxylate and 1-dimethylcarbamoyl derivatives, when administered to rats, induced poisoning typical of uncouplers of oxidative phosphorylation. At 48 h rats ...

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