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过氧化乙酸叔丁酯

过氧化乙酸叔丁酯用途

【用途一】
氟呋尿嘧啶的中间体，也可作氧化剂，聚合反应引发剂。

过氧化乙酸叔丁酯名称

[ CAS 号 ]:
107-71-1

[ 中文名 ]:
过氧化乙酸叔丁酯

[ 英文名 ]:
tert-Butyl peroxyacetate

[中文别名 ]:

[英文别名 ]:

tert-butyl ethaneperoxoate
MFCD00048240
tert-Butyl peroxyacetate
tert-Butyl peracetate
EINECS 203-514-5

过氧化乙酸叔丁酯物理化学性质

[ 密度 ]:
0.828 g/mL at 25 °C

[ 沸点 ]:
122.7ºC at 760 mmHg

[ 熔点 ]:
-20 °C

[ 分子式 ]:
C₆H₁₂O₃

[ 分子量 ]:
132.15800

[ 闪点 ]:
99 °F

[ 精确质量 ]:
132.07900

[ PSA ]:
35.53000

[ LogP ]:
1.27960

[ 蒸汽压 ]:
13.8mmHg at 25°C

[ 折射率 ]:
n20/D 1.412

[ 储存条件 ]:
库房通风低温干燥,与有机物、还原物、易燃物、强酸分开存放

过氧化乙酸叔丁酯MSDS

过氧化乙酸叔丁酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: SD8925000

CHEMICAL NAME :: Peroxyacetic acid, tert-butyl ester

CAS REGISTRY NUMBER :: 107-71-1

BEILSTEIN REFERENCE NO. :: 1701510

LAST UPDATED :: 199701

DATA ITEMS CITED :: 11

MOLECULAR FORMULA :: C6-H12-O3

MOLECULAR WEIGHT :: 132.18

WISWESSER LINE NOTATION :: 1X1&1&OOV1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Rinsed with water

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: ZAARAM Zentralblatt fuer Arbeitsmedizin und Arbeitsschutz. (Darmstadt, Fed. Rep. Ger.) V.1-25, 1951-75. Volume(issue)/page/year: 8,25,1958 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 675 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,30,1982

TYPE OF TEST :: LC33 - Lethal Concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 8200 mg/m3/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,30,1982

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 632 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 9,78,1967

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 6000 mg/m3

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 9,78,1967 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1 mg/m3/4H/17W-I

TOXIC EFFECTS :: Behavioral - alteration of operant conditioning Blood - other changes Blood - changes in other cell count (unspecified)

REFERENCE :: TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 10,44,1968 ** REPRODUCTIVE DATA **

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

DOSE :: 1 mg/m3/4H

SEX/DURATION :: male 17 week(s) pre-mating

TOXIC EFFECTS :: Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count)

REFERENCE :: TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 10,44,1968 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-GERMANY JAN 1993 OEL-RUSSIA:STEL 0.1 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5363 No. of Facilities: 3 (estimated) No. of Industries: 1 No. of Occupations: 8 No. of Employees: 277 (estimated)

过氧化乙酸叔丁酯安全信息

[ 符号 ]:

GHS02, GHS06, GHS08

[ 信号词 ]:
Danger

[ 危害声明 ]:
H226-H242-H302-H304-H315-H319-H331-H335-H340-H350

[ 警示性声明 ]:
P201-P210-P280-P304 + P340 + P312-P308 + P313-P370 + P378

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T: Toxic;F: Flammable;O: Oxidizing agent;Xi: Irritant;

[ 风险声明 (欧洲) ]:
R23/24/25

[ 安全声明 (欧洲) ]:
S16-S26-S36/37/39-S45-S62-S47-S14-S7-S53-S3/7

[ 危险品运输编码 ]:
UN 3103 5.2

[ WGK德国 ]:
2

[ RTECS号 ]:
SD8925000

[ 包装等级 ]:
II

[ 危险类别 ]:
5.2

[ 海关编码 ]:
2918300090

过氧化乙酸叔丁酯合成路线

过氧化乙酸叔丁酯制备

用叔丁醇以过氧化氢氧化，生成叔丁基过氧化氢，然后与乙酸酐反应制得该品

过氧化乙酸叔丁酯海关

[ 海关编码 ]: 2918300090

[ 中文概述 ]:
2918300090 其他含醛基或酮基不含其他含氧基羧酸（包括酸酐、酰卤化物、过氧化物和过氧酸及该税号的衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

过氧化乙酸叔丁酯文献

J. Chem. Soc. Perkin Trans. I , 277, (1990)

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