杀虫磺

杀虫磺用途

【用途一】
用于防治水稻二化螟、三化螟、小菜蛾、马铃薯象甲、葡萄缀穗蛾等鳞翅目和鞘翅目害虫
【用途二】
该品具有胃毒、触杀作用,使害虫麻痹中毒拒食而死亡。可在马铃薯、玉米、水稻上防治多种害虫,对水稻螟虫、马铃薯甲虫、小菜蛾等鳞翅目和鞘翅目害虫有很强的杀灭作用。

杀虫磺名称

[ CAS 号 ]:
17606-31-4

[ 中文名 ]:
杀虫磺

[ 英文名 ]:
bensultap

[中文别名 ]:

[英文别名 ]:

杀虫磺物理化学性质

[ 密度 ]:
1.353g/cm3

[ 沸点 ]:
590.8ºC at 760mmHg

[ 熔点 ]:
82 - 83ºC

[ 分子式 ]:
C17H21NO4S4

[ 分子量 ]:
431.61300

[ 闪点 ]:
311.1ºC

[ 精确质量 ]:
431.03500

[ PSA ]:
138.88000

[ LogP ]:
5.32240

[ 蒸汽压 ]:
6.22E-14mmHg at 25°C

[ 折射率 ]:
1.62

[ 储存条件 ]:
0-6°C

杀虫磺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DB8000000
CHEMICAL NAME :
Benzenesulfonic acid, thio-, S,S'-(2-(dimethylamino)trimethylene) ester
CAS REGISTRY NUMBER :
17606-31-4
LAST UPDATED :
199612
DATA ITEMS CITED :
18
MOLECULAR FORMULA :
C17-H21-N-O4-S4
MOLECULAR WEIGHT :
431.63
WISWESSER LINE NOTATION :
WSR&S1YN1&1&1SSWR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1105 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>700 mg/m3
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - ptosis Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
438 mg/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - ptosis Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1160 mg/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - ptosis Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
415 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
343 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1202 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - chicken
DOSE/DURATION :
103 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - quail
DOSE/DURATION :
60 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
5460 mg/kg/13W-C
TOXIC EFFECTS :
Liver - changes in liver weight Kidney, Ureter, Bladder - changes in bladder weight Blood - pigmented or nucleated red blood cells
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
21840 mg/kg/2Y-C
TOXIC EFFECTS :
Cardiac - changes in heart weight Liver - multiple effects Liver - changes in liver weight
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
3276 mg/kg/13W-C
TOXIC EFFECTS :
Liver - other changes Blood - normocytic anemia Blood - changes in bone marrow (not otherwise specified)
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
43680 mg/kg/1Y-C
TOXIC EFFECTS :
Gastrointestinal - other changes Kidney, Ureter, Bladder - other changes Blood - changes in erythrocyte (RBC) count
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
87360 mg/kg/2Y-C
TOXIC EFFECTS :
Blood - pigmented or nucleated red blood cells Blood - other changes Blood - changes in leukocyte (WBC) count
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
18200 mg/kg/1Y-C
TOXIC EFFECTS :
Liver - changes in liver weight Blood - normocytic anemia Nutritional and Gross Metabolic - weight loss or decreased weight gain
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
660 mg/kg
SEX/DURATION :
female 7-17 day(s) after conception
TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - musculoskeletal system

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Human Lymphocyte
DOSE/DURATION :
1 mg/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 241,109,1990

杀虫磺安全信息

[ 符号 ]:

GHS07, GHS09

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302-H410

[ 警示性声明 ]:
P273-P501

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xn: Harmful;N: Dangerous for the environment;

[ 风险声明 (欧洲) ]:
R22

[ 安全声明 (欧洲) ]:
S60-S61

[ 危险品运输编码 ]:
UN3077 9/PG 3

[ RTECS号 ]:
DB8000000

[ 海关编码 ]:
2930909065

杀虫磺制备

2-N,N-二甲氨基-1,3-二氯丙烷与硫代苯磺酸钠在乙醇中回流反应而制得。

杀虫磺海关

[ 海关编码 ]: 2930909065

[ 中文概述 ]:
2930909065 硫线磷、氯甲硫磷、杀虫磺等〔包括砜吸磷、砜拌磷、异拌磷、三硫磷、芬硫磷〕。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ 监管条件 ]: S.进出口农药登记证明

[ Summary ]:
2930909065 s-(2-(isopropylthio)ethyl) o,o-dimethyl phosphorodithioate

杀虫磺文献

[Experimental studies on antidotes for the insecticides bancol and nereistoxin acute poisoning].

Zhonghua Yu Fang Yi Xue Za Zhi 21(3) , 149-51, (1987)

[Detection of bancol for the purpose of forensic chemical expertise].

Sud. Med. Ekspert. 53(6) , 39-41, (2010)

Optimal conditions for the extraction of bancol from the biological material with toluene are described. The possibility of its purification and separation from co-extracted compounds on a silicagel L...

[Detection of bensultap (bancol) derivatives and metabolites by chromatographic methods].

Sud. Med. Ekspert. 52(5) , 30-5, (2009)

This paper is designed to describe methods for the detection of derivatives and metabolites of the insecticidic agent bancol (nereistoxin precursor) by chromatographic methods including thin layer chr...


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标题:杀虫磺_用途_密度_熔点_杀虫磺CAS号【17606-31-4】_化源网 地址:https://www.chemsrc.com/amp/cas/17606-31-4_402139.html