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磷化锌

磷化锌用途

1.磷化锌可以毒杀各种鼠类,是一种优良的杀鼠剂。也可用作粮食仓库熏蒸剂。

2.高毒、急性无机杀鼠剂。鼠吞食后即与胃液中的盐酸作用,放出剧毒的磷化氢,使鼠类中枢神经系统麻痹,血压下降,休克致死。用于杀灭家鼠、田鼠及其他啮齿类动物。应用时一般配成毒饵,连续投药,鼠会产生拒食现象,可与其他杀鼠剂配合使用。
3.磷化锌还可用于树木保护,其原理是磷化锌遇酸释放出剧毒的磷化氢气体,将蛀干类害虫杀灭。目前使用的是熏蒸毒签。制作方法:将阿拉伯胶加水,加热溶解后加入定量的磷化锌,混均后用竹签一端蘸之。晾干后再蘸以草酸、阿拉伯胶,制成毒签。应用时插入有活虫的树洞中,深度3~9cm。也可按磷化锌:草酸为1:3(或1:4)混合后直接装入医用胶囊,使用时将胶囊堵住蛀干害虫损蚀过的洞口即可,防治效果96%。

磷化锌名称

[ CAS 号 ]:
1314-84-7

[ 中文名 ]:
磷化锌

[ 英文名 ]:
zinc phosphide

[中文别名 ]:

[英文别名 ]:

磷化锌物理化学性质

[ 密度 ]:
4,55 g/cm3

[ 沸点 ]:
1100°C

[ 熔点 ]:
420°C

[ 分子式 ]:
H2P2Zn3

[ 分子量 ]:
260.10300

[ 闪点 ]:
1100°C

[ 精确质量 ]:
255.75100

[ PSA ]:
46.94000

[ LogP ]:
1.17950

[ 外观性状 ]:
灰色/黑色杂色颗粒

[ 储存条件 ]:
库房通风低温干燥,与碱、酸类、食品添加剂分开存放

磷化锌MSDS

磷化锌毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
ZH4900000
CHEMICAL NAME :
Zinc phosphide
CAS REGISTRY NUMBER :
1314-84-7
LAST UPDATED :
199701
DATA ITEMS CITED :
22
MOLECULAR FORMULA :
P2-Zn3
MOLECULAR WEIGHT :
258.05
WISWESSER LINE NOTATION :
ZN3 P2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Human - woman
DOSE/DURATION :
80 mg/kg
TOXIC EFFECTS :
Gastrointestinal - nausea or vomiting
REFERENCE :
ZACCAL Zacchia. Archivio di Medicina Legale, Sociale e Criminologica. Zacchia. Archives of Forensic, Social and Criminological Medicine. (Viale Regina Elena 336, Rome 00161, Italy) V.1-13, 1921-34; V.1- 1937- Volume(issue)/page/year: 23,144,1948
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Human - man
DOSE/DURATION :
40 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AJPEAG American Journal of Public Health and the Nation's Health. (New York, NY) V.18-60, 1928-70. For publisher information, see AJHEAA. Volume(issue)/page/year: 36,1427,1946
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
12 mg/kg
TOXIC EFFECTS :
Gastrointestinal - other changes
REFERENCE :
MAGJAL Malaysian Agricultural Journal. (Ministry of Agriculture, Kuala Lumpur, Malaysia) V.45- 1965- Volume(issue)/page/year: 52(2),166,1979
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
450 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 31(9),24,1987
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
45 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
YKYUA6 Yakkyoku. Pharmacy. (Nanzando, 4-1-11, Yushima, Bunkyo-ku, Tokyo, Japan) V.1- 1950- Volume(issue)/page/year: 30,397,1979
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
40 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
YKYUA6 Yakkyoku. Pharmacy. (Nanzando, 4-1-11, Yushima, Bunkyo-ku, Tokyo, Japan) V.1- 1950- Volume(issue)/page/year: 31,1247,1980
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
263 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 31(9),24,1987
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
40 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
YKYUA6 Yakkyoku. Pharmacy. (Nanzando, 4-1-11, Yushima, Bunkyo-ku, Tokyo, Japan) V.1- 1950- Volume(issue)/page/year: 27,189,1976
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - cat
DOSE/DURATION :
40 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
YKYUA6 Yakkyoku. Pharmacy. (Nanzando, 4-1-11, Yushima, Bunkyo-ku, Tokyo, Japan) V.1- 1950- Volume(issue)/page/year: 28,329,1977
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
40 mg/kg
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - respiratory depression Lungs, Thorax, or Respiration - respiratory stimulation
REFERENCE :
JAPMA8 Journal of the American Pharmaceutical Association, Scientific Edition. (Washington, DC) V.29-49, 1940-60. For publisher information, see JPMSAE. Volume(issue)/page/year: 41,468,1952
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A421,1984
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - quail
DOSE/DURATION :
13500 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A421,1984
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - duck
DOSE/DURATION :
37500 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A421,1984
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - domestic
DOSE/DURATION :
60 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,865,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - wild bird species
DOSE/DURATION :
23700 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AECTCV Archives of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 070944) V.1- 1973- Volume(issue)/page/year: 12,355,1983 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
910 mg/kg/13W-C
TOXIC EFFECTS :
Behavioral - food intake (animal) Nutritional and Gross Metabolic - weight loss or decreased weight gain Related to Chronic Data - death
REFERENCE :
IJEBA6 Indian Journal of Experimental Biology. (Publications & Information Directorate, CSIR, Hillside Rd., New Delhi 110 012, India) V.1- 1963- Volume(issue)/page/year: 18,854,1980
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1 mg/m3/17W-I
TOXIC EFFECTS :
Cardiac - pulse rate increase, without fall in BP Blood - pigmented or nucleated red blood cells Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 31(9),24,1987 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:TWA 0.1 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X2920 No. of Facilities: 275 (estimated) No. of Industries: 3 No. of Occupations: 3 No. of Employees: 3862 (estimated) No. of Female Employees: 48 (estimated)

磷化锌安全信息

[ 危害码 (欧洲) ]:
F,T+,N

[ 风险声明 (欧洲) ]:
R15/29

[ 安全声明 (欧洲) ]:
S3/9/14-S30-S36/37-S45-S60-S61

[ 危险品运输编码 ]:
1714

[ RTECS号 ]:
ZH4900000

[ 包装等级 ]:
I

[ 危险类别 ]:
4.3

[ 海关编码 ]:
2848000010

磷化锌制备

1.合成法将赤磷和锌粉混合后,经高温烧成反应,然后冷却、粉碎,制得磷化锌成品。其

磷化锌海关

[ 海关编码 ]: 2848000010

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标题:磷化锌_MSDS_用途_密度_磷化锌CAS号【1314-84-7】_化源网 地址:https://www.chemsrc.com/amp/cas/1314-84-7_829427.html