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1-己硫醇

1-己硫醇用途

【用途一】
食品用香料。

1-己硫醇名称

[ CAS 号 ]:
111-31-9

[ 中文名 ]:
1-己硫醇

[ 英文名 ]:
hexanethiol

[中文别名 ]:

[英文别名 ]:

1-Mercaptohexane,Hexyl mercaptan,MCH
1-Hexanethiol
EINECS 203-857-0
Hexane-1-thiol
hexanethiol
Hexyl Mercaptan
MFCD00004909
n-hexanethiol

1-己硫醇物理化学性质

[ 密度 ]:
0.8±0.1 g/cm3

[ 沸点 ]:
152.3±3.0 °C at 760 mmHg

[ 熔点 ]:
-81 °C

[ 分子式 ]:
C₆H₁₄S

[ 分子量 ]:
118.240

[ 闪点 ]:
20.6±0.0 °C

[ 精确质量 ]:
118.081619

[ PSA ]:
38.80000

[ LogP ]:
3.37

[ 外观性状 ]:
透明液体

[ 蒸汽压 ]:
4.5±0.3 mmHg at 25°C

[ 折射率 ]:
1.446

[ 储存条件 ]:
库房通风低温干燥,与食品、酸类、氧化剂分开储运

[ 水溶解性 ]:
insoluble

1-己硫醇MSDS

1-己硫醇毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MO4550000

CHEMICAL NAME :: 1-Hexanethiol

CAS REGISTRY NUMBER :: 111-31-9

BEILSTEIN REFERENCE NO. :: 1731295

LAST UPDATED :: 199709

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C6-H14-S

MOLECULAR WEIGHT :: 118.26

WISWESSER LINE NOTATION :: SH6

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1254 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - respiratory depression Behavioral - coma

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 19,171,1958

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1080 ppm/4H

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - respiratory stimulation Behavioral - somnolence (general depressed activity) Sense Organs and Special Senses (Eye) - lacrimation

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 19,171,1958

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 396 mg/kg

TOXIC EFFECTS :: Behavioral - muscle weakness Behavioral - ataxia Lungs, Thorax, or Respiration - cyanosis

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 19,171,1958

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 528 ppm/4H

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - lacrimation Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - respiratory stimulation

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 19,171,1958

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 200 mg/kg

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD277-689 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO 1-HEXANETHIOL-air:CL 0.5 ppm/15M REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

1-己硫醇安全信息

[ 符号 ]:

GHS02, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H226-H302-H331

[ 警示性声明 ]:
P261-P311

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R10;R20/22

[ 安全声明 (欧洲) ]:
S23-S24/25-S16

[ 危险品运输编码 ]:
UN 1228 3/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
MO4550000

[ 包装等级 ]:
III

[ 危险类别 ]:
3

[ 海关编码 ]:
2930909090

1-己硫醇合成路线

1-己硫醇海关

[ 海关编码 ]: 2930909090

[ 中文概述 ]:
2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

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