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氯化烯丙基钯(II)二聚物

氯化烯丙基钯(II)二聚物用途

有机合成催化剂

氯化烯丙基钯(II)二聚物名称

[ CAS 号 ]:
12012-95-2

[ 中文名 ]:
氯化烯丙基钯(II)二聚物

[ 英文名 ]:
allyl-chloro-palladium

[中文别名 ]:

[英文别名 ]:

chloropalladium(1+),prop-1-ene
MFCD00044874
Bis(allylchloropalladium)
[PdCl(allyl)]2
EINECS 234-579-8
Bis(allyl)dichlorodipalladium
Diallyldichlorodipalladium
Allylpalladium(II) Chloride Dimer
[PdCl(C3H5)]2
Bis(allyl)dichloropalladium

氯化烯丙基钯(II)二聚物物理化学性质

[ 熔点 ]:
120°C (dec.)

[ 分子式 ]:
C₆H₁₀Cl₂Pd₂

[ 分子量 ]:
365.890

[ 精确质量 ]:
363.822937

[ LogP ]:
3.65900

[ 外观性状 ]:
黄色结晶粉末

[ 蒸汽压 ]:
8480mmHg at 25°C

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开存放

[ 水溶解性 ]:
分解

氯化烯丙基钯(II)二聚物MSDS

详细MSDS(安全技术说明书)

氯化烯丙基钯(II)二聚物毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: RT3510000

CHEMICAL NAME :: Palladium chloride, allyl- (Dimer)

CAS REGISTRY NUMBER :: 12012-95-2

LAST UPDATED :: 197901

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C6-H10-Cl2-Pd2

MOLECULAR WEIGHT :: 365.86

WISWESSER LINE NOTATION :: 2U1-PD-G 2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: AEHLAU Archives of Environmental Health. (Heldref Pub., 4000 Albemarle St., NW, Washington, DC 20016) V.1- 1960- Volume(issue)/page/year: 30,168,1975

氯化烯丙基钯(II)二聚物安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P280-P304 + P340 + P312-P305 + P351 + P338-P337 + P313

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
26-36

[ 危险品运输编码 ]:
UN 3278

[ WGK德国 ]:
3

[ RTECS号 ]:
RT3510000

[ 包装等级 ]:
I

[ 危险类别 ]:
6.1(a)

[ 海关编码 ]:
28439090

氯化烯丙基钯(II)二聚物上下游产品

氯化烯丙基钯(II)二聚物上游产品

氯化烯丙基钯(II)二聚物下游产品

氯化烯丙基钯(II)二聚物海关

[ 海关编码 ]: 28439090

氯化烯丙基钯(II)二聚物文献

Room-temperature Stille cross-couplings of alkenyltin reagents and functionalized alkyl bromides that possess beta hydrogens.

J. Am. Chem. Soc. 125 , 3718, (2003)

This communication describes a significant expansion in the scope of Stille reactions of Csp3-X electrophiles, specifically, that Pd/P(t-Bu)2Me catalyzes the room-temperature cross-coupling of a varie...

The first applications of carbene ligands in cross-couplings of alkyl electrophiles: sonogashira reactions of unactivated alkyl bromides and iodides.

J. Am. Chem. Soc. 125 , 13642, (2003)

A Pd/N-heterocyclic carbene-based catalyst achieves the Sonogashira coupling of an array of functionalized, beta-hydrogen-containing alkyl bromides and iodides under mild conditions. By furnishing the...

Palladium-catalyzed hydroamination of 1,3-dienes: a colorimetric assay and enantioselective additions.

J. Am. Chem. Soc. 123 , 4366, (2001)

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