<生产厂家价格>

六氟丙酮倍半水

六氟丙酮倍半水用途

六氟丙酮水合物是一种优良的溶剂，溶解能力特别强。能与醚和胺形成氢键。可用来从石油馏分中萃取芳香族化合物和用作合成药物的中间体。

六氟丙酮倍半水名称

[ CAS 号 ]:
13098-39-0

[ 中文名 ]:
六氟丙酮倍半水

[ 英文名 ]:
Hexafluoroacetone sesquihydrate

[英文别名 ]:

Hexafluoro-2-propanone sesquihydrate
MFCD00149063
2-Propanone,hexafluoro-,sesquihydrate
1,1,1,3,3,3-Hexafluoroacetone sesquihydrate
Hexafluoroacetone 1.5-hydrate
Acetone,hexafluoro-,sesquihydrate
Hexafluoroacetone sesquihydrate

六氟丙酮倍半水物理化学性质

[ 密度 ]:
1.496g/cm3

[ 沸点 ]:
234.3ºC at 760mmHg

[ 熔点 ]:
10ºC

[ 分子式 ]:
C₆H₆F₁₂O₅

[ 分子量 ]:
386.09000

[ 闪点 ]:
104.3ºC

[ 精确质量 ]:
386.00200

[ PSA ]:
61.83000

[ LogP ]:
3.16730

[ 外观性状 ]:
无色液体

[ 蒸汽压 ]:
5010mmHg at 25°C

[ 储存条件 ]:
库房通风低温干燥,与氧化剂,及食品分开储运

[ 稳定性 ]:
Stable. Reacts with DMSO.

六氟丙酮倍半水MSDS

详细MSDS(安全技术说明书)

六氟丙酮倍半水毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: UC2660000

CHEMICAL NAME :: 2-Propanone, hexafluoro-, sesquihydrate

CAS REGISTRY NUMBER :: 13098-39-0

LAST UPDATED :: 199710

DATA ITEMS CITED :: 9

MOLECULAR FORMULA :: C3-F6-O.3/2H2-O

MOLECULAR WEIGHT :: 193.06

WISWESSER LINE NOTATION :: FXFFVXFFF 2 &QH 3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 670 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CRTXB2 CRC Critical Reviews in Toxicology. (CRC Press, Inc., 2000 Corporate Blvd., NW, Boca Raton, FL 33431) V.1- 1971- Volume(issue)/page/year: 21,149,1990

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 300 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JMCMAR Journal of Medicinal Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB POB 57136, West End Stn., Washington, DC 20037) V.6- 1963- Volume(issue)/page/year: 13,1215,1970

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 250 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JMCMAR Journal of Medicinal Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB POB 57136, West End Stn., Washington, DC 20037) V.6- 1963- Volume(issue)/page/year: 13,1215,1970

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 180 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#03172 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2600 mg/kg/2W-I

TOXIC EFFECTS :: Gastrointestinal - hypermotility, diarrhea Blood - changes in bone marrow (not otherwise specified) Related to Chronic Data - death

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0555368 ** REPRODUCTIVE DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Administration onto the skin

DOSE :: 1820 mg/kg

SEX/DURATION :: male 14 day(s) pre-mating

TOXIC EFFECTS :: Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count) Reproductive - Paternal Effects - testes, epididymis, sperm duct

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 68,188,1983

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Administration onto the skin

DOSE :: 1820 mg/kg

SEX/DURATION :: male 14 day(s) pre-mating

TOXIC EFFECTS :: Reproductive - Paternal Effects - other effects on male

REFERENCE :: TOXID9 Toxicologist. (Soc. of Toxicology, Inc., 475 Wolf Ledge Parkway, Akron, OH 44311) V.1- 1981- Volume(issue)/page/year: 4,135,1984

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Administration onto the skin

DOSE :: 546 mg/kg

SEX/DURATION :: male 14 day(s) pre-mating

TOXIC EFFECTS :: Reproductive - Paternal Effects - testes, epididymis, sperm duct

REFERENCE :: EXMPA6 Experimental and Molecular Pathology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1962- Volume(issue)/page/year: 40,29,1984

六氟丙酮倍半水安全信息

[ 危害码 (欧洲) ]:
Xi,T

[ 风险声明 (欧洲) ]:
R24/25

[ 安全声明 (欧洲) ]:
S36-S45

[ 危险品运输编码 ]:
UN 2552

[ RTECS号 ]:
UC2660000

[ 包装等级 ]:
II

[ 危险类别 ]:
6.1(a)

六氟丙酮倍半水制备

精制方法：先将六氟丙酮气体通过五氧化二磷干燥，再通过一个装有被浓硫酸润湿的Pyrex玻璃棉的管子除去乙烯。若需进一步精制可用低温蒸馏的方法。