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高铼酸钠

高铼酸钠名称

[ CAS 号 ]:
13472-33-8

[ 中文名 ]:
高铼酸钠

[ 英文名 ]:
Sodium perrhenate, 99.99% metals basis

[中文别名 ]:

过铼酸钠

[英文别名 ]:

MFCD00014231
EINECS 236-742-9
sodium,oxido(trioxo)rhenium

高铼酸钠物理化学性质

[ 密度 ]:
5.39

[ 熔点 ]:
300ºC

[ 分子式 ]:
NaO₄Re

[ 分子量 ]:
273.19400

[ 精确质量 ]:
273.92500

[ PSA ]:
74.27000

[ 储存条件 ]:
室温

高铼酸钠MSDS

详细MSDS(安全技术说明书)

高铼酸钠毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: WD3675000

CHEMICAL NAME :: Sodium perrhenate

CAS REGISTRY NUMBER :: 13472-33-8

LAST UPDATED :: 199701

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: Na.O4-Re

MOLECULAR WEIGHT :: 273.19

WISWESSER LINE NOTATION :: NA RE-O4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1050 mg/kg

TOXIC EFFECTS :: Behavioral - rigidity (including catalepsy) Lungs, Thorax, or Respiration - dyspnea Lungs, Thorax, or Respiration - cyanosis

REFERENCE :: PSEBAA Proceedings of the Society for Experimental Biology and Medicine. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1903/04- Volume(issue)/page/year: 45,576,1940

高铼酸钠安全信息

[ 符号 ]:

GHS03, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H272-H315-H319-H335

[ 警示性声明 ]:
P220-P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
O: Oxidizing agent;Xi: Irritant;

[ 风险声明 (欧洲) ]:
R8

[ 安全声明 (欧洲) ]:
S17;S26;S27;S36/S37/S39

[ 危险品运输编码 ]:
UN 1479

[ RTECS号 ]:
WD3675000

[ 包装等级 ]:
II

[ 危险类别 ]:
5.1

高铼酸钠制备

1.用高铼酸溶解氢氧化钠或碳酸钠生成。

2.由五氯化铼与氢氧化钠水溶液一起加热，得高铼酸钠的白色烟雾和ReO2·xH2O黑色沉淀。

高铼酸钠文献

Non-Complexing Anions for Quantitative Speciation Studies Using Raman Spectroscopy in Fused Silica High-Pressure Optical Cells Under Hydrothermal Conditions.

Appl. Spectrosc. 69 , 972-83, (2015)

This paper reports methods for obtaining time-dependent reduced isotropic Raman spectra of aqueous species in quartz capillary high-pressure optical cells under hydrothermal conditions, as a means of ...

Implication of cysteine residues in the selection of oxorhenium inhibitors of cyclophilin hCyp18.

Metallomics 4(2) , 179-87, (2012)

The dynamic combinatorial assembly of libraries of modular cyclophilin hCyp18 oxorhenium inhibitors of general formula [A˙ReO˙B] was accelerated by addition of increasing concentrations of hCyp18 ('Cy...

Immobilization, trapping, and anion exchange of perrhenate ion using copper-based tripodal complexes.

Inorg. Chem. 50(19) , 9499-507, (2011)

We describe a multidentate tripodal ligand in which three pendant arms carrying di(2-picolyl)amine units are linked to the ortho positions of a tris(o-xylyl) scaffold, providing N(CH(2)-o-C(6)H(4)CH(2...

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