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二正丁基二硫代氨基甲酸镍

二正丁基二硫代氨基甲酸镍用途

可用作聚丙烯的光稳定剂，并广泛用作合成橡胶的抗臭氧剂和光稳定剂

二正丁基二硫代氨基甲酸镍名称

[ CAS 号 ]:
13927-77-0

[ 中文名 ]:
双(二丁氨基二硫代甲酸)镍

[ 英文名 ]:
Nickel dibutyldithiocarbamate

[中文别名 ]:

[英文别名 ]:

Perkacit NDBC
Dibutyldithiocarbamic Acid Nickel(II) Salt
Nickel dibutyldithiocarbamate
Nickel(2+) bis(dibutylcarbamodithioate)
Naugard NBC
EINECS 237-696-2
MFCD00067273
Antiozonant NIBUD
Nickel(II) Bis(dibutyldithiocarbamate)
Nickel(II) dibutyldithiocarbamate

二正丁基二硫代氨基甲酸镍物理化学性质

[ 密度 ]:
1,26 g/cm3

[ 沸点 ]:
257.7ºC at 760mmHg

[ 熔点 ]:
86°C

[ 分子式 ]:
C₁₈H₃₆N₂NiS₄

[ 分子量 ]:
467.445

[ 闪点 ]:
260°C

[ 精确质量 ]:
466.111481

[ PSA ]:
121.26000

[ LogP ]:
6.73950

[ 外观性状 ]:
绿色至暗绿色油状

[ 蒸汽压 ]:
0.0144mmHg at 25°C

[ 储存条件 ]:
库房通风低温干燥

[ 水溶解性 ]:
水溶性：实际上不溶；易溶于：苯,甲苯,氯仿,丙酮；微溶：甲醇,乙醇

二正丁基二硫代氨基甲酸镍MSDS

详细MSDS(安全技术说明书)

二正丁基二硫代氨基甲酸镍毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: QR6140000

CHEMICAL NAME :: Nickel, bis(dibutyldithiocarbamato)-

CAS REGISTRY NUMBER :: 13927-77-0

LAST UPDATED :: 199710

DATA ITEMS CITED :: 8

MOLECULAR FORMULA :: C18-H36-N2-Ni-S4

MOLECULAR WEIGHT :: 467.51

WISWESSER LINE NOTATION :: 4N4&YUS&S 2-NI-

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 17 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: IPSTB3 International Polymer Science and Technology. (Rapra Technology Ltd., Shawbury, Shrewsbury, Shropshire SY4 4NR, UK) Volume(issue)/page/year: 3,93,1976 ** TUMORIGENIC DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 22 mg/kg/78W-I

TOXIC EFFECTS :: Tumorigenic - equivocal tumorigenic agent by RTECS criteria Lungs, Thorax, or Respiration - tumors Liver - tumors

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: PB223-159

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1000 mg/kg

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: PB223-159 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO NICKEL, INORGANIC-air:10H CA TWA 0.015 mg(Ni)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84025 No. of Facilities: 16 (estimated) No. of Industries: 2 No. of Occupations: 4 No. of Employees: 166 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 84025 No. of Facilities: 207 (estimated) No. of Industries: 2 No. of Occupations: 13 No. of Employees: 7058 (estimated) No. of Female Employees: 236 (estimated)

二正丁基二硫代氨基甲酸镍安全信息

[ 危害码 (欧洲) ]:
Xi

[ RTECS号 ]:
QR6140000

[ 海关编码 ]:
3812309000

二正丁基二硫代氨基甲酸镍合成路线

详细合成路线

二正丁基二硫代氨基甲酸镍上下游产品

二正丁基二硫代氨基甲酸镍上游产品

二正丁基二硫代氨基甲酸镍下游产品

二正丁基二硫代氨基甲酸镍制备

（1）二丁基二硫代氨基甲酸钠的合成将二丁胺、二硫化碳和烧碱以1.02∶1∶1（mol）的配比加入反应釜，搅拌下于25～30℃反应，生成二丁基二硫代氨基甲酸钠溶液。

（2）N,N-二正丁基二硫代氨基甲酸镍的合成在二丁基二硫代氨基甲酸钠溶液中加入浓度为40%～50%的氯化镍溶液，搅拌下于20～30℃进行复分解反应，反应产物以固体析出。经过滤、水洗、干燥，即得成品。

二正丁基二硫代氨基甲酸镍海关

[ 海关编码 ]: 2930909090

[ 中文概述 ]:
2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%