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4-羧基苯硼酸

4-羧基苯硼酸用途

4-硼酸是一种生物化学试剂,可作为生物材料或有机化合物用于生命科学相关研究。

4-羧基苯硼酸名称

[ CAS 号 ]:
14047-29-1

[ 中文名 ]:
4-羧基苯硼酸

[ 英文名 ]:
p-Boronobenzoic acid

[中文别名 ]:

[英文别名 ]:

4-(Dihydroxyboryl)benzoic acid
Benzoic acid, 4-borono-
4-Carboxybenzeneboronic Acid
4-Boronobenzoic acid
MFCD00151801
4-Carboxyphenylboronic acid
p-Carboxybenzeneboronic acid
p-Boronobenzoic acid
4-(dihydroxyboranyl)benzoic acid

4-羧基苯硼酸生物活性

[ 描述 ]:

4-硼酸是一种生物化学试剂,可作为生物材料或有机化合物用于生命科学相关研究。

[ 相关类别 ]:

研究领域 >> 其他

信号通路 >> 其他 >> 其他

4-羧基苯硼酸物理化学性质

[ 密度 ]:
1.4±0.1 g/cm3

[ 沸点 ]:
406.4±47.0 °C at 760 mmHg

[ 熔点 ]:
220 °C (dec.)(lit.)

[ 分子式 ]:
C₇H₇BO₄

[ 分子量 ]:
165.94

[ 闪点 ]:
199.6±29.3 °C

[ 精确质量 ]:
166.043747

[ PSA ]:
77.76000

[ LogP ]:
1.27

[ 外观性状 ]:
无气味的白色-灰白色粉末

[ 蒸汽压 ]:
0.0±1.0 mmHg at 25°C

[ 折射率 ]:
1.585

[ 储存条件 ]:
0-6°C

[ 水溶解性 ]:
可溶于：甲醇

4-羧基苯硼酸MSDS

4-羧基苯硼酸毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: CY8925000

CHEMICAL NAME :: Benzeneboronic acid, p-carboxy-

CAS REGISTRY NUMBER :: 14047-29-1

BEILSTEIN REFERENCE NO. :: 3031088

LAST UPDATED :: 199712

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C7-H7-B-O4

MOLECULAR WEIGHT :: 165.95

WISWESSER LINE NOTATION :: VHOR DBQQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >3 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: APYPAY Acta Physiologica Polonica. (Karger-Libri, POB CH-4009, Warszawa, Switzerland) V.1-41, 1950-90. Volume(issue)/page/year: 12,173,1961

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1740 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New York, John Wiley & Sons, Inc., 1964 Volume(issue)/page/year: -,693,1964

4-羧基苯硼酸安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xi:Irritant

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S37/39-S26

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
2

[ RTECS号 ]:
CY8925000

4-羧基苯硼酸合成路线

4-羧基苯硼酸上下游产品

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4-羧基苯硼酸文献

Highly efficient aerobic oxidative hydroxylation of arylboronic acids: photoredox catalysis using visible light.

Angew. Chem. Int. Ed. Engl. 3rd ed., 51 , 784-788, (2012)

A new access to 3-substituted-1(2H)-isoquinolone by tandem palladium-catalyzed intramolecular aminocarbonylation annulation.

Org. Biomol. Chem. 13th ed., 10 , 2683-2691, (2012)

An original tribromide derivative based, palladium-catalyzed synthesis of 3-substituted-1(2H)-isoquinolone is described based on a regioselective Suzuki-Miyaura C-C coupling on o-halo-(2,2-dihalovinyl...

Synthesis of new trisulfonated calix[4]arenes functionalized at the upper rim, and their complexation with the trimethyllysine epigenetic mark.

Org. Lett. 6th ed., 14 , 1512-1515, (2012)

A synthetic route to produce a new family of trisulfonated calix[4]arenes bearing a single group, selectively introduced, that lines the binding pocket is reported. Ten examples, including new sulfona...

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