<生产厂家价格>

高氯酸锰六水合物

高氯酸锰六水合物名称

[ CAS 号 ]:
15364-94-0

[ 中文名 ]:
高氯酸锰六水合物

[ 英文名 ]:
manganese (ii) perchlorate

[中文别名 ]:

[英文别名 ]:

Manganese(II) perchlorate hexahydrate
MFCD00150255
EINECS 237-390-9

高氯酸锰六水合物物理化学性质

[ 密度 ]:
2.100

[ 熔点 ]:
165ºC

[ 分子式 ]:
Cl₂H₁₂MnO₁₄

[ 分子量 ]:
361.93100

[ 精确质量 ]:
360.89800

[ PSA ]:
203.92000

[ LogP ]:
0.04280

[ 外观性状 ]:
Crystalline Solid | Pink

[ 储存条件 ]:
库房通风,轻装轻卸,与有机物、还原剂、硫磷易燃物分开存放

[ 稳定性 ]:
hygroscopic

[ 水溶解性 ]:
Soluble in benzene, ethyl acetate | Soluble in water, benzene, ethyl acetate

高氯酸锰六水合物MSDS

详细MSDS(安全技术说明书)

高氯酸锰六水合物毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: SC9275000

CHEMICAL NAME :: Perchloric acid, manganese(2+) salt, hexahydrate

CAS REGISTRY NUMBER :: 15364-94-0

LAST UPDATED :: 199712

DATA ITEMS CITED :: 20

MOLECULAR FORMULA :: Cl2-O8.Mn.6H2-O

MOLECULAR WEIGHT :: 361.96

WISWESSER LINE NOTATION :: MN G-O4*2 &QH 6

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 410 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JAFCAU Journal of Agricultural and Food Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC 20037) V.1- 1953- Volume(issue)/page/year: 14,512,1966 *** REVIEWS *** ACGIH TLV-TWA 0.2 mg(Mn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:CL 5 mg(Mn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,149,1971 OSHA PEL (Gen Indu):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 5 mg(Mn)/m3 JAN 1993 OEL-BELGIUM:TWA 5 mg(Mn)/m3 JAN 1993 OEL-DENMARK:TWA 2.5 mg(Mn)/m3 JAN 1993 OEL-FINLAND:TWA 2.5 mg(Mn)/m3 JAN 1993 OEL-HUNGARY:TWA 0.3 mg(Mn)/m3;STEL 0.6 mg(Mn)/m3 JAN 1993 OEL-JAPAN:TWA 0.3 mg(Mn)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg(Mn)/m3 JAN 1993 OEL-POLAND:TWA 0.3 mg(Mn)/m3 JAN 1993 OEL-SWEDEN:TWA 1 mg(Mn)/m3;STEL 2.5 mg(Mn)/m3 (resp. dust) JAN 1993 OEL-SWEDEN:TWA 2.5 mg(Mn)/m3;STEL 5 mg(Mn)/m3 (total dust) JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg(Mn)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

高氯酸锰六水合物安全信息

[ 危害码 (欧洲) ]:
O,Xi

[ 风险声明 (欧洲) ]:
R8

[ 安全声明 (欧洲) ]:
S15

[ 危险品运输编码 ]:
UN 1481 5.1/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
SC9275000

[ 包装等级 ]:
II

[ 危险类别 ]:
5.1

高氯酸锰六水合物制备

把过量的（5mL）无水高氯酸在-80℃（用干冰冷却）加到大约2g无水硝酸锰中。此时没有反应发生，缓慢升温至0℃以下开始反应。放置过夜。抽真空除去过量的高氯酸，在110℃，真空下至恒重，得水合高氯酸锰。