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2-(二丁氨基)乙醇

2-(二丁氨基)乙醇用途

【用途一】
用作聚氨酯的催化剂，纤维助剂及乳化剂。

2-(二丁氨基)乙醇名称

[ CAS 号 ]:
102-81-8

[ 中文名 ]:
2-(二丁氨基)乙醇

[ 英文名 ]:
2-Dibutylaminoethanol

[中文别名 ]:

2-N-二丁氨基乙醇

[英文别名 ]:

2-(dibutylamino)-ethanol
2-Dibutylaminoethanol
2-(dibutylamino) ethanol
MFCD00014033
2-(Dibutylamino)ethanol
Ethanol, 2-(dibutylamino)-
EINECS 203-057-1
Ethanol, 2- (dibutylamino)-

2-(二丁氨基)乙醇物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
229.5±0.0 °C at 760 mmHg

[ 熔点 ]:
-75ºC

[ 分子式 ]:
C₁₀H₂₃NO

[ 分子量 ]:
173.296

[ 闪点 ]:
91.7±0.0 °C

[ 精确质量 ]:
173.177963

[ PSA ]:
23.47000

[ LogP ]:
2.86

[ 外观性状 ]:
无色液体

[ 蒸汽密度 ]:
6 (vs air)

[ 蒸汽压 ]:
0.0±1.0 mmHg at 25°C

[ 折射率 ]:
1.453

[ 储存条件 ]:
库房通风低温干燥,与食品、氧化剂分开储运

[ 稳定性 ]:
Stable. Combustible. Incompatible with strong oxidizing agents.

2-(二丁氨基)乙醇MSDS

2-(二丁氨基)乙醇毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: KK3850000

CHEMICAL NAME :: Ethanol, 2-(dibutylamino)-

CAS REGISTRY NUMBER :: 102-81-8

BEILSTEIN REFERENCE NO. :: 1738441

LAST UPDATED :: 199806

DATA ITEMS CITED :: 23

MOLECULAR FORMULA :: C10-H23-N-O

MOLECULAR WEIGHT :: 173.34

WISWESSER LINE NOTATION :: Q2N4&4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Open irritation test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 11/29/1963

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,695,1986 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1070 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 144 mg/kg

TOXIC EFFECTS :: Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 12,486,1968

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 52 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: RCRVAB Russian Chemical Reviws (English Translation). Translation of USKHAB. (Royal Soc. of Chemistry, Distribution Centre, Blackhorse Rd., Letchworth, Herts SG6 1HN, UK) V.29- 1960- Volume(issue)/page/year: 38,975,1969

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 1680 uL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 120 mg/kg

TOXIC EFFECTS :: Cardiac - change in rate Lungs, Thorax, or Respiration - respiratory depression Gastrointestinal - hypermotility, diarrhea

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 8,344,1966 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 7 gm/kg/5W-C

TOXIC EFFECTS :: Kidney, Ureter, Bladder - changes in bladder weight

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,46,1969

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 70 ppm/6H/5D-I

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,46,1969 *** REVIEWS *** ACGIH TLV-TWA 3.5 mg/m3 (0.5 ppm) (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 2 ppm (14 mg/m3) (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,74,1971 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 2 ppm (14 mg/m3);Skin JAN 1993 OEL-BELGIUM:TWA 2 ppm (14 mg/m3);Skin JAN 1993 OEL-DENMARK:TWA 2 ppm (14 mg/m3);Skin JAN 1993 OEL-FINLAND:TWA 2 ppm (14 mg/m3);STEL 4 ppm (28 mg/m3);Skin JAN 1993 OEL-FRANCE:TWA 2 ppm (14 mg/m3);Skin JAN 1993 OEL-THE NETHERLANDS:TWA 2 ppm (14 mg/m3);Skin JAN 1993 OEL-SWITZERLAND:TWA 2 ppm (14 mg/m3);Skin JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO 2-N-DIBUTYLAMINOETHANOL-air:10H TWA 2 ppm (Sk) REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

2-(二丁氨基)乙醇安全信息

[ 符号 ]:

GHS05, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H302 + H312-H314

[ 警示性声明 ]:
P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
C

[ 风险声明 (欧洲) ]:
21/22-34

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45

[ 危险品运输编码 ]:
UN 2873 6.1/PG 3

[ WGK德国 ]:
1

[ RTECS号 ]:
KK3850000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1(b)

[ 海关编码 ]:
2922199090

2-(二丁氨基)乙醇合成路线

2-(二丁氨基)乙醇上下游产品

2-(二丁氨基)乙醇上游产品

2-(二丁氨基)乙醇下游产品

2-(二丁氨基)乙醇制备

由二丁胺与环氧乙烷反应而得。

2-(二丁氨基)乙醇海关

[ 海关编码 ]: 2922199090

[ 中文概述 ]:
2922199090. 其他氨基醇及其醚，酯和它们的盐（但含一种以上含氧基的除外）. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乙醇胺及其盐应报明色度, 乙醇胺及其盐应报明包装

[ Summary ]:
2922199090. other amino-alcohols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

2-(二丁氨基)乙醇文献

Environmentally Friendly and Highly Sensitive Ruthenium (II) Tris(2,2'-bipyridyl) Electrochemiluminescent System Using 2-(Dibutylamino) ethanol as Co-Reactant. Liu X, et al.

Angew. Chem. Weinheim Bergstr. Ger. 119(3) , 425-428, (2007)

Asymmetric alkenylation of chiral and prochiral aldehydes catalysed by chiral or achiral amino alcohols: catalytic diastereoselective synthesis of protected erythro-sphingosine and enantioselective synthesis of chiral diallyl alcohols. Soai K and Takahashi K.

J. Chem. Soc. Perkin Trans. I 10 , 1257-1258, (1994)

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