Novel rearrangement of some phenoxyphosphonium salts

DB Denney, SM Felton

文献索引：Denney,D.B.; Felton,S.M. Journal of the American Chemical Society, 1968 , vol. 90, p. 183 - 187

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被引用次数: 6

摘要

Abstract: Treatment of tris (diethy1amino) phenoxyphosphonium chloride (Ia) and tris (diethy1amino)-p-methoxy-phenoxyphosphonium chloride (Ha) with lithium diethylamide in benzene-hexane led to the rearranged betaines (111 and VI). The structures of these materials were demonstrated by alternate syntheses of derivatives of them. Treatment of the hexafluorophosphate (Ib) in benzene-hexane and hexane alone with lithium diethylamide ...