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[双(2-甲氧基乙基)胺]三氟化硫

[双(2-甲氧基乙基)胺]三氟化硫名称

[ CAS 号 ]:
202289-38-1

[ 中文名 ]:
[双(2-甲氧基乙基)胺]三氟化硫

[ 英文名 ]:
Bis(2-methoxyethyl)aminosulphur trifluoride

[中文别名 ]:

[英文别名 ]:

DeoxofluorTM
MFCD01321415
UNII-A6219390VZ
diethylaminosulfur trifluoride
Sulfur, [bis(2-methoxyethyl)amino]trifluoro-
Bis-(2-methoxyethyl)aminosulfur trifluoride
Deoxo-Fluor solution
EINECS 478-190-3
Deoxo-Fluor
[Bis(2-methoxyethyl)amino]sulfur trifluoride,2.7M

[双(2-甲氧基乙基)胺]三氟化硫物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
256.3±25.0 °C at 760 mmHg

[ 分子式 ]:
C₆H₁₄F₃NO₂S

[ 分子量 ]:
221.241

[ 闪点 ]:
108.8±23.2 °C

[ 精确质量 ]:
221.069733

[ PSA ]:
47.00000

[ LogP ]:
1.95430

[ 外观性状 ]:
暗黄色-橙色液体

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.392

[ 储存条件 ]:
2-8°C

[双(2-甲氧基乙基)胺]三氟化硫MSDS

[双(2-甲氧基乙基)胺]三氟化硫安全信息

[ 符号 ]:

GHS02, GHS05, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H261-H301-H314-H331

[ 补充危害声明 ]:
Contact with water liberates toxic gas., Reacts violently with water.

[ 警示性声明 ]:
P231 + P232-P261-P280-P301 + P310-P305 + P351 + P338-P422

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F:Flammable;T:Toxic;

[ 风险声明 (欧洲) ]:
R11;R14;R25;R35;R48/20;R63;R65;R67

[ 安全声明 (欧洲) ]:
23-26-36/37/39-43-45-8-62-46-25-16

[ 危险品运输编码 ]:
UN REST

[ WGK德国 ]:
3

[双(2-甲氧基乙基)胺]三氟化硫合成路线

[双(2-甲氧基乙基)胺]三氟化硫文献

[Bis(2-methoxyethyl)amino]sulfur trifluoride, the Deoxo-Fluor reagent: application toward one-flask transformations of carboxylic acids to amides.

J. Org. Chem. 69 , 2573, (2004)

The use of the Deoxo-Fluor reagent is a versatile method for acyl fluoride generation and subsequent one-flask amide coupling. It provides mild conditions and facile purification of the desired produc...

Fluorination of thiocarbonyl compounds with Bis(2-methoxyethyl)aminosulfur trifluoride (Deoxo-fluor reagent): A facile synthesis of gem-difluorides

J. Org. Chem. 65 , 4830, (2000)

A variety of thiocarbonyl derivatives (thioketone, thioester, thioamide, dithioester, and dithiocarbamate) were converted to the corresponding gem-difluorides in excellent yields on reaction with the ...

One-pot route to new alpha,alpha-difluoroamides and alpha-ketoamides.

J. Org. Chem. 68 , 6063, (2003)

New alpha,alpha-difluoroamides (4a-d, 6a-d) and alpha-ketoamides (5a-d, 7a-d) result from one-pot reactions of alpha-ketoacids, RCOCO(2)H (R = C(6)H(5), CH(3), CH(3)CH(2), thienyl) (1a-d) with bis(2-m...

更多文献

[双(2-甲氧基乙基)胺]三氟化硫

[双(2-甲氧基乙基)胺]三氟化硫名称

[双(2-甲氧基乙基)胺]三氟化硫物理化学性质

[双(2-甲氧基乙基)胺]三氟化硫MSDS

详细MSDS(安全技术说明书)

[双(2-甲氧基乙基)胺]三氟化硫安全信息

[双(2-甲氧基乙基)胺]三氟化硫合成路线

详细合成路线

[双(2-甲氧基乙基)胺]三氟化硫文献

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