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黄色氧化铅

黄色氧化铅用途

1.用于制造聚氯乙烯塑料稳定剂。是其他铅盐的原料。在油漆工业中与油制成铅皂，用作油漆中的催干剂。

2.用于制造高折射率光学玻璃、陶瓷瓷釉、精密机床的平面研磨剂，是医用原料、橡胶着色剂。还用于蓄电池极板制造及石油精制等。

3.用于电子管、显像管、光学玻璃和防Ｘ射线的铅玻璃及防辐射橡胶制品。

4.用于化学分析，如测定金和银，沉淀氨基酸。冶金助熔剂，油漆催干剂。也用于玻璃和橡胶工业。能与甘油混合生成坚硬物，作为胶黏剂。

5.一氧化铅用于镀铅及合金中可溶性铅盐的配制，如氟硼酸铅的配制等。

6.用作颜料、冶金助熔剂、油漆催干剂、橡胶硫化促进剂、杀虫剂等。

黄色氧化铅名称

[ CAS 号 ]:
1317-36-8

[ 中文名 ]:
黄色氧化铅

[ 英文名 ]:
Lead monoxide

[中文别名 ]:

[英文别名 ]:

Lead Monoxide
EINECS 215-267-0
oxolead
MFCD00011164
Lead(II) oxide

黄色氧化铅物理化学性质

[ 密度 ]:
9.53

[ 沸点 ]:
1470ºC

[ 熔点 ]:
886ºC

[ 分子式 ]:
OPb

[ 分子量 ]:
223.19900

[ 精确质量 ]:
223.97200

[ PSA ]:
17.07000

[ 外观性状 ]:
黄色粉末

[ 蒸汽压 ]:
10 mm Hg ( 0 °C)

[ 折射率 ]:
2.67

[ 储存条件 ]:
库房通风低温干燥,与食品添加剂分开存放

[ 稳定性 ]:
Stable. Reacts violently with hydrogen peroxide, strong oxidizing agents, aluminium, zirconium, halogens, sulphur trioxide, boron, silicon, sodium, zinc.

黄色氧化铅MSDS

详细MSDS(安全技术说明书)

黄色氧化铅毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: OG1750000

CHEMICAL NAME :: Lead monoxide

CAS REGISTRY NUMBER :: 1317-36-8

LAST UPDATED :: 199712

DATA ITEMS CITED :: 33

MOLECULAR FORMULA :: O-Pb

MOLECULAR WEIGHT :: 223.19

WISWESSER LINE NOTATION :: PB O

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 430 mg/kg

TOXIC EFFECTS :: Blood - other changes

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Mammal - dog

DOSE/DURATION :: 1400 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 10 ug/m3/24H/22W-C

TOXIC EFFECTS :: Brain and Coverings - recordings from specific areas of CNS Blood - changes in bone marrow (not otherwise specified) Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase

MUTATION DATA

TYPE OF TEST :: Morphological transformation

TEST SYSTEM :: Rodent - hamster Embryo

REFERENCE :: CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut Sts., Philadelphia, PA 19106) V.1- 1941- Volume(issue)/page/year: 39,193,1979 *** REVIEWS *** ACGIH TLV-TWA 0.05 mg(Pb)/m3; animal carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 IARC Cancer Review:Animal Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 23,325,1980 TOXICOLOGY REVIEW 85DHAX "Medical and Biologic Effects of Environmental Pollutants Series," Washington, DC, National Academy of Sciences, 1972-77 Volume(issue)/page/year: Pb,254,1972 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.05 mg(Pb)/m3 JAN 1993 OEL-AUSTRALIA:TWA 0.15 mg(Pb)/m3 JAN 1993 OEL-AUSTRIA:TWA 0.1 mg(Pb)/m3 JAN 1993 OEL-BELGIUM:TWA 0.15 mg(Pb)/m3 JAN 1993 OEL-DENMARK:TWA 0.1 mg(Pb)/m3 JAN 1993 OEL-FINLAND:TWA 0.1 mg(Pb)/m3 JAN 1993 OEL-FRANCE:TWA 0.15 mg(Pb)/m3 JAN 1993 OEL-GERMANY:TWA 0.1 mg(Pb)/m3 JAN 1993 OEL-HUNGARY:STEL 0.04 mg(Pb)/m3;Carcinogen JAN 1993 OEL-THE PHILIPPINES:TWA 0.15 mg(Pb)/m3 JAN 1993 OEL-RUSSIA:STEL 0.005 ppm (0.01 mg(Pb)/m3) JAN 1993 OEL-SWEDEN:TWA 0.05 mg(Pb)/m3 (resp. dust) JAN 1993 OEL-SWEDEN:TWA 0.1 mg(Pb)/m3 (total dust) JAN 1993 OEL-SWITZERLAND:TWA 0.1 mg(Pb)/m3 JAN 1993 OEL-THAILAND:TWA 0.2 mg(Pb)/m3 JAN 1993 OEL-TURKEY:TWA 0.2 mg(Pb)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.15 mg(Pb)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO LEAD, INORGANIC-air:10H TWA <0.1 mg(Pb)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M0125 No. of Facilities: 1613 (estimated) No. of Industries: 35 No. of Occupations: 37 No. of Employees: 23488 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M0125 No. of Facilities: 2531 (estimated) No. of Industries: 40 No. of Occupations: 47 No. of Employees: 59832 (estimated) No. of Female Employees: 19722 (estimated)

黄色氧化铅安全信息

[ 符号 ]:

GHS07, GHS08, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H302 + H332-H351-H360Df-H362-H372-H410

[ 警示性声明 ]:
P201-P260-P263-P280-P301 + P312 + P330-P308 + P313

[ 靶器官 ]:
Blood, Central nervous system, Kidney

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves;type P2 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
T:Toxic; N:Dangerous for the environment;

[ 风险声明 (欧洲) ]:
R20/22;R33;R50/53;R61;R62

[ 安全声明 (欧洲) ]:
S45-S53-S60-S61

[ 危险品运输编码 ]:
UN 1479/2291

[ WGK德国 ]:
3

[ RTECS号 ]:
OG1750000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1(b)

黄色氧化铅制备

1.采用金属铅氧化法。将铅粒在170～210℃进行磨粉，再进行600℃以上高温焙烧氧化，再经粉碎、精制得到一氧化铅成品。

2.在一个2L的玻璃容器中，先将120g醋酸铅溶于250g水中，在强烈搅拌下加入1500mL浓氨水（15mol/L），立即形成白色胶状的碱式醋酸铅2Pb(OH)2·PbAc2沉淀，继续搅拌1～2h，白色沉淀转变为浅绿色结晶，有时要采用倾泻法用浓氨水洗涤几次，沉淀才发生转变。用2mol/L氨水洗涤沉淀，将湿沉淀收集在浅的玻璃器皿中，先在70～95℃下干燥，然后加热至150℃。大约可获得60g金丝雀黄氧化铅。

3.在2L聚乙烯瓶中，让165g三水醋酸铅溶于350mL水中。该溶液以75mL/min速率通过1个铅柱纯化。铅柱是用玻璃柱（10×φ2.5cm）内填充325g纯铅制成的直径10～100μm的小球制成。纯化后的溶液收集在另1个2L聚乙烯瓶中。瓶里放一磁力搅拌子，在激烈搅拌下加入1650mL浓度为10mol/L氨水。几分钟后形成大量白色沉淀并转化为浅绿色沉淀。用2mol/L氨水经倾泻法洗沉淀5次。然后加入200mL水，在80℃下混合10h，得到红色结晶，再用2mol/L氨水洗5次。95℃下白金皿中干燥。最后将干燥的红色PbO加热至150℃，可得80～85g超纯PbO。

4.将工业氧化铅（稍过量）溶解于醋酸水溶液中，加热至沸，反应生成醋酸铅：

保温静置，滤去不溶物，然后边搅拌边加入相对密度为0.90～0.91的氨水（40℃），加热至55-60℃，继续搅拌：

当白色胶状物转变为黄绿色至易下沉的黄色氧化铅后，停止加热，过滤，沉淀用热水洗涤至合格，甩干并干燥，即得试剂氧化铅。

黄色氧化铅文献

Structural investigations on sodium-lead borophosphate glasses doped with vanadyl ions.

J. Phys. Chem. A 116(14) , 3547-55, (2012)

Electron paramagnetic resonance (EPR), optical absorption, and FT-IR spectra of vanadyl ions in the sodium-lead borophosphate (Na(2)O-PbO-B(2)O(3)-P(2)O(5)) (SLBP) glass system have been studied. EPR ...

Electrochemical degradation of the dimethyl phthalate ester on a fluoride-doped Ti/β-PbO2 anode.

Chemosphere 109 , 187-94, (2014)

The electrooxidation of the dimethyl phthalate (DMP) ester was galvanostatically carried out in a filter-press reactor using a fluoride-doped lead dioxide (β-PbO2,F) film electrodeposited on a Ti subs...

A (S)TEM gas cell holder with localized laser heating for in situ experiments.

Microsc. Microanal. 19(2) , 470-8, (2013)

The advent of aberration correction for transmission electron microscopy has transformed atomic resolution imaging into a nearly routine technique for structural analysis. Now an emerging frontier in ...

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