蒽
蒽用途
用于提取蒽、菲、咔唑,亦可制取蒽醌系染料、炭黑、合成鞣剂及各种油漆
【用途二】
用于制造分散染料、茜素、还原染料的中间体蒽醌,可作塑料、绝缘材料的原料
【用途三】
用作分析试剂及闪烁体,也用于染料的合成
【用途四】
本品主要用于制造染料中间体蒽醌及单宁。可用作杀虫剂、杀菌剂和汽油阻凝剂。高纯蒽用于制取单晶蒽,用在闪烁计数器上。
【用途五】
用以检定茚。制造蒽醌及茜素染料,也用作杀虫剂、杀菌剂、汽油阻凝剂等。
【用途六】
用以检定茚。制造蒽醌及茜素染料,也用作杀虫剂、杀菌剂、汽油阻凝剂等。校准仪器和装置;评价方法;工作标准;质量保证/质量控制;其他。
蒽名称
[ CAS 号 ]:
120-12-7
[ 中文名 ]:
蒽
[ 英文名 ]:
Anthracene
[中文别名 ]:
[英文别名 ]:
- EINECS 204-371-1
- Anthracene
- MFCD00001240
- Paranaphthalene
- ANTHRACEN
蒽物理化学性质
[ 密度 ]:
1.1±0.1 g/cm3
[ 沸点 ]:
337.4±9.0 °C at 760 mmHg
[ 熔点 ]:
215 °C
[ 分子式 ]:
C14H10
[ 分子量 ]:
178.229
[ 闪点 ]:
146.6±12.8 °C
[ 精确质量 ]:
178.078247
[ LogP ]:
4.68
[ 外观性状 ]:
淡黄色片
[ 蒸汽密度 ]:
6.15 (vs air)
[ 蒸汽压 ]:
0.0±0.3 mmHg at 25°C
[ 折射率 ]:
1.715
[ 储存条件 ]:
库房通风低温干燥,与氧化剂分开存放
[ 水溶解性 ]:
0.045 mg/L (25 ºC)
蒽MSDS
蒽毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- CA9350000
- CHEMICAL NAME :
- Anthracene
- CAS REGISTRY NUMBER :
- 120-12-7
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 41
- MOLECULAR FORMULA :
- C14-H10
- MOLECULAR WEIGHT :
- 178.24
- WISWESSER LINE NOTATION :
- L C666J
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - mouse
- TYPE OF TEST :
- LD - Lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- >17 gm/kg
- TOXIC EFFECTS :
- Liver - fatty liver degeneration
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 430 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 20 gm/kg/79W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Liver - tumors
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 3300 mg/kg/33W-I
- TOXIC EFFECTS :
- Tumorigenic - neoplastic by RTECS criteria Tumorigenic - tumors at site of application
- TYPE OF TEST :
- TD - Toxic dose (other than lowest)
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 660 mg/kg/33W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Tumorigenic - tumors at site of application
- TYPE OF TEST :
- Specific locus test
- TYPE OF TEST :
- Micronucleus test
MUTATION DATA
- TYPE OF TEST :
- Cytogenetic analysis
- TEST SYSTEM :
- Rodent - hamster Lung
- DOSE/DURATION :
- 15 mg/L
- REFERENCE :
- ESKHA5 Eisei Shikenjo Hokoku. Bulletin of the Institute of Hygienic Sciences. (Kokuritsu Eisei Shikenjo Kagaku, 18-1 Bushitsu Johobu, Setagaya-ku, Tokyo 158, Japan) V.1- 1886- Volume(issue)/page/year: (103),64,1985 *** REVIEWS *** IARC Cancer Review:Animal Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 32,105,1983 IARC Cancer Review:Human No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 32,105,1983 IARC Cancer Review:Group 3 IMSUDL IARC Monographs, Supplement. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) No.1- 1979- Volume(issue)/page/year: 7,56,1987 *** U.S. STANDARDS AND REGULATIONS *** OSHA PEL (Gen Indu):8H TWA 0.2 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.2 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.2 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.2 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - A1491 No. of Facilities: 149 (estimated) No. of Industries: 4 No. of Occupations: 5 No. of Employees: 2304 (estimated)
蒽安全信息
[ 符号 ]:
GHS07, GHS09
[ 信号词 ]:
Warning
[ 危害声明 ]:
H315-H319-H335-H410
[ 补充危害声明 ]:
Repeated exposure may cause skin dryness or cracking.
[ 警示性声明 ]:
P261-P273-P305 + P351 + P338-P501
[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves
[ 危害码 (欧洲) ]:
Xi:Irritant
[ 风险声明 (欧洲) ]:
R36/37/38
[ 安全声明 (欧洲) ]:
S26-S60-S61-S24/25-S16-S9-S45-S36/37-S62
[ 危险品运输编码 ]:
UN 3077 9/PG 3
[ WGK德国 ]:
2
[ RTECS号 ]:
CA9350000
[ 危险类别 ]:
9.0
[ 海关编码 ]:
29029010
蒽上下游产品
蒽上游产品
蒽下游产品
蒽制备
1.在煤焦油中,蒽的含量为1.4%。焦油连续蒸馏所得的I蒽油馏分段,占焦油12-14%,初馏点为300℃,在350℃前的馏出量为95%。I蒽油经冷却结晶、真空过滤或用离心机脱除部分油分,离心后的粗蒽含油分大于20-25%,其余成分是:蒽25-30%,咔唑20-25%、菲30%左右。其中蒽的收率占焦油中蒽源的58-87%。除了苯和萘以外,蒽是煤焦油中最重要的组分之一。在蒽的工业生产中,因为必须把沸点相近的菲和咔唑分离掉,所以比萘的制造困难得多。即使把蒸馏、结晶及溶剂抽提巧妙地结合起来,其产率也只有40-50%。从粗蒽中提取和精制蒽,是先利用菲易溶于油的特性使菲与蒽、咔唑分离。进一步分离蒽与咔唑的方法有蒸馏分离法和钾熔法。
2.在蒸馏煤焦油最后阶段得到。
蒽海关
[ 海关编码 ]: 2902909090
[ 中文概述 ]:
2902909090. 其他芳香烃. 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:2.0%. 普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量
[ Summary ]:
2902909090 other aromatic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%
蒽文献
Nanoscale 7(16) , 7234-45, (2015)
We report the fabrication of an efficient, label-free, selective and highly reproducible immunosensor with unprecedented sensitivity (femto-molar) to detect a breast cancer biomarker for early diagnos...
High-Sensitivity Surface-Enhanced Raman Scattering (SERS) Substrate Based on a Gold Colloid Solution with a pH Change for Detection of Trace-Level Polycyclic Aromatic Hydrocarbons in Aqueous Solution.Appl. Spectrosc. 69 , 574-9, (2015)
In this study, a gold colloid solution whose parameters were optimized, and without any surfactants, was developed as a surface-enhanced Raman scattering (SERS) substrate for the detection of trace-le...
L-cysteine-capped core/shell/shell quantum dot-graphene oxide nanocomposite fluorescence probe for polycyclic aromatic hydrocarbon detection.Talanta 146 , 780-8, (2015)
Environmental pollutants, such as the polycyclic aromatic hydrocarbons (PAHs), become widely distributed in the environment after emission from a range of sources, and they have potential biological e...
相关化工产品/化学物质:
推荐生产厂家/供应商:
公司名:上海吉至生化科技有限公司
区域:上海市奉贤区
价格:
¥448.0/500g
¥128.0/100g
联系人:刘佳
产品详情:蒽
公司名:上海源溪生物科技有限公司
区域:上海市浦东新区
价格:
¥需询单/1g
联系人:赖经理
产品详情:Anthracene
公司名:上海阿拉丁生化科技股份有限公司
区域:上海市浦东新区
价格:
¥419.0/500g
¥需询单/1g
¥需询单/1g
¥99.0/100g
联系人:阿拉丁李高志
产品详情:蒽
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相关化合物
【蒽】化源网提供蒽CAS号120-12-7,蒽MSDS及其说明、性质、英文名、生产厂家、作用/用途、分子量、密度、沸点、熔点、结构式等。CAS号查询蒽上化源网,专业又轻松。>>电脑版:蒽
标题:蒽_MSDS_用途_密度_蒽CAS号【120-12-7】_化源网 地址:https://www.chemsrc.com/amp/cas/120-12-7_749699.html