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3-烯丙氧基-1,2-丙二醇

3-烯丙氧基-1,2-丙二醇用途

三、用途: 可用于不饱和聚酯型聚氨酯橡胶中不饱和双键的引入单体，使得硫化得以进行。

3-烯丙氧基-1,2-丙二醇名称

[ CAS 号 ]:
123-34-2

[ 中文名 ]:
甘油烯丙基醚

[ 英文名 ]:
3-allyloxy-1,2-propanediol

[中文别名 ]:

[英文别名 ]:

Glycerol-1-allylether
EINECS 204-620-4
Glycerol α-Monoallyl Ether
MFCD00004721
3-prop-2-enoxypropane-1,2-diol
3-ALLYLOXY-1,2-PROPANEDIOL

3-烯丙氧基-1,2-丙二醇物理化学性质

[ 密度 ]:
1.068 g/mL at 25 °C(lit.)

[ 沸点 ]:
142 °C28 mm Hg(lit.)

[ 熔点 ]:
-100 °C

[ 分子式 ]:
C₆H₁₂O₃

[ 分子量 ]:
132.15800

[ 闪点 ]:
132 °C

[ 精确质量 ]:
132.07900

[ PSA ]:
49.69000

[ 外观性状 ]:
透明无色液体

[ 蒸汽压 ]:
0.00991mmHg at 25°C

[ 折射率 ]:
n20/D 1.462(lit.)

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开存放

3-烯丙氧基-1,2-丙二醇MSDS

详细MSDS(安全技术说明书)

3-烯丙氧基-1,2-丙二醇毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TY2700000

CHEMICAL NAME :: 1,2-Propanediol, 3-allyloxy-

CAS REGISTRY NUMBER :: 123-34-2

BEILSTEIN REFERENCE NO. :: 1701144

LAST UPDATED :: 199701

DATA ITEMS CITED :: 8

MOLECULAR FORMULA :: C6-H12-O3

MOLECULAR WEIGHT :: 132.18

WISWESSER LINE NOTATION :: Q1YQ1O2U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 2,574,1950

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 2,574,1950

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,632,1986 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 4200 mg/kg

TOXIC EFFECTS :: Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage) Behavioral - altered sleep time (including change in righting reflex) Lungs, Thorax, or Respiration - respiratory depression

REFERENCE :: FEPRA7 Federation Proceedings, Federation of American Societies for Experimental Biology. (Bethesda, MD) V.1-46, 1942-87. Volume(issue)/page/year: 8,477,1949

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1135 mg/kg

TOXIC EFFECTS :: Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage) Behavioral - muscle weakness Lungs, Thorax, or Respiration - other changes

REFERENCE :: JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 93,470,1948

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 39(4),86,1974 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84034 No. of Facilities: 5 (estimated) No. of Industries: 1 No. of Occupations: 4 No. of Employees: 69 (estimated)

3-烯丙氧基-1,2-丙二醇安全信息

[ 个人防护装备 ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 风险声明 (欧洲) ]:
R36

[ 安全声明 (欧洲) ]:
S26

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
1

[ RTECS号 ]:
TY2700000

[ 海关编码 ]:
2909499000

3-烯丙氧基-1,2-丙二醇合成路线

详细合成路线

3-烯丙氧基-1,2-丙二醇上下游产品

3-烯丙氧基-1,2-丙二醇上游产品

3-烯丙氧基-1,2-丙二醇下游产品

3-烯丙氧基-1,2-丙二醇制备

二、生产方法: 以3-氯丙烯和甘油为原料，乙醇作稀释剂，可进一步合成该品。原料消耗定额：甘油（≥95） 2870kg 、t；3-氯丙烯（≥90） 2150kg 、t；乙醇（≥95） 3680kg 、t；氢氧化钠（≥95） 1040kg 、t

3-烯丙氧基-1,2-丙二醇海关

[ 海关编码 ]: 2909499000

[ 中文概述 ]:
2909499000 其他醚醇及其卤化、磺化、硝化或亚硝化衍生物. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2909499000. ether-alcohols and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:9.0%. . MFN tariff:5.5%. General tariff:30.0%