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二氯化铂

二氯化铂用途

用于制备高纯铂盐等

二氯化铂名称

[ CAS 号 ]:
10025-65-7

[ 中文名 ]:
二氯化铂

[ 英文名 ]:
Platinum(II) chloride

[中文别名 ]:

氯化铂(II)

[英文别名 ]:

dichloroplatinum(ii)
EINECS 233-034-1
Platinum(2+) dichloride
dichloroplatinum
Platinum (II) chloride
platinum chloride
MFCD00011181
Platinum dichloride
Dichlorure de Platine (2+)
Platinum(II) chloride

二氯化铂物理化学性质

[ 密度 ]:
6.05

[ 熔点 ]:
581ºC

[ 分子式 ]:
Cl₂Pt

[ 分子量 ]:
265.990

[ 精确质量 ]:
264.902496

[ 外观性状 ]:
黄色-绿色固体

[ 蒸汽压 ]:
33900mmHg at 25°C

[ 储存条件 ]:
库房低温,通风,干燥

[ 水溶解性 ]:
INSOLUBLE

二氯化铂MSDS

详细MSDS(安全技术说明书)

二氯化铂毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TP2275000

CHEMICAL NAME :: Platinum chloride (PtCl2)

CAS REGISTRY NUMBER :: 10025-65-7

LAST UPDATED :: 199707

DATA ITEMS CITED :: 9

MOLECULAR FORMULA :: Cl2-Pt

MOLECULAR WEIGHT :: 265.99

WISWESSER LINE NOTATION :: PT G2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3423 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >239 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD40 - Lethal Dose

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 26 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Mammal - dog

DOSE/DURATION :: 156 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold Gastrointestinal - hypermotility, diarrhea

MUTATION DATA

TYPE OF TEST :: Morphological transformation

TEST SYSTEM :: Rodent - hamster Embryo

DOSE/DURATION :: 30 umol/L

REFERENCE :: CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut Sts., Philadelphia, PA 19106) V.1- 1941- Volume(issue)/page/year: 39,193,1979

二氯化铂安全信息

[ 符号 ]:

GHS05, GHS08

[ 信号词 ]:
Danger

[ 危害声明 ]:
H314-H317-H334

[ 警示性声明 ]:
P261-P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
C:Corrosive;Xi:Irritant;

[ 风险声明 (欧洲) ]:
R34;R36/37/38;R42/43

[ 安全声明 (欧洲) ]:
S24-S26-S27-S36/37/39-S45

[ 危险品运输编码 ]:
UN 3260

[ WGK德国 ]:
2

[ RTECS号 ]:
TP2275000

[ 包装等级 ]:
I; II; III

[ 危险类别 ]:
8.0

[ 海关编码 ]:
28439090

二氯化铂制备

1.通常对水体是稍微有害的，不要将未稀释或大量产品接触地下水，水道或污水系统，未经政府许可勿将材料排入周围环境

2.将H2PtCl6·6H2O加热至150℃左右进行预分解，然后将残留物碾碎，在缓慢通入空气下加热至360℃分解。加热时间视取用试样量多寡而定，有时需数小时。最后，未分解的H2PtCl6用水提取除去。产物再次在360℃下干燥。

二氯化铂海关

[ 海关编码 ]: 28439090

二氯化铂文献

Yang, S. C.; Tsai, Y. C.; Shue, Y. J.

Organometallics 20 , 5326, (2001)

Oyamada, J.; Kitamura, J.

Tetrahedron Lett. 46 , 3823, (2005)

Shibata, T.; Fujirawa, R.; Ueno, Y

Synlett , 152, (2005)

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