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1,5-环辛二烯(乙酰丙酮)铱(I)

1,5-环辛二烯(乙酰丙酮)铱(I)名称

[ CAS 号 ]:
12154-84-6

[ 中文名 ]:
1,5-环辛二烯(乙酰丙酮)铱

[ 英文名 ]:
(Acetylacetonato)(1,5-cyclooctadiene)iridium(I)

[中文别名 ]:

[英文别名 ]:

ir(acac)(cod)
(ACETYLACETONATO)(1,5-CYCLOOCTADIENE)IRIDIUM(I)
(acetylacetonato)(1,5-cyclopentadienyl)iridium(I)
acetylacetonate-1,5-cyclooctadiene iridium I
MFCD08273779
acetylacetonate-1,5-cyclooctadieneiridium
(1,5-cyclooctadiene)(2,4-pentanedionato)iridium
1,5-CYCLOOCTADIENE(ACETYLACETONATO)IRIDIUM (I)
1,5-CYCLOOKTADIENE(ACETYLACETONATO)IRIDIUM(I)
[Ir(cod)acac]

1,5-环辛二烯(乙酰丙酮)铱(I)物理化学性质

[ 沸点 ]:
152ºC at 760 mmHg

[ 熔点 ]:
145-150ºC (dec.)

[ 分子式 ]:
C₁₃H₁₉IrO

[ 分子量 ]:
383.50600

[ 闪点 ]:
30ºC

[ 精确质量 ]:
384.10700

[ PSA ]:
17.07000

[ LogP ]:
3.40610

[ 外观性状 ]:
crystal | yellow

[ 蒸汽压 ]:
4.56mmHg at 25°C

[ 储存条件 ]:
存放于惰性气体之中;避免空气

[ 水溶解性 ]:
Insoluble in water.

1,5-环辛二烯(乙酰丙酮)铱(I)MSDS

1,5-环辛二烯(乙酰丙酮)铱(I)毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: NO3615000

CHEMICAL NAME :: Iridium, ((1,2,5,6-eta)-1,5-cyclooctadiene)(2,4-pentanedionato -O,O')-

CAS REGISTRY NUMBER :: 12154-84-6

LAST UPDATED :: 198806

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C13-H19-Ir-O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 47 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CBINA8 Chemico-Biological Interactions. (Elsevier Scientific Pub. Ireland Ltd., POB 85, Limerick, Ireland) V.1- 1969- Volume(issue)/page/year: 45,1,1983

1,5-环辛二烯(乙酰丙酮)铱(I)安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
26

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
NO3615000

1,5-环辛二烯(乙酰丙酮)铱(I)合成路线

1,5-环辛二烯(乙酰丙酮)铱(I)文献

Antitumor effects of rhodium(I), iridium(I) and ruthenium(II) complexes in comparison with cis-dichlorodiammino platinum(II) in mice bearing Lewis lung carcinoma.

Chem. Biol. Interact. 45(1) , 1-6, (1983)

The effects of square planar rhodium, [RhacacCOD]o and iridium, [IracacCOD]o complexes and of octahedral ruthenium, [cis-RuCl2 (DMSO)4]o complex have been examined in comparison with cis-dichlorodiamm...

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