右旋反式胺菊酯

右旋反式胺菊酯用途

【用途一】
富右旋胺菊酯是我公司主产品之一，产品性状与右旋胺菊酯相同，是世界卫生组织推荐用于公共卫生的主要杀虫剂之一。富右旋胺菊酯对蚊、蝇等卫生昆虫具有卓越的击倒力，对蟑螂有较强的驱赶作用，可将栖居在黑暗裂隙处的蟑螂赶跑出来，但致死性能差，有复苏现象，故常与其它杀死力高的药剂复配使用。加工成气雾剂或喷射剂，以防治家庭和畜舍的蚊、蝇和蟑螂等。还可以防治庭园害虫和食品仓库害虫。

右旋反式胺菊酯名称

[ CAS 号 ]:
1166-46-7

[ 中文名 ]:
右旋反式胺菊酯

[ 英文名 ]:
D-Tetramethrin

[中文别名 ]:

[英文别名 ]:

MFCD00084635
Tetramethrin
EINECS 214-619-0
d-trans-Tetramethrin
(+)-trans-Phthalthrin
(1R)-trans-Tetramethrin
D-Tetramethrin

右旋反式胺菊酯物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
453.2±45.0 °C at 760 mmHg

[ 熔点 ]:
68-70ºC

[ 分子式 ]:
C₁₉H₂₅NO₄

[ 分子量 ]:
331.406

[ 闪点 ]:
227.9±28.7 °C

[ 精确质量 ]:
331.178345

[ PSA ]:
63.68000

[ LogP ]:
4.78

[ 蒸汽压 ]:
0.0±1.1 mmHg at 25°C

[ 折射率 ]:
1.558

[ 水溶解性 ]:
insoluble

右旋反式胺菊酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: GZ1710000

CHEMICAL NAME :: Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methylpropenyl)-, ester with N-(hydroxy methyl)-1-cyclohexene-1,2-dicarboximide, (+)-(E)-

CAS REGISTRY NUMBER :: 1166-46-7

LAST UPDATED :: 199203

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C19-H25-N-O4

MOLECULAR WEIGHT :: 331.45

WISWESSER LINE NOTATION :: T56 BVNV&TJ C1OV- BL3TJ A1 A1 C1UY1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >2500 mg/kg

TOXIC EFFECTS :: Behavioral - tremor Behavioral - excitement Behavioral - ataxia

REFERENCE :: EVHPAZ EHP, Environmental Health Perspectives. (U.S. Government Printing Office, Supt of Documents, Washington, DC 20402) No.1- 1972- Volume(issue)/page/year: 14,15,1976

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 42 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PCBPBS Pesticide Biochemistry and Physiology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1971- Volume(issue)/page/year: 4,456,1974

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Amphibian - frog

DOSE/DURATION :: >20 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PCBPBS Pesticide Biochemistry and Physiology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1971- Volume(issue)/page/year: 20,217,1983

右旋反式胺菊酯制备

1.2,3,6-甲氢氢邻苯二酸酐与五氧化二磷在200C下反应48小时，得到81% 3,4,5,6-甲氢邻苯二酸酐，沸点144～151°C/599．85Pa(4.5mmHg)，熔点69～70°C，该化合物与氨反应，得到相应的邻苯酰亚胺，熔点170～170.5°C，再与49%甲醛反应，得到89%的N-羟甲基衍生物与1.1L干燥3.5ml苯，21.5g菊酰氯在60ml苯中回流反应12小时，即制得89%的本品。