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六氯丙烯

六氯丙烯用途

【用途一】
用于有机合成。

六氯丙烯名称

[ CAS 号 ]:
1888-71-7

[ 中文名 ]:
六氯丙烯

[ 英文名 ]:
Hexachloropropene

[中文别名 ]:

全氯丙烯

[英文别名 ]:

1,1,2,3,3,3-Hexachloro-1-propene
MFCD00000835
Hexachloropropene
Perchloropropylene
2-chloro-1,1,3,3,3-pentachloropropene
EINECS 217-560-9
RCRA waste no. U243
1,1,2,3,3,3-hexachloroprop-1-ene
PERCHLOROPROPENE
Hexachloropropylene

六氯丙烯物理化学性质

[ 密度 ]:
1.8±0.1 g/cm3

[ 沸点 ]:
209.5±0.0 °C at 760 mmHg

[ 熔点 ]:
-73°C

[ 分子式 ]:
C₃Cl₆

[ 分子量 ]:
248.750

[ 闪点 ]:
69.9±23.3 °C

[ 精确质量 ]:
245.813110

[ LogP ]:
6.08

[ 外观性状 ]:
无色液体

[ 蒸汽密度 ]:
8.3 (vs air)

[ 蒸汽压 ]:
0.3±0.4 mmHg at 25°C

[ 折射率 ]:
1.554

[ 储存条件 ]:
室温

[ 稳定性 ]:
Stable. Incompatible with strong oxidizing agents.

六氯丙烯MSDS

六氯丙烯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: UD0175000

CHEMICAL NAME :: Propene, hexachloro-

CAS REGISTRY NUMBER :: 1888-71-7

BEILSTEIN REFERENCE NO. :: 1766640

LAST UPDATED :: 199710

DATA ITEMS CITED :: 9

MOLECULAR FORMULA :: C3-Cl6

MOLECULAR WEIGHT :: 248.73

WISWESSER LINE NOTATION :: GYGUYGXGGG

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 425 ppm/30M

TOXIC EFFECTS :: Behavioral - excitement Lungs, Thorax, or Respiration - dyspnea Liver - hepatitis (hepatocellular necrosis), diffuse

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 400 uL/kg

TOXIC EFFECTS :: Liver - hepatitis (hepatocellular necrosis), diffuse Kidney, Ureter, Bladder - changes in tubules (including acute renal failure, acute tubular necrosis)

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 300 ppm/30M

TOXIC EFFECTS :: Behavioral - excitement Lungs, Thorax, or Respiration - dyspnea

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 85 ppm/30M

TOXIC EFFECTS :: Behavioral - excitement Lungs, Thorax, or Respiration - dyspnea

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 15 umol/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 170,1,1986 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X6277 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 1822 (estimated) No. of Female Employees: 272 (estimated)

六氯丙烯安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H332-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T:Toxic;

[ 风险声明 (欧洲) ]:
R23;R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45

[ 危险品运输编码 ]:
UN 3382 6.1/PG 1

[ WGK德国 ]:
3

[ RTECS号 ]:
UD0175000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1

[ 海关编码 ]:
2903299090

六氯丙烯合成路线

六氯丙烯制备

将1,1,1,2,2,3,3-七氯丙烷溶于乙醇，保持30-40℃，滴加乙醇钾溶液，然后加热回流1h。将反应物中乙醇蒸出回收，冷却后倾入水中分层，取有机层用水洗涤，干燥，减压蒸馏，收集98-100℃（2.67kPa）馏分，得六氯丙烯，收率86.7-89.2

六氯丙烯海关

[ 海关编码 ]: 2903299090

[ 中文概述 ]:
HS: 2903299090. 其他无环烃的不饱和氯化衍生物. 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2903299090 other unsaturated chlorinated derivatives of acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

六氯丙烯文献

Mutagenicity of chloroolefins in the Salmonella/mammalian microsome test. III. Metabolic activation of the allylic chloropropenes allyl chloride, 1,3-dichloropropene, 2,3-dichloro-1-propene, 1,2,3-trichloropropene, 1,1,2,3-tetrachloro-2-propene and hexachloropropene by S9 mix via two different metabolic pathways.

Mutat. Res. 170(1-2) , 1-9, (1986)

In the presence of S9 mix all allylic chloropropenes tested exert considerable indirect mutagenic activity which is most pronounced for 1,2,3-trichloropropene. Lower as well as higher chlorinated deri...

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